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1.
A rapid, efficient, convenient and cost-effective procedure has been developed for the synthesis of 3,5-bis-(arylmethylidene)-tetrahydropyran-4-ones by the condensation of tetrahydropyran-4-one with araldehydes in the presence of catalytic amount of iodine to obtain the products in good to excellent yield. The reactions work at 25 °C and go to completion within 30–60 min. 相似文献
2.
Sonochemical oxidation of benzyl alcohols into corresponding aldehydes by FeCl(3)/HNO(3) in acetone at room temperature has been reported. All substrates give good yield of the products within 10-25 min. The reaction of selected substrates were also studied under reflux and at the room temperature. Further, various Lewis acids were used to evaluate their catalytic efficacy. 相似文献
3.
An expeditious synthesis of 2-aryl-benzimidazoles by the condensation of o-phenylenediamine with various araldehydes is described. This greener protocol is catalyzed by Amberlite IR-120, and proceeds efficiently in the absence of any organic solvent under microwave irradiation within 3–5 min. 相似文献
4.
Siddekha A Nizam A Pasha MA 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2011,81(1):431-440
We describe a one-pot four component synthesis of pyranopyroles from aryl aldehydes, ethyl acetoacetate, malononitrile and hydrazine hydrate in the presence of catalytic amounts of an organocatalyst imidazole in water as medium. A plausible mechanism for the formation of imidazole catalyzed pyranopyrazoles has been envisaged. This method is rapid, simple, provides products in good yield, and is eco-friendly. In addition, based on the optimized geometry, the frequency and intensity of the vibrational bands of 6-amino-4-(4'-methoxyphenyl)-5-cyano-3-methyl-1-phenyl-1,4-dihydropyrano[2,3-c]pyrazole were obtained by the density functional theory (DFT) calculations using 6-31G(d,p) basis set. The vibrational frequencies were calculated and the scaled values have been compared with experimental FT-IR and FT-Raman spectra. The observed and the calculated frequencies are found to be in good agreement. 相似文献
5.
A rapid and practical green route for the N-formylation of amines with formic acid using Amberlite IR-120 as a catalyst is described. This method provides an efficient and much improved modification over the reported methods in terms of yield, reaction time, and work-up procedure. A wide variety of substituents is tolerated, which is not the case for existing procedures. 相似文献
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7.
Aatika Nizam 《合成通讯》2013,43(19):2864-2868
A mixture of β-naphthol, araldehydes, and urea in the presence of a catalytic amount of iodine as catalyst under solvent-free condition was heated for 5 min on a preheated hot plate to get the corresponding 1,2-dihydro-1-aryl-naphtho[1,2-e][1,3]oxazine-3-ones in very good yield. 相似文献
8.
Jameel M. Al-Khayri Wudali N. Sudheer Vasantha V. Lakshmaiah Epsita Mukherjee Aatika Nizam Muthu Thiruvengadam Praveen Nagella Fatima M. Alessa Muneera Q. Al-Mssallem Adel A. Rezk Wael F. Shehata Mahesh Attimarad 《Molecules (Basel, Switzerland)》2022,27(9)
Artemisinin is an anti-malarial sesquiterpene lactone derived from Artemisia annua L. (Asteraceae family). One of the most widely used modes of treatment for malaria is an artemisinin-based combination therapy. Artemisinin and its associated compounds have a variety of pharmacological qualities that have helped achieve economic prominence in recent years. So far, research on the biosynthesis of this bioactive metabolite has revealed that it is produced in glandular trichomes and that the genes responsible for its production must be overexpressed in order to meet demand. Using biotechnological applications such as tissue culture, genetic engineering, and bioreactor-based approaches would aid in the upregulation of artemisinin yield, which is needed for the future. The current review focuses on the tissue culture aspects of propagation of A. annua and production of artemisinin from A. annua L. cell and organ cultures. The review also focuses on elicitation strategies in cell and organ cultures, as well as artemisinin biosynthesis and metabolic engineering of biosynthetic genes in Artemisia and plant model systems. 相似文献
9.
An environmentally benign method for the synthesis of octahydro-quinazolin-2,5-diones by the reaction of aromatic aldehydes,dimedone,and urea in the presence of SiO2-NaHSO4 is reported.SiO2-NaHSO4 acts as an efficient,mild,and recyclable heterogeneous catalyst to give excellent yields within a short reaction time in water at 60-80℃. 相似文献
10.
An environmentally benign method for the synthesis of octahydro-quinazolin-2,5-diones by the reaction of aromatic aldehydes,dimedone,and urea in the presence of SiO2-NaHSO4 is reported.SiO2-NaHSO4 acts... 相似文献