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Cobait(Ⅱ) nitrate reacted with 1,10-phenanthroline (phen) and 5-sulfosaiicylic acid (H3ssal) to yield the cobait(Ⅰ) complex [Co(phen)2(H2O)2](Hssal)o4H2O (1) and the reaction of 1 with copper acetate led to a novel complex [Co(phen)(H2O)4][Cu2(ssal)2(phen)2]·5H2O (2). These two complexes were cationanion species and the cationic motif [Co(phen)2(H2O)2]^2+of 1 could be converted to [Co(phen)(H2O)4]^2+ in the formation process of new anion [Cu2(phen)2(ssal)2]^2- of 2. In both complexes abundant hydrogen bonds construct different supramolecular architectures, thus the conversion reaction can provide a new path to create novel supramolecular network. 相似文献
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