近距离下射流冲击平板PIV实验研究

运用时间分辨粒子成像测速系统(time-resolved particle image velocimetry, TR-PIV)对近距离下射流冲击平板时的流场进行了直接测量, 通过对两个正交的平面流场开展测量, 揭示了冲击距离和雷诺数对射流间隙内三维流动特征及涡系结构演化规律的影响. 结果表明: 射流间隙存在三种典型的涡系结构, 分别为双涡环模式、单涡环模式和卷吸模式, 但在大流量湍流状态下, 射流可能会冲破涡环, 形成随机的高速出流, 各流动模式的出现主要与射流流态及壁面约束作用有关. 运用涡量分析对三种典型涡系结构的能量传递和损失特性进行了比较. 结果表明: 近距离冲击时, 射流的能量通过涡环模式向外传递. 在双涡环模式下, 两个涡环的旋向相反, 端面的约束作用使得两个涡环都被严格约束在射流棒端面之内, 且一次涡环强度显著大于二次涡环强度. 最后, 运用本征正交分解方法对射流间隙内的流动模态及其能量分布进行了分析. 单涡和双涡模式前十阶模态分析结果表明: 能量脉动在较低阶时即以配对的模式出现, 这表明一次涡环与二次涡环均具有良好的对称性, 同时在双涡模式中, 一次涡环是占主导作用的大尺度流动结构. 卷吸模式的前三阶模态分析表明: 射流的能量集中在射流上游, 能量随紊动扩散急剧衰减.      

Synthesis,Structure,and Characterization of a Novel Coordination Polymer with Polythreading Feature

A novel coordination polymer 1 with formula of Zn₂(BDC)₂(TPPA) was built from 1,4-dicarboxybenzene (H₂BDC),tris(4-(pyridin-3-yl)phenyl)amine (TPPA),and Zn(Ⅱ) ion.It was characterized by single-crystal and powder X-ray diffraction,Fourier-transform infrared spectra (FT-IR),thermal gravimetric analysis (TGA),and UV-vis.1 crystallizes in triclinic space group P1 with a=14.589,b=14.606,c=16.108?,α=115.635~o,β=90.328~°,γ=114.662~o,V=2738.6A³,Z=2,M_r=935.52 g/mol,D_c=1.134 g/cm~3,F(000)=956,GOOF=1.062,the final R=0.0685 and w R=0.1817 for 7701 observed reflections with (I>2σ(I)),and R=0.0717 and w R=0.1843 for all data.In 1,Zn(Ⅱ) is coordinated with H₂BDC to form a 2D square grid,and TPPA ligands were arranged above and beneath the 2D layer.Two neighbor layers are interpenetrated each other byπ-πinteractions to generate a polythreading framework structure.Moreover,the photoluminescence of 1 was also studied.