Synthesis, Crystal Structure and Antibacterial Activity of Two Hydrazones Derived from 2-Fluorobenzhydrazide

Two new Schiff base benzoyl hydrazone compounds, C14H10FN3O3 (Ⅰ) and C14H10F2N2O (Ⅱ), have been synthesized and characterized by elemental analysis, IR, UV and X-ray single-crystal diffraction. Both compounds crystallize in monoclinic, space group P21/c with a = 7.0514(14), b = 25.928(5), c = 7.7099(15), β = 111.823(2)°, V = 1308.6(4)3, Z = 4, C14H10FN3O3, Mr = 287.25, Dc = 1.458 g/cm3, μ(MoKα) = 0.115 mm-1, F(000) = 592, the final R = 0.0841 and wR = 0.2489 for 1901 observed reflections (I > 2σ(I)) for I; a = 11.232(3), b =12.735(4), c = 8.612(2) , β = 90.869(3)°, V = 1231.7(6)3, Z = 4, C14H10F2N2O, Mr = 260.24, Dc = 1.403 g/cm3, μ(MoKα) = 0.111 mm-1, F(000) = 536, the final R = 0.0453 and wR = 0.1085 for 1317 observed reflections (I > 2σ(I)) for Ⅱ. The antibacterial activities of both compounds against two bacteria were first studied and one compound showed considerable antibacterial activity against K. Pneumonia and S. aureus.     

便携式回路热管辅助热电制水装置的性能研究

目前,由于全球性淡水短缺,开发高效淡水制取技术迫在眉睫。热电空气制水因其小巧,性能可靠并且结构简单,而被应用于便携式野外生存制水。为进一步提升其制水能力,本文提出了一种新型回路热管辅助热电制水装置。基于传统热电制水装置,利用回路热管的高效换热性能对湿空气预冷,通过提升制冷量的方式提高其制水量。本文构建了新型装置的稳态仿真数学模型并与传统装置进行了对比分析。结果表明新型装置一天可以制取淡水2.12 L。与传统装置相比,新型装置的制冷量和制水量分别提高了16.22%和32.89%。此外,本文还研究了换热器热沉端的翅片数,进口湿空气的湿度以及质量流量对性能的影响。结果可为实际系统构建提供一定的理论指导。