含硫甲基的芴-苯结构化合物的合成、结构和性能

通过双Suzuki偶联反应一步合成了2种含硫甲基的芴-苯结构化合物2,7-二(4-硫甲基苯基)-9,9-二己基-芴(a)和2,7-二(2,6-二甲基-4-硫甲基苯基)-9,9-二己基-芴(b).紫外-可见和荧光光谱以及分子轨道理论计算表明,位阻较小的化合物a具有更好的共轭性能,其最大紫外-可见吸收波长达到351nm,比两端苯基含4个邻位取代基的化合物b红移了38nm;化合物a的最大荧光发射波长达到410nm,为典型的蓝光化合物,比化合物b红移了43nm.化合物a和b都具有较高的荧光量子产率,分别为59%和65%,在光电材料方面具有潜在的应用前景.     

逆升压式吊舱涡轮冷却器动力涡轮变工况特性研究

随着现代战机电子战能力的提升,电子吊舱设备发热功率日益增大,采用冲压空气作为冷源的逆升压式电子吊舱环控系统能够为机载吊舱提供充足的冷量。具有膨胀涡轮、动力涡轮、压缩涡轮的涡轮冷却器是逆升压式环控系统的核心部件。针对一种应用于机载电子吊舱的逆升压式空气循环系统进行了关键部件的匹配性能研究,通过改变动力轮进口压力来调节膨胀轮出口温度、压力、流量等参数,实现对环控系统的制冷量的控制,获得动力轮进口压力变化对环控系统性能的影响规律。     

Constructing the three-qudit unextendible product bases with strong nonlocality

Unextendible product bases (UPBs) are interesting members of a family of orthogonal product bases. Here, we investigate the construction of 3-qudit UPBs with strong nonlocality. First, a UPB set in ${{C}^{3}}\otimes {{C}^{3}}\otimes {{C}^{3}}$ of size 19 is presented based on the shift UPBs. By mapping the system to a Rubik's cube, we provide a general method of constructing UPBs in ${{C}^{d}}\otimes {{C}^{d}}\otimes {{C}^{d}}$ of size ${{\left(d-1 \right)}^{3}}+2d+5$, whose corresponding Rubik's cube is composed of four parts. Second, for the more general case where the dimensions of parties are different, we extend the classical tile structure to the 3-qudit system and propose the tri-tile structure. By means of this structure, a ${{C}^{4}}\otimes {{C}^{4}}\otimes {{C}^{5}}$ system of size 38 is obtained based on a ${{C}^{3}}\otimes {{C}^{3}}\otimes {{C}^{4}}$ system of size 19. Then, we generalize this approach to the ${{C}^{{{d}_{1}}}}\otimes {{C}^{{{d}_{2}}}}\otimes {{C}^{{{d}_{3}}}}$ system which also consists of four parts. Our research provides a positive answer to the open question raised in by Halder et al. [$Phys. Rev. Lett$. 122 040403 (2019)], indicating that there do exist UPBs that can exhibit strong quantum nonlocality without entanglement.     

以N为中心的阴离子离子液体的合成、表征及应用

首次通过不同阴离子的钾盐和不同的季铵化的咪唑,吡咯溴盐/氯盐进行离子交换,合成了一系列含氰基官能团的阴离子功能化离子液体。通过红外、核磁共振、质谱对离子液体的结构进行表征;通过TGA对离子液体的热稳定性进行测定,结果发现功能化离子液体具有良好的热稳定性,其分解温度在224-289℃范围内。将功能化离子液体[EMIm][N(CN)COC2H5]作为配体应用于无膦配体的Suzuki偶联反应,发现在反应中加入功能化离子液体[EMIm][N(CN)COC2H5]可以使反应收率提高10-20%。     

A rational quantum state sharing protocol with semi-off-line dealer

A rational quantum state sharing protocol with the semi-off-line dealer is proposed. Firstly, the dealer Alice shares an arbitrary two-particle entangled state with the players by Einstein-Podolsky-Rosen (EPR) pairs and Greenberger-Horne-Zeilinger (GHZ) states. The EPR pairs are prepared by Charlie instead of the dealer, reducing the workload of the dealer. Secondly, all players have the same probability of reconstructing the quantum state, guaranteeing the fairness of the protocol. In addition, the dealer is semi-off-line, which considerably reduces the information exchanging between the dealer and the players. Finally, our protocol achieves security, fairness, correctness, and strict Nash equilibrium.