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本文报道了中药五味子中新的降转氨酶活性物质五味子丙素,即:5,6,7,8四氢-1,12-双甲氧基-2,3,10,11-双次甲二氧基-6,7-顺式二甲基联苯[a,c]环辛四烯(12-B)及其6,7-反式二甲基异构体(16-B)的全合成。同时合成了它们的同分异构体——5,6,7,8-四氢-3,10-双甲氧基-1,2,11,12,-双次甲二氧基-6,7-顺式二甲基联苯[a,c]环辛四烯(12-A)和6,7-反式二甲基异构体(16-A)。讨论了四个异构体的质谱,核磁共振谱及紫外光谱。合成化合物12-B的红外光谱(氯仿溶液)、紫外光谱、核磁共振谱和质谱与天然五味子丙素相同。 相似文献
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This paper reports the total synthesis of (±) schizandrin, C, namely S, 6, 7, 8-tetrahydro-1,12-dimethoxy-2, 3, 10, 11-bismethylenedioxy-6, 7-cis-dimethyldibenzo (a, c) cyclooctene (12B), a new active SGPT lowering principle isolated from the Chinese medical plant Schizandra chinensis, and its 6, 7-trans-dimethyl isomer (16B). We also synthesized two more isomers, namely 5, 6, 7, 8-tetrahydro-3, 10-dimethoxy-1, 2, 11, 12-bismethylenedioxy-6, and 7-cis-(and trans-) dimethyldibenzo (a, c) eyelooctene (12A and 16A). The NMR, UV and mass spectra of these four isomers are discussed. IR (in chloroform), UV, NMR and MS of synthetic schizandrin C (12B) are identical with those of the natural compound. 相似文献
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