聚对苯二甲酸乙二酯的熔融双峰

未拉伸聚对苯二甲酸乙二酯(PET)、单轴拉伸PET、双轴拉伸PET在不同条件下热处理,并进行了DSC热分析、X-射线衍射分析、红外分析。结果表明:熔融双峰现象起因于DSC等速升温过程中PET的部分熔融和重结晶;低温峰是等温热处理过程中形成的不完善微晶的熔融峰,高温峰是重结晶后较完善的微晶的熔融峰;在等速升温过程中,PET晶胞参数不变、晶格完善、晶粒增大,并且规则折迭链增加,但晶粒随温度增大的过程中出现低谷。     

THE DOUBLE MELTING PEAKS OF POLY(ETHYLENE TEREPHTHALATE)

Three sets of PET samples, comprising original (undrawn), uniaxially drawn and biaxially ones, after annealed at 230°, 240°and 250℃respectively, were subjected to DSC thermal analysis, X-ray diffraction analysis and IR analysis. The results indicate that the phenomenon of double melting peaks during DSC analysis is due to the partial melting and recrystallization of the crystallite at the moment of thermal scanning. The lower temperature peak, which varies slightly according to annealing condition, corresponds to the melting of imperfect crystallite, and the higher temperature peak corresponds to the melting of better organized crystallite. In the course of temperature scanning, the unit cell parameters of PET remains unchanged while the crystals turn to better crystal lattice, greater crystal size and more regular folding.We also found that there is a slight reduction in crystal size between the two melting peaks, and an explanation is suggested for this phenomenon.