对硝基甲苯在多硫化钠溶液中氧化还原机理的质谱研究

采用高分辨质谱仪跟踪监测对硝基甲苯在多硫化钠存在下于乙醇-碱性水溶液中生成对氨基苯甲醛过程中反应中间体的变化及转变规律.结果显示,在80℃时反应进行到120min之内,有数种分子量较大的缩合中间体生成,表明对氨基苯甲醛可能是经类席夫碱的多聚体水解生成的.同时,对席夫碱多聚体的形成提出了与文献不同的机理.     

Strain-modulated excitonic gaps in mono-and bi-layer MoSe_2

Photoluminescence(PL) and Raman spectra under uniaxial strain were measured in mono- and bi-layer MoSe_2 to comparatively investigate the evolution of excitonic gaps and Raman phonons with strain. We observed that the strain dependence of excitonic gaps shows a nearly linear behavior in both flakes. One percent of strain increase gives a reduction of ~42 meV(~35 me V) in A-exciton gap in monolayer(bilayer) MoSe_2. The PL width remains little changed in monolayer MoSe_2 while it increases rapidly with strain in the bilayer case. We have made detailed discussions on the observed strain-modulated results and compared the difference between monolayer and bilayer cases. The hybridization between 4d orbits of Mo and 4p orbits of Se, which is controlled by the Se–Mo–Se bond angle under strain, can be employed to consistently explain the observations. The study may shed light into exciton physics in few-layer MoSe_2 and provides a basis for their applications.     

全光纤差分吸收激光雷达大气成分探测精度分析

为了提高全光纤差分吸收激光雷达的探测精度,研究近距离探测条件下使用光环形器的差分吸收激光雷达,这对提高气体探测精度具有重要的意义。分析了差分吸收激光雷达的探测精度与激光回波能量测量的关系,发现近距离条件下的气体探测精度将会受到环形器"串音"的影响,分析了不同探测高度下串音对探测精度的影响程度。结合CO2浓度探测的实例并通过仿真计算,得到了信噪比与探测相对误差随探测高度的变化曲线。结果表明,环形器中存在的"串音"会干扰激光回波信号,对探测信噪比与精度产生严重影响。该研究对设计与完善全光纤差分吸收激光雷达系统具有重要的借鉴意义。     

基于液晶相控阵和体全息光栅的激光多目标指示技术

为解决现今激光制导武器指示器指示效率低下、单次指示集群目标能力差等问题,从光束偏转控制和光束角度放大技术的原理出发,以液晶相控阵和多路复用体全息光栅为控件,设计了可用于多目标指示的大角度激光光束偏转控制系统;分析了影响液晶相控阵光束偏转特性的参数的选取规则,确定了大角度光束偏转系统的设计方法,模拟了激光多目标指示系统的指示过程,并对系统误差来源和误差修正方法进行了理论分析和仿真。结果表明:该系统可以快速地对光束实现最大偏转角度为15.63°的二维准连续、可编程控制的偏转;误差修正方法可有效提高激光光束的指示精度,使误差角度下降50%左右。所提出的激光多目标指示系统的设想,可实现对二维平面内多目标的准连续、准同时的精确指示,可为激光多目标指示器的设计提供参考。