一维链状配位聚合物[Co(imbz)2(H2O)2]n[imbz=4′-(1-咪唑基亚甲基)苯甲酸根]的合成及晶体结构

A new coordination polyme[Co (imbz)₂(H₂O)₂]_n[imbz =4'-(imidazol-1-ylmethyl)benzoate anion]was synthesized and characterized by x-ray crystallography.The title complex crystallizes in monoclinic,space group P2₁/c,a=10.910(2),b=8.8720(18),c=11.252(2)Å,β=92.20(3)°,V=1088.3(4)ų,Z =2,D_c=1.518g·cm^-3,μ=0.836cm^-1,F(000)=514,R=0.0679,wR=0.1710.Each Co(Ⅱ)atom has a distorted octahedral coordination geometry and is six-coord-inated by two water molecules and fou rimbz ligands.Each imbz ligand connects two Co(Ⅱ) to gen-erate an infinite 1Dtwisted chain structure.     

一维链状配位聚合物[Co(imbz)_2(H_2O)_2]_n[imbz=4′-(1-咪唑基亚甲基)苯甲酸根]的合成及晶体结构(英文)

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