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1.
肌酐是肾脏疾病诊断和监测的关键生物标志物,因此,快速、灵敏的肌酐检测非常重要.本文提供了一种通过提高低温下的光子诱导电荷转移效率来促进表面增强拉曼散射光谱(SERS)活性的有效策略.采用种子生长法获得纳米金二十面体(Au20),以此作为SERS活性基底.采用极低温(98 K)SERS检测技术实现对染料分子结晶紫(CV)和生理盐水中的肌酐含量的快速、灵敏检测.实验结果表明:常温296 K下, Au20基底对CV分子的检测限(LOD)低至10–12 mol/L,并且信号均匀;低温98 K时, CV分子的LOD可达10–14 mol/L,比296 K时降低2个数量级.最后,使用Au20基底对生理盐水中的肌酐进行无标记检测.结果表明,常温296 K时该SERS基底对肌酐的LOD为10–6 mol/L, 1619 cm–1峰的线性相关系数为0.9839.低温98 K时,肌酐的浓度探测极限低至10–8 mol/L, 1619... 相似文献
2.
An analysis is made of the effect of Doppler broadening on gain
without inversion (GWI) from different aspects in a closed
lambda-type three-level system with an incoherent pump. It is shown
that, regardless of the driving field being on resonance or not, for
the counter- or co-propagating of the probe and driving fields (PDF),
GWI does not monotonically decrease or increase with increasing
Doppler width. Except for the case of counter-propagating PDF with
off-resonance driving field, at a suitable Doppler width one can
obtain a gain maximum value much larger than that without Doppler
broadening; especially in the situation of the resonant driving
field, the co-propagating geometry leads to a larger GWI. In
addition, for the counter-propagating geometry, when Doppler width is
larger enough, GWI oscillation occurs, and the oscillation amplitude
and region increase with increasing Doppler width. These conclusions
are very different from that obtained in previous investigation
(Lukin {\it et al}, {\it Laser Phys.} {\bf 6} 436 (1996)). 相似文献
3.
Imprints of molecular orbitals using photoelectron angular distribution by strong laser pulses of circular polarization 下载免费PDF全文
We theoretically investigate the strong-field ionization of H+2 molecules in four different electronic states by calculating photoelectron angular distributions in circularly polarized fields. We find that the structure of photoelectron angular distribution depends on the molecular orbital as well as the energy of the photoelectron. The location of main lobes changes with the symmetric property of the molecular orbital. Generally, for molecules with bonding electronic states, the photoelectron's angular distribution shows a rotation of π/2 with respect to the molecular axis, while for molecules with antibonding electronic states, no rotation occurs. We use an interference scenario to interpret these phenomena. We also find that, due to the interference effect, a new pair of jets appears in the waist of the main lobes, and the main lobes or jets of the photoelectron's angular distribution are split into two parts if the photoelectron energy is sufficiently high. 相似文献
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家电行业并购的财务风险预警研究 总被引:1,自引:0,他引:1
通过对家电行业的特点及其并购过程中财务风险的分析,建立了家电行业并购的财务风险评价指标体系,运用层次分析法确定各指标权重,给出了我国家电行业并购财务风险预警的模糊综合评价模型,并通过四川长虹与美菱电器的并购案例进行了实证分析,对并购活动中财务风险防范与控制方面存在的问题进行了分析,明确了财务风险防范与控制的重点. 相似文献
6.
Effect of spontaneously generated coherence on inversionless lasing gain in an atomic system with Doppler broadening 总被引:1,自引:0,他引:1 下载免费PDF全文
We have studied the effect of the spontaneously generated coherence
(SGC) on gain of lasing without inversion (LWI) in a closed
three-level $\Lambda $-type atomic system with Doppler broadening. It
is shown that, regardless of the driving and probe fields being co-
or counter-propagating, at a suitable value of the Doppler width, we
can obtain a much larger LWI gain with SGC than that without SGC; and
the region of the LWI gain spectrum with SGC is obviously larger than
that without SGC. When the Doppler width takes a constant value, the
gain does not monotonically decrease or increase with increasing
strength of SGC, the largest LWI gain can be obtained by adjusting
strength of SGC. Generally speaking, the co-propagating probe and
driving fields is favourable to obtain a larger LWI gain. 相似文献
7.
Comparison between effects of Doppler broadening on pure and non-pure inversionless gains with frequency up-conversion 下载免费PDF全文
A study is made of the effects of Doppler broadening on
pure gain without inversion, which means that neither one-photon
nor two-photon inversions are allowed, and non-pure gain without
inversion, which means that one-photon inversion does not occur
but two-photon inversion is present, in a closed Λ-type
three-level system with incoherent pumping. It is shown that when
the driving field is resonant but the probe field is not, in a
certain range of Doppler width, for the case of the lower degree of
frequency up-conversion, generally, pure gain without inversion
increases monotonically and non-pure gain without inversion does
not monotonically increase or decrease with increasing Doppler width;
for the case of the higher degree of frequency
up-conversion, pure gain without inversion decreases
monotonically but non-pure gain without inversion cannot be
produced. In the case of two-photon resonance, in some range of
Doppler width, pure gain without inversion does not
monotonically increase or decrease while non-pure gain without
inversion decreases monotonically with Doppler width increasing.
Finally, an experimental scheme for examining our theoretical result
is given. 相似文献
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稳态循环伏安法具有简单、快速判别电极性能和估算电极尺寸的特性,因而被广泛应用于超微电极的表征.但纳米电极由于尺寸极小,其表面形貌的细微变化对电化学行为有明显的扰动,从而影响纳米电极表征的准确性.结合电化学实验和有限元模拟,探讨了纳米电极尺寸、绝缘层半径和电极半径之和与电极半径之比(RG)和尖端孔道对稳态电流的影响.研究表明尺寸较小(r ≤ 80 nm)的纳米圆盘电极,由于反应速率相对扩散较慢,电极反应过程受动力学效应控制,使稳态电流曲线偏离半球形扩散控制的标准"S"型.此外RG值较小的纳米圆盘电极,物质到电极的传递被增强,使极限电流值增大.我们对内嵌式纳米电极进行了进一步研究,并发现电极尖端孔道阻碍了电活性物质的扩散,削弱了动力学的限制,使极限电流值低于同尺度的纳米圆盘电极,伏安电流曲线呈现标准的"S"型.本研究系统地探讨了电极尖端形貌与稳态电流的相互关系,加深了对纳米电极电化学行为的理解. 相似文献
10.
随机需求下基于商业信用的回购与收入共享联合契约协调研究 总被引:2,自引:0,他引:2
在由单个供应商和单个零售商组成的供应链中,零售商由于资金短缺或风险规避不能达到系统的最优订货量,因此需要采取一些措施使得供应链节点企业间相互合作来实现供应链的协调。本文针对需求随机且供应链节点企业存在缺货惩罚的情况,通过设计基于商业信用(即供应商允许零售商延期支付货款)的完全回购契约来促进零售商提高订购量,以实现供应链系统达到最优利润,分析给出了该契约下的最优订货量和批发价格;在此基础上,为了合理分配供应链系统的总利润,建立了回购与收入共享联合契约模型,发现通过共享系数的变动能够实现供应链系统协调和渠道成员双赢。 相似文献