等规聚苯乙烯的分子量分级

用配位聚合法得到的高等规度的等规聚苯乙烯(i-PS),一般具有较宽的分子量分布,对其进行分子量分级是比较难的,迄今已有不少这方面的报道,其中包括采用热力学的方法,以及采用分子量降解的方法。为了获得分子量分布较窄的i-PS样品来研究单链单晶,我们也进行了i-PS的分级研究,我们选用了一种新的溶剂/不良溶剂体系对i-PS     

近场宽带电场耦合天线的高频结构模拟器软件仿真及性能分析

近场宽带电场耦合天线是一种新型的短距离、高速无线通信天线,它是索尼公司力推的近距离高速无线通信技术——.Transferjet^TM的工作天线.使用高频结构模拟器软件,对一种典型的近场宽带电场耦合天线进行了参数化的结构设计;通过仿真模拟,分析短截线的线长和线宽,以及耦合电极的面积对天线中心频率和工作带宽的影响;分析了天线间的距离和夹角,以及耦合电极的面积,对天线传输损耗和性能的影响.设计了一个满足Transferjet^TM技术指标的小尺寸天线,给出了性能仿真结果.     

等规聚苯乙烯的单分子链及单链单晶的尺寸判据

将等规聚苯乙烯配成苯的稀溶液，在水面上逐滴扩散，制备得到等规聚苯乙烯的超细微粒，并将微粒在４４８．２Ｋ等温结晶．用透射电镜对非晶态和昌态的粒子进行研究．由电镜测量得到的等规聚苯乙烯的分子量及分子量分布与其ＧＰＣ表征值基本相符，证明我们所得到的超细微粒是单分子尺寸的．     

An electromagnetic view of relay time in propagation of neural signals

We review the experimental and computational data about the propagation of neural signals in myelinated axons in mice,cats,rabbits,and frogs published in the past five decades.In contrast to the natural assumption that neural signals occur one by one in time and in space,we figure out that neural signals are highly overlapped in time between neighboring nodes.This phenomenon was occasionally illustrated in some early reports,but seemed to have been overlooked for some time.The shift in time between two successive neural signals from neighboring nodes,defined as relay timeτ,was calculated to be only 16.3μs-87.0μs,i.e.,0.8%-4.4%of the average duration of an action potential peak(roughly 2 ms).We present a clearer picture of the exact physical process about how the information transmits along a myelinated axon,rather than a whole action potential peak,what is transmitted is only a rising electric field caused by transmembrane ion flows.Here in the paper,τrepresents the waiting time until the neighboring node senses an attenuated electric field reaching the threshold to trigger the open state.The mechanisms addressed in this work have the potential to be universal,and may hold clues to revealing the exact triggering processes of voltage-gated ion channels and various brain functions.     

Long range electromagnetic field nature of nerve signal propagation in myelinated axons

The nature of saltatory conduction in myelinated axon described by equivalent circuit and circuit theory is still contentious. Recent experimental observations of action potentials transmitting through disjointed nerve fibers strongly suggest an electromagnetic wave propagation mechanism of the nerve signals. In this paper, we employ the electromagnetic wave model of the myelinated axon to describe action potential signal propagation. We use the experimental frequency-dependent conductivity and permittivity values of the nerve tissues in order to reliably calculate the electromagnetic modes by using electromagnetic mode solvers. We find that the electromagnetic waves above 10 {kHz} can be well confined in extracellular fluid—myelin sheath—intracellular fluid waveguide and propagate a distance of 7 mm without much attenuation. Our study may serve as one of the fundamental researches for the better understanding of the nervous system.     

等规聚苯乙烯的分子量分级

Fractionation of isotactic polystyrene based on phase equilibrium was preformed by using o-dimethylphthalate (DMP) as a solvent and cyclohexanol (CHA) as a nonsolvent. Fractionation with semi-preparative GPC was also preformed. The effect of fractionation based on phase equilibrium is limited, but the result obtained from semi-preparative GPC is quite well.     

体超导铟对一维锌超导纳米线超导电性的抑制效应

文章细致研究了超导体铟／一维锌超导纳米线阵列／超导体铟夹心结构的超导电性．实验发现，当锌纳米线的长度在2—6μm、直径等于40nm时，宏观尺寸的超导体铟电极对中间的锌纳米线的超导电性具有反常的抑制作用,即当铟处在超导态时，中间的锌纳米线则停留在正常态．如果施加一个磁场，使超导体铟电极变为正常态，锌纳米线则恢复其超导电性，这种奇异的现象与超导电极材料的类型及锌纳米线的直径和长度有关。