水溶性Rh-BISBIS配合物对阿维菌素催化加氢的研究

The hydrogenation of avermectin catalyzed by [RhCl(COD)]_2-BISBIS[COD:1,5-cyclooctadiene,BISBIS:sulfonated 1,1'-bis(diphenylphosphino Methyl-2,2'-biphenyl)] in situ in aquenous/organic two-phase system was studied.The influence of various parameters,such as the surfactant concentration,the molar ratio of rhodium to phosphine,the reaction temperature and pressure on this hydrogenation were investigated.The results showed that the hydrogenation activities of diphosphine was higher that of monophosphine.     

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为了实现 EAST 装置真空室内的内窥多关节机械臂的实时高精度控制,提出了一种逆运动学算法,即建立机械臂多变量的方程组,转化成为矩阵的特征值问题求解。为了验证和满足实际控制的需要,还基于 VC++6.0 开发了 MFC 运动学算法程序。结果表明,该算法能在 ms 级别内得到机械臂的所有运动学逆解。     

金属离子对Ru-Pt/γ-Al2O3催化剂上对氯硝基苯选择加氢反应的影响

 采用混合醇还原法制备了聚乙烯吡咯烷酮(PVP)稳定的Ru-Pt/γ-Al2O3双金属催化剂,考察了其催化对氯硝基苯(p-CNB)选择加氢反应的性能,探讨了反应温度、压力、第三金属离子的种类、添加量及添加方式对反应的影响. 结果表明,以Ru-Pt/γ-Al2O3为催化剂,在1.0 MPa和50 ℃的条件下反应1 h,p-CNB的转化率可达48.2%,生成对氯苯胺(p-CAN)的选择性为87.3%. 在反应体系中添加适量的Fe3+或Sn4+离子时,在相同的反应条件下,p-CNB的转化率和p-CAN的选择性分别提高到100%和99.0%. Fe3+或Sn4+的添加量及添加方式对p-CNB的转化率有较大的影响,加入Fe2+,Co2+和Ni2+离子也有利于提高催化剂的活性和选择性. Ru-Pt/γ-Al2O3催化剂体系对其它氯硝基苯的加氢反应也有明显的催化作用.     

Effect of initial-state target polarization on single ionization of helium by 1-keV electron impact

We report new results of triple differential cross sections for the single ionization of helium by 1-KeV electron impact at the ejection energy of 10 eV. Investigations have been made for both the perpendicular plane and the plane perpendicular to the momentum transfer geometries. The present calculation is based on the three-Coulomb wave function. Here we have also incorporated the effect of target polarization in the initial state. A comparison is made between the present calculation with the results of other theoretical methods and a recent experiment [D黵r M, Dimopoulou C, Najjari B, Dorn A, Bartschat K, Bray I, Fursa D V, Chen Z, Madison D H and Ullrich J 2008 Phys. Rev. A 77 032717]. At an impact energy of 1 KeV, the target polarization is found to induce a substantial change of the cross section for the ionization process. We observe that the effect of target polarization plays a dominant role in deciding the shape of triple differential cross sections.     

模函数的H(o)lder连续性与次可乘性

研究了模函数(ψ)K(a,r)的H(o)lder连续性及次可乘性,建立了(ψ)K(a,r)的几个精确不等式.     

线上线下相融合的教学模式在大学数学教学中的应用与实践

构建了基于翻转课堂的混合式教学模式,将线上教学与线下教学相融合,来培养学生解决复杂问题的综合能力.教学形式呈现先进性和互动性,学生学习具有自主性,课程结构具有开放性,学习协作性等特点.采用线上线下混合式的教学模式,将知识、能力、素质有机融合,努力去构建课前、课中、课后一体化的教学环境.     

一道习题结论的巧用

高中《代数》第二册有这样一道习题:求证:(a~2 b~2)(c~2 d~2)≥(ac bd)~2当且仅当ad=bc时取等号。它是柯西不等式的特例。当然此不等式的证明相当简单;可利用该结论解决一些不等式问题,巧妙简捷,颇具新意,常能使问题化难为易,化繁为简。例1 设a,b均为正数且a b=1,求证:((2a 1)~(1/2)) ((2b 1)~(1/2))≤2 2~(1/2)。     

Effect of Different Energy Sources on Ochrobactrum anthropi Bacteria Chromium Reduction

Ochrobactrum anthropi CTS-325 isolated from a chromium-contaminated site had better resistance to Cr(Ⅵ) in LB medium under aerobic condition.Meanwhile,it was found that the reduction of Cr(Ⅵ) is not complete during the experimental process.Therefore,a series of small molecule energy sources including nitrogen and carbon sources were added into the LB medium in the bacterial stationary phase to promote the chromium reducibility.The result showed that the bacterial growth was positively correlated with the chromium reduction.SDS-PAGE analysis indicated that the protein groups were changed when the bacteria were stimulated by the chromium.Additionally,it was revealed that O.anthropi CTS-325 could utilize the cheaper alternative of sugar(sucrose residue leaching solution) well for further growth and restart the chromium reduction,which offered a new method for practical appli-cations.     

高原地区太阳UV-B增加对燕麦有效光合叶面积及灌浆的影响研究

由于大气的污染造成大气层臭氧层变薄,从而导致来自太阳紫外线-B辐射量增加,青藏高原UV-B增加量为全球第二,主要集中在6～9月份,正是植物生长、繁殖期,因此对植物可能产生一些负面影响。试验在大田条件下通过采用人工UV-B 灯管模拟来增加太阳光辐射量5%和10%,进行对燕麦(Avena sativa)叶片衰老及灌浆期处理研究。结果表明:UV-B强度增加对有效光合面积和叶绿素含量下降的速率并无显著的影响,也未出现提前结束灌浆及早衰的趋势。表明在大田群体条件下,UV-B增加并未显著加速灌浆期燕麦的衰老过程。换言之,在青藏高原上来自太阳紫外辐射量的增加不会造成对草地显著影响。     

植物次生化合物光谱分析预测动物采食量研究进展

植食动物采食量的研究对提高动物生产力以及野生动植物保护有重要的意义,但长期以来对放牧动物和野生动物一直缺乏比较准确的采食量预测方法。植物次生化合物及其代谢物与动物采食量有相关关系,动物排泄物中次生代谢物种类及含量取决于其采食的植物次生化合物。应用波谱分析技术,对动物排泄物中的次生代谢物及其在植物中的前体物(对应的植物次生化合物)进行提取、分离和纯化、结构鉴定,并进行量化分析,建立次生代谢物与采食量之间的回归相关关系和浓度-比率模型,可以准确地预测放牧家畜和野生动物的采食量。最具预测采食量潜力的一类次生化合物是芳香族化合物及其衍生物,并已经在利用光谱技术的基础上,以单宁、链烷、类黄酮等作内源标记物预测采食量方面取得了进展。提出了存在问题和需进一步研究的方向。