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排序方式: 共有181条查询结果,搜索用时 31 毫秒
1.
Robert W. Baker Geoffrey R. Pocock Melvyn V. Sargent Edi Twiss 《Tetrahedron: Asymmetry》1993,4(12):2423-2426
Introduction of a 2-isopropoxycarbonyl or 2-NN-dimethylcarbamoyl group into homochiral 1-p-tolyl- or 1-t-butyl-sulfinylnaphthalenes, via directed metalation reaction, followed by ligand coupling reaction with 1-naphthylmagnesium bromide, furnished atropisomeric 1,1′-binaphthyls in 82–95% enantiomeric excess (e.e.). 相似文献
2.
B. Brocklehurst R.S. Dixon E.M. Gardy V.J. Lopata M.J. Quinn A. Singh F.P. Sargent 《Chemical physics letters》1974,28(3):361-363
Excited state formation by ion recombination in solutions of fluorene in squalene has been studied by pulse radiolysis at the center of a large electromagnet. The products of the slower part of the ion recombination are affected by an applied magnetic field. The fluorescence yield increases by a factor of about 1.5 whereas the triplet yield decreases. 相似文献
3.
Liu JF Ye P Zhang B Bi G Sargent K Yu L Yohannes D Baldino CM 《The Journal of organic chemistry》2005,70(16):6339-6345
A microwave-promoted three-component one-pot reaction has been developed to provide access to the core pyrazino[2,1-b]quinazoline-3,6-dione (1) scaffold, which is common to several families of alkaloids with significant biological activities. By adapting this synthetic strategy through the use of selected Boc-amino acids and amino acid esters, we have accomplished highly efficient and concise total syntheses of glyantrypine (2), fumiquinazoline F (3), and fiscalin B (5), achieving overall yields of 55, 39, and 20%, respectively. 相似文献
4.
Distribution ratios of 15 ethers were determined with various ammonium sulfate eluents and were used to determine the conditions necessary for the separation of five-and seven-component mixtures by salting-out chromatography. The application of this technique was found to be less successful than ion-exchange chromatography for the separation of carboxylic acids. 相似文献
5.
6.
Andrew L. Sargent Mark E. Rollog Cassandra T. Eagle 《Theoretical chemistry accounts》1997,97(1-4):283-288
Fenske-Hall molecular orbital calculations have been applied to a new, structurally isolable analog of the intermediate involved
in catalytic rhodium carboxylate carbenoid transformations. Results from the structural characterization of axially ligated
rhodium acetate phenylisonitrile complexes have been utilized in approximate molecular orbital calculations. The results from
the calculations suggest that a significant degree of π back-bonding exists between the metal and isonitrile fragments which,
by analogy, implies that π back-bonding should also exist in the rhodium carbenoid intermediate. Sensitivity of the Fenske-Hall
method to the magnitude of π back-donation in these complexes was gauged through calculations involving different phenylisonitrile
groups in which the π back-bonding ability was modulated through derivativization. The reliability of the Fenske-Hall method
was evaluated through a comparison to a high-level calculation.
Received: 13 December 1996 / Accepted: 18 March 1997 相似文献
7.
Zhao X Gorelikov I Musikhin S Cauchi S Sukhovatkin V Sargent EH Kumacheva E 《Langmuir : the ACS journal of surfaces and colloids》2005,21(3):1086-1090
Thiol-capped water-soluble PbS nanocrystals (NCs) stabilized with 1-thioglycerol, dithioglycerol, or a mixture of 1-thioglycerol/dithioglycerol (TGL/DTG) were prepared via one-stage synthesis at room temperature. We found that NCs stabilized with a TGL/DTG mixture show efficient and stable infrared photoluminescence centered in the second "biological window" (1050-1200 nm). Under optimized conditions, full width at half-maximum of the PL emission peak was from 70 to 100 nm. PbS NCs were stable to precipitation and aggregation for the time period from 2 to 3 months when stored in the dark under room temperature. Room-temperature photoluminescence quantum efficiency of NCs was from 7 to 10%. When NCs were stored at 37 degrees C, their PL emission red-shifted, consistent with the NC growth. 相似文献
8.
In this paper,we study the surface instability of a cylindrical pore in the absence of stress. This instability is called the Rayleigh-Plateau instabilty. We consider the model developed by Spencer et ... 相似文献
9.
Ebraheem Abdu Musad Saleh Abdullah Mohammed AL Dawsari Kakul Husain Ismail Hassan Kutty K.M.Lokanatha Rai 《Molecules (Basel, Switzerland)》2021,26(2)
A novel synthesis of thiazolo[2,3-b]quinazolines 4(a–e), pyrido[2′,3′:4,5]thiazolo[2,3-b]quinazolines {5(a–e), 6(a–e), and 7(a–e)}, pyrano[2′,3′:4,5]thiazolo[2,3-b]quinazolines 8(a–e), and benzo[4,5]thiazolo[2,3-b]quinazoloine9(a–e) derivatives starting from 2-(Bis-methylsulfanyl-methylene)-5,5-dimethyl-cyclohexane-1,3-dione 2 as efficient α,α dioxoketen dithioacetal is reported and the synthetic approaches of these types of compounds will provide an innovative molecular framework to the designing of new active heterocyclic compounds. In our study, we also present optimization of the synthetic method along with a biological evaluation of these newly synthesized compounds as antioxidants and antibacterial agents against the bacterial strains, like S. aureus, E. coli, and P. aeruginosa. Among all the evaluated compounds, it was found that some showed significant antioxidant activity at 10 μg/mL while the others exhibited better antibacterial activity at 100 μg/mL. The results of this study showed that compound 6(c) possessed remarkable antibacterial activity, whereas compound 9(c) exhibited the highest efficacy as an antioxidant. The structures of the new synthetic compounds were elucidated by elemental analysis, IR, 1H-NMR, and 13C-NMR. 相似文献
10.
In this paper, we develop an algorithmic method for the evaluation of the steady state probability vector of a special class of finite state Markov chains. For the class of Markov chains considered here, it is assumed that the matrix associated with the set of linear equations for the steady state probabilities possess a special structure, such that it can be rearranged and decomposed as a sum of two matrices, one lower triangular with nonzero diagonal elements, and the other an upper triangular matrix with only very few nonzero columns. Almost all Markov chain models of queueing systems with finite source and/or finite capacity and first-come-first-served or head of the line nonpreemptive priority service discipline belongs to this special class. 相似文献