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The pyridine coordinated sandwich-type heteropolytungstate Na7[Ni(H2O)6] { [Na(H2O)2]3[Ni(C5H5N)]3(AsW9O33)2}·28H2O was obtained by the reaction of Na2WO4·2H2O, NaAsO2 and pyridine with NiCl2·6H2O at pH =7.0 and characterized by elemental analysis, IR, UV-Vis,^1H NMR spectra and magnetic measurement. The structure of this heteropolytungstate was determined by X-ray diffraction analysis, which crystallized in triclinic system, space group P1 with a= 1.3153(9) nm, b= 1.7228(12) nm, c=2.6866(19) nm, a=74.130(11)°,β=78.032(12)°, γ = 73.179(12)° and Z= 2, R1 = 0.0604, wR2 = 0.0915 [I〉 2σ(I)]. Polyanion {[Na(H2O)2]3[Ni(C5H5N)]3(AsW9O33)2}^9- has approximately C3 symmetry, and three pyridine coordinated Ni(C5H5N)^2+ and three Na(H2O)2^+ are encapsulated between two AsW9O33^9- . Magnetic measurements show that central Ni3 unit in the polyanion exhibits ferromagnetic Ni-Ni exchange interactions (J=6.17 cm^-1). 相似文献
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