应用移动反应界面富集技术进行毛细管电泳尿液指纹分析

快速灵敏的尿液指纹图谱分析对于临床诊断中发现新的生物标记至关重要。该文建立了一种简便、快速、灵敏的移动反应界面(MRB)介导的富集技术进行毛细管电泳尿液指纹图谱分析。MRB由25 mmol/L甘氨酸（Gly）-HCl（pH 2.5）作为样品缓冲液和50 mmol/L Gly-NaOH（pH 12.3）作为电泳缓冲液形成。与常规的毛细管区带电泳只能观察到尿液中不到10个峰相比,采用MRB可以观察到超过80个峰并将检测灵敏度提高了至少十几倍,显示该方法对于代谢组学分析具有重要的意义。     

MRCI+Q study of the low-lying electronic states of CdF including spin-orbit coupling

Cd F molecule, which plays an important role in a great variety of research fields, has long been subject to numerous researchers. Due to the unstable nature and heavy atom Cd containing in the Cd F molecule, electronic states of the molecule have not been well studied. In this paper, high accurate ab initio calculations on the Cd F molecule have been performed at the multi-reference configuration interaction level including Davidson correction(MRCI + Q). Adiabatic potential energy curves(PECs) of the 14 low-lying Λ–S states correlating with the two lowest dissociation limits Cd(~1S_g) + F(~2P_u) and Cd(~3P_u) + F(~2P_u) have been constructed. For the bound Λ–S and ? states, the dominant electronic configurations and spectroscopic constants are obtained,and the calculated spectroscopic constants of bound states are consistent with previous experimental results. The dipole moments(DMs) of 2 Σ+ and 2Π are determined, and the spin–orbit(SO) matrix elements between each pair of X2Σ+, 22Σ+, 12Π, and 22Π are obtained. The results indicate that the sudden changes of DMs and SO matrix elements arise from the variation of the electronic configurations around the avoided crossing region. Moreover,the Franck–Condon factors(FCFs), the transition dipole moments(TDMs), and radiative lifetimes of low-lying states-the ground state X2Σ+are determined. Finally, the transitional properties of 22Π–X2Σ+and 22Σ+–X2Σ+are studied. Based on our computed spectroscopic information of Cd F, the feasibility and challenge for laser cooling of Cd F molecule are discussed.     

核科学中的世纪女杰

在20世纪的核物理领域中出现了四位令人瞩目的女科学家,除了我们所熟悉的居里夫人、吴键雄之外,还有奥地利物理学家丽丝·迈特纳和美国物理学家玛丽亚·梅耶.她们都堪称核科学中的巾帼英雄,对核科学的发展起了巨大的推动作用.     

核力与电荷无关吗

 在核物理教科书中,几乎都要讲到核力的电荷无关性,或者说同位旋不变性。所谓核力与电荷无关是指一对核子,不论是中子－中子,质子－质子或中子－质子,只要处于同样的空间状态和自旋状态,就具有相同的核力作用。核力的电荷无关性也可表述为两个核子之间的作用与两个核子的总同位旋投影Ｔ３无关。但是,核力的电荷无关只是近似成立,核力在同位旋空间的转动不变性,并不是绝对的,而是存在着破缺。这种破缺包括电荷无关性破缺（ＣＩＢ）和电荷对称性破缺（ＣＳＢ）,总共约有１％的量级。关于这种破缺的根源和对核物理各方面的影响已有不少研究。     

超核物理学进展

简要评述超核物理学近几年的发展,包括常规超核和非常规超核两个方面.对于包含通常超子的常规超核,重点介绍近来在日本KEK完成的一批超核实验及其理论分析.对其中关于超子杂质效应和超子平均自由路程等实验测量结果进行了理论分析,得到一些有意义的结果.并对奇异数为S=-2的Ξ超核的结构和性质进行了若干研究.对于包含C夸克或B夸克的其他味超核,以及可能的包含pentaquark的θ+超核也做了适当的介绍. Progress and recent status of experimental and theoretical investigations on hypernuclear physics are briefly reviewed, including conventional hypernuclear physics and unconventional hypernuclear physics. We introduce the recent progress of hypernuclear experiments in KEK, Japan and the studies of fine structure in γ-ray spectroscopy of Λ hypernuclei. The spin-flip transition between the ground-state spin doublet of light hypernuclei has been observed and the transition energy provides important..