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The thermal behavior and thermal decomposition kinetic parameters of podophyllotoxin (1) and 4 derivatives, picropodophyllin (2), deoxypodophyllotoxin (3), fl-apopicropodophyllin (4), podophyllotoxone (5) in a temperature-programmed mode have been investigated by means of DSC and TG-DTG. The kinetic model functions in differential and integral forms of the thermal decomposition reactions mentioned above for first stage were established. The kinetic parameters of the apparent activation energy Ea and per-exponential factor A were obtained from analy- sis of the TG-DTG curves by integral and differential methods. The most probable kinetic model function of the decomposition reaction in differential form was (1- a)^2 for compounds 1-3,2/3·a^-1/2 for compound 4 and 1/2(1-a)·[-In(1-a)]^-1 for compound 5. The values of Ea indicated that the reactivity of compounds 1-5was increased in the order: 5〈4〈2〈1〈3. The values of the entropy of activation △S^≠, enthalpy of activation △H^≠ and free energy of activation △G^≠ of the reactions were estimated. The values of △G^≠ indicated that the thermal stability of compounds 1-3 with the samef(a) was increased in the order: 2〈3〈1. 相似文献
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为了满足光学非线性器件设备对工作材料的要求,探究具有高阶非线性效应的固态薄膜材料的制备方法,并对其光学特性进行表征,采用化学插入法,将甲基蓝染料分子插入到具有纳米量级的层状钛酸盐片间,制备了甲基蓝-钛酸盐纳米聚合物薄膜,通过吸收光谱和荧光光谱的测定,发现薄膜的吸收峰相对于染料溶液发生了明显的蓝移,表明染料分子在纳米片间是H-聚集排列。进一步应用单光束连续He-Ne激光Z-扫描技术研究了样品的非线性光学特性,结果显示:插入染料分子的钛酸盐纳米MB/HTO聚合物薄膜具有“负”的非线性折射率,在低功率连续激光作用下聚合物薄膜的非线性折射率系数n2的量级为10-10 m2/W。 相似文献
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