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硅钼钒和硅钨钒杂多酸催化过氧化氢直接氧化苯制苯酚的活性研究 总被引:4,自引:0,他引:4
以自制的两种Keggin型杂多酸,硅钼钒杂多酸和硅钨钒杂多酸作催化剂,冰醋酸作溶剂,过氧化氢作氧化剂,研究了由苯直接羟基化制苯酚的催化活性,发现对于所研究的体系,即苯为0.02mol,过氧化氢为0.16mol,冰醋酸为0.24mol,当杂多酸的用量为0.10~0.15mmol、反应温度323K、反应时间80min时,硅钼钒和硅钨钒上苯酚的收率分别可达17.2%和4.3%,选择性达90.3%和87.4%. 相似文献
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钼钒磷杂多酸的合成及催化性能研究 总被引:15,自引:0,他引:15
Three heteropoly acids containing different amounts of V and Mo have been prepared by multi-step method. The methed was simple, economic in raw materials’ cost, and with relatively higher yield. ICP, TGA, Potentiometric Titrations, Infrared, XRD and 51V NMR characterizations revealed that the compounds synthesized in present work had Keggin structure. The catalytic performance of the heteropoly acids obtained for the direct hydroxylation of benzene to phenol was also investigated, 26% phenol yield with more than 90% selectivity was obtained. 相似文献
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