Structural evolution and bandgap modulation of layered β-GeSe2 single crystal under high pressure

Germanium diselenide (GeSe₂) is a promising candidate for electronic devices because of its unique crystal structure and optoelectronic properties. However, the evolution of lattice and electronic structure of $β$-GeSe₂ at high pressure is still uncertain. Here we prepared high-quality $β$-GeSe₂ single crystals by chemical vapor transfer (CVT) technique and performed systematic experimental studies on the evolution of lattice structure and bandgap of $β$-GeSe₂ under pressure. High-precision high-pressure ultra low frequency (ULF) Raman scattering and synchrotron angle-dispersive x-ray diffraction (ADXRD) measurements support that no structural phase transition exists under high pressure up to 13.80 GPa, but the structure of $β$-GeSe₂ turns into a disordered state near 6.91 GPa and gradually becomes amorphous forming an irreversibly amorphous crystal at 13.80 GPa. Two Raman modes keep softening abnormally upon pressure. The bandgap of $β$-GeSe₂ reduced linearly from 2.59 eV to 1.65 eV under pressure with a detectable narrowing of 36.5%, and the sample under pressure performs the piezochromism phenomenon. The bandgap after decompression is smaller than that in the atmospheric pressure environment, which is caused by incomplete recrystallization. These results enrich the insight into the structural and optical properties of $β$-GeSe₂ and demonstrate the potential of pressure in modulating the material properties of two-dimensional (2D) Ge-based binary material.     

铕掺杂纳米二氧化钛透明光触媒乳液的制备及光催化性能研究

本文采用常温络合—控制水解法,以TiCl_4,有机羧酸,氨水,硝酸铕,D-山梨醇等为主要实验药品,制备了Eu掺杂纳米TiO_2光触媒乳液。以酸性红3R染料为待降解物,分别考察了不同条件下制备的TiO_2光触媒乳液在太阳光模拟器生成光照射下的光催化性能。此外,还考察了Eu掺杂纳米二氧化钛透明光触媒乳液对于不同浓度染料的光催化性能。通过酸性红3R染料的降解实验,研究了影响Eu掺杂纳米二氧化钛透明光触媒乳液光催化活性的因素。通过X射线衍射仪(XRD)、纳米激光粒度分析仪、紫外可见分光光度计(UV-Vis)等对样品进行表征。结果表明:样品的平均粒度为4.1 nm左右,晶型为锐钛矿,样品的吸收光谱可拓宽至可见光区。当Eu掺杂量为0.3%,pH值为6,回流时间是15 min时,制备的Eu掺杂纳米二氧化钛光触媒乳液的光催化性能最佳。该光触媒乳液经太阳光照射1 h之后,对浓度为25 mg/L的酸性红3R模型反应物的降解效率最高,达到97%以上。     

时间延迟增强双稳系统的共振抑制

研究了时间延迟对双稳系统激活率的影响.在短时间延迟的情况下,应用最陡下降法导出延迟双稳系统的平均首通时间表达式和相应的与延迟时间有关的激活率表达式.数值计算结果表明,时间延迟可以增强双稳系统的共振抑制.     

时间延迟增强双稳系统的共振抑制

研究了时间延迟对双稳系统激活率的影响.在短时间延迟的情况下,应用最陡下降法导出延迟双稳系统的平均首通时间表达式和相应的与延迟时间有关的激活率表达式.数值计算结果表明,时间延迟可以增强双稳系统的共振抑制.     

空间太阳能电站发展及研究

随着国际能源危机的日益紧迫,空间太阳能电站（SPS）概念受到了世界各国的广泛关注,发展SPS,优化能源结构也成为我国解决能源需要的可靠途径。本文对SPS的起源、概念和发展历程进行了阐述,针对当前SPS典型系统模型,分析和总结了SPS的关键技术。结合我国当前的技术水平和未来科技发展的进步,对我国发展SPS提出了设想,采用先进的轻型薄膜聚光设计概念初步提出了一种新型SPS构型,并介绍了该构型的组成、功能及光路设计。该结构大大减小了系统质量,降低了运载的发射成本和发射难度,可为未来我国SPS的发展提供有益补充和借鉴。     

聚合氯化铝制备拟薄水铝石及γ-Al2O3的研究Ⅱ——表面活性剂影响探讨

本实验采用自制的聚合氯化铝溶液为原料,利用溶胶-凝胶法制备拟薄水铝石及其衍生物γ-Al2O3,采用XRD、TEM和N2吸附法对样品进行表征和分析,探讨了不同pH值、不同合成温度以及不同pluronic表面活性剂对产物结构性质的影响。结果表明:当pH值为8.5时水合氧化铝以拟薄水铝石为主;当温度为70℃时制备的产物为拟薄水铝石晶相。随着表面活性剂L64、L65和F68分子量的增加,生成的拟薄水铝石及其衍生物γ-Al2O3的物相结晶度升高,但产物的晶相没有改变。所制备的拟薄水铝石在500℃焙烧6 h后均得到γ-Al2O3,其中表面活性剂为L65时扩孔效果最佳,比表面积、孔容和孔径分别为231 m2.g-1、0.28 cm3.g-1和4.52 nm。     

氧化钇纳米粉浸渍处理对氧化铝陶瓷抗钢液腐蚀性能的影响

研究了氧化钇纳米粉浸溃处理方式对氧化铝陶瓷的抗钢液腐蚀性能的影响。分别考察了氧化钇纳米粉浸溃时间和浸溃次数对该性能的影响。实验结果表明：试样经不同的浸溃处理后，其气孔率减小，晶粒细化，材料的抗钢液腐蚀性能也得到显著改善，但不同的处理方式改善的程度不同，延长纳米浸泡时间48h以及提高材料的浸泡次数均可以大大提高材料的抗钢液腐蚀能力。     

Misalignment error calibration of faro retro probe for laser tracker system

A technique to calibrate faro retro probe using laser tracker system (LTS) is presented. The deep-access retro probe enables LTS to perform three-dimensional (3D) measurements of surface hidden features. It has been shown that misalignment errors are the key contributor to measuring errors of retro probe. A device for measuring misalignment errors of retro probe is invented. Theoretical analysis and experiment show that using this technique to calibrate retro probe, the misalignment errors of retro probe can be eliminated effectively and quickly.