黑柱石-水之间氢同位素动力分馏的实验研究

在350—650℃,实验研究了黑柱石-水之间氢同位素动力分馏。研究结果表明,黑柱石-水之间氢同位素交换以扩散交换为主。氢扩散活化能为118.5kJ/mol(圆柱模式)和115.5kJ/mol(薄板模式),交换活化能为122.2kJ/mol,黑柱石-水之间氢同位素交换的封闭温度远低于其形成温度,因此黑柱石形成后,还会与后期热液继续进行氢同位素交换。     

Experimental Study of Hydrogen Isotope Kinetic Fractionation Between Ilvaite and Water——The Kinetics of D-H Exchange in Ilvaite-H_2O

Hydrogen isotope kinetic fractionation in the ilvaite and water system has been studied experimentally at 350-650℃. The result of study shows that the exchange mechanism of hydrogen isotope between ilvaite and water is dominated by hydrogen diffusion.The activation energy for hydrogen diffusion in ilvaite is 118.4 kJ/mol for cylinder model and 115.5 kJ/mol for plate model, respectively.The activation energy for hydrogen isotope exchange in ilvaite is 122.6 kJ/mol.The closure temperature for the cessation of hydrogen isotope exchange between ilvaite and water is much lower than its formation temperature.So, after ilvaite crystallizes, the hydrogen isotope exchange between ilvaite and late hydrothermal solution will continue to take place.