铝钛合金溴化物对直链烷烃异构化反应的催化作用

首次研究了铝铁合金溴化物的合成及其对直链烷烃异构化反应的催化作用,讨论了正戊烷的异构化反应,得到其动力学方程为1nC/C_0=-0.50t,表观活化能为26.3 kJ/moJ,测定了正己烷、正庚烷、正辛烷在不同溶剂中、不同温度下催化异构化反应的动力学曲线,为铝铁合金溴化物的工业应用提供了理论依据。     

乙醇对超临界CO2中乙酰乙酸乙酯异构化平衡的影响

超临界流体（SCF）是物质所处的温度和压力同时高于其临界值时的流体．在超临界体系中存在特殊的分子间相互作用，从而使其具有诸如高压缩性、高扩散系数、强溶剂化力等许多独特的性质.在超临界流体研究领域引起人们普遍关注的问题之一是共溶剂效应（cosolventeffect），即在超     

复合材料树脂传递模塑工艺及适用树脂

简要介绍树脂模型工艺（RTM）的基本原理,优点及适用树脂的特性;对适用于RTM工艺的先进基体树脂进行综述,并介绍了国内外的商业开发情况。     

Tl系超导薄膜金属涂层的生长与特性研究

我们研究了Tl-2212超导薄膜在带有YSZ/CeO2缓冲层和带有CeO2/YSZ/CeO2缓冲层的Ni金属RABiTS基带上的生长情况.基带上的缓冲层是采用PLD方法制备的,Tl-2212薄膜的制备采用了磁控溅射和后热处理两步方法.XRD 实验结果表明,Tl-2212薄膜都具有很好的C轴垂直于膜面的织构,并具有双向外延生长特性.在CeO2/YSZ/CeO2/Ni基带上制作的Tl-2212薄膜的Tc达到102.8 K,Jc(77 K,0 T)达到2.6 MA/cm2;在YSZ/CeO2/Ni基带上薄膜Tc可达97.7 K,Jc(77 K,0 T)也可以达到0.45 MA/cm2.     

高温退火对蓝宝石基片的表面形貌和对CeO缓冲层以及Tl-2212超导薄膜长的影响

研究了蓝宝石(1102)基片在不同温度和时间下退火时表面形貌和表面相结构的变化,以及它对CeO2缓冲层和T1-2212超导薄膜生长的影响.原子力显微镜(AFM)研究表明,在流动氧环境中1000℃温度下退火,蓝宝石(1102)的表面首先局部区域形成台阶结构,然后表面形成叠层台阶结构,随着退火时间的延长.表面发生了台阶合并现象,表面形貌最终演化为稳定的具有光滑平台的宽台阶结构.XRD测试表明,通过高温热处理可以大幅度提高蓝宝石基片表面结构的完整性.在1000℃温度下热处理20 h的蓝宝石(1102)基片上可以生长出具有面内取向的CeO2(001)缓冲层.在具有缓冲层的蓝宝石基片上可以制作出高质量c轴织构的外延11-2212超导薄膜,其临界转变温度(Tc)为104.7 K,液氮温度下临界电流密度(Jc)达到3.5 MA/cm2,微波表面电阻R(77 K,10 GHz)约为390μΩ.     

热噪声对约瑟夫森结I-V特性及微波感应台阶的影响研究

采用数值仿真的方法研究了热噪声对约瑟夫森结I-V特性及微波感应台阶的影响。研究表明,热噪声导致约瑟夫森结的I-V特性曲线呈现"圆拱化",也使得微波感应台阶高度减小。得出了取不同约瑟夫森结临界电流和结电阻时,热噪声对台阶的影响规律     

A NEW METHOD OF ADAPTIVE ARRAY PROCESSING FOR SIGNALS OF UNKNOWN CHARACTERISTICS

This paper describes a new method of adaptive array processing for signals of unknown frequencycharacteristics.Under practical circumstances,it is easier to obtain the estimation of the power spec-trum in the observed direction than to obtain that of the frequency characteristics.Thus the maximumentropy spectral analysis can be used to incorporate with the adaptive array processing. In this paper the autocorrelation function is calculated from the power spectrum and the predictedcoefficients of MEM(maximum entropy method)can be obtained by solving the normal equation of thecorrelation matrix,and the predicted coefficients are used as the constrained conditions of the algorithmfor adaptive array processing. The above method is further extended and an adaptive array processor is presented for the moregeneral cases,in which the signal characteristics in the observed direction are completely unknown.Firstly the space filtering of the adaptive array is performed by the all-pass constrained conditions inthe fr     

Phase Locking and Chaos in a Josephson Junction Array Shunted by a Common Resistance

The dynamics of a Josephson junction array shunted by a common resistance are investigated by using numerical methods. Coexistence of phase locking and chaos is observed in the system when the resistively and capacitively shunted junction model is adopted. The corresponding parameter ranges for phase locking and chaos are presented. When there are three resistively shunted junctions in the array, chaos is found for the first time and the parameter range for chaos is also presented. According to the theory of Chernikov and Schmidt, when there are four or more junctions in the array, the system exhibits chaotic behavior. Our results indicate that the theory of Chernikov and Schmidt is not exactly appropriate.     

约瑟夫森结的混沌行为及其在保密通信中的应用

约瑟夫森结的混沌行为在研究和应用方面都具有重要的价值。电阻-电容-电感并联约瑟夫森结在直流电流的驱动下会出现混沌行为,采用数值计算的方法,对混沌行为进行了研究。通过电压波形、频谱、对初始条件的敏感依赖以及奇怪吸引子,证实了混沌的存在,在此基础上首次提出了基于约瑟夫森结混沌行为的保密通信方案。     

TlBaCaCuO外延膜的光响应

在波长γ＝６３２．８ｎｍ，入射功率约０．８ｍ的Ｈｅ－Ｎｅ激光照射下，对ＴｌＢａ２Ｃａ２ＣｕＯ２（Ｔｌ－２２１２）外延膜的光响应行为进行了实验研究。结果显示：在样品转变温度（Ｔｃ＝１０５．５Ｋ）附近，ＴｌＢａ－ＣａＣｕＯ外延膜的光响应行为表现为辐射热与非辐射热效应共存现象。光响应信号电平与样品温度、偏置电流、及入射光束的调制频率等诸因素有密切关系的关系。实验结果还表明，辐射热与非辐射热效应的响应行为