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A series of random copolymers(PCLAs) were synthesized by ring-opening polymerization of D,L-lactide(LA)and ε-caprolactone(CL) with different molar ratios. PCLA based polyurethanes(PCLAUs) were obtained by chain-extending of PCLA and polytetramethylene ether(PTMEG) with hexamethylene diisocyanate(HDI). All the PCLAUs exhibit good shape memory properties with high shape fixity ratios above 98% and shape recovery ratios above 82% in the first cycle and 91% in the second cycle. PCLAUs with less CL content show faster recovery speed and PCLAUs with more CL content show higher shape recovery ratio. The trigger temperature can be tuned or controlled around body temperature by adjusting the molar ratio of LA to CL. The PCLAUs have potential applications in implant biomedical devices, especially for minimally invasive deployable devices. 相似文献
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电场纺丝是制备生物可降解及生物材料纳米纤维非织造布的简单工艺,由于纳米纤维具有较大的比表面积,具有多孔结构,使其在生物医学领域,如:组织工程、药物缓释及医用纱布等领域有潜在的应用前景。本文综述了生物降解材料及生物材料的电场纺丝及其应用。 相似文献
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