用后功能化方法合成含吲哚二阶非线性光学发色团侧基的高分子

用后功能化方法合成了两类连有吲哚二阶非线性光学发色团侧基的高分子.通过核磁、红外、紫外-可见、示差扫描量热分析、分子量测定等手段对所得高分子进行了鉴定.此合成方法简便易行,易于产物的分离提纯,为二阶非线性光学材料的合成提供了一种新方法.     

A New Synthetic Strategy to Prepare a Polyphosphazene with Charge－Transporting Agents and Nonlinear Optical Chromophores as Side Chains

A new strategy, a post coupling method to develop the polyphosphazene (P2) functionalized with carbazolyl groups and nonlinear optical (NLO) chromophores, has been ex-plored. P2 exhibits good solubility in common organic solvents. The poled film of P2 exhibits a resonant d33 value of 42 pm/V by second harmonic generation (SHG) measurements.     

Synthesis and Characterization of a Series of New Functional Poly(ferrocenylenesilanes) for Nonlinear Optics

ＩｎｔｒｏｄｕｃｔｉｏｎＰｏｌｙ(ｆｅｒｒｏｃｅｎｙｌｓｉｌａｎｅｓ)ａｒｅａｎｏｖｅｌｃｌａｓｓｏｆｔｒａｎｓｉｔｉｏｎｍｅｔａｌｏｒｇａｎｏｍｅｔａｌｌｉｃｐｏｌｙｍｅｒｓｗｉｔｈａｂａｃｋｂｏｎｅｃｏｎｓｉｓｔｉｎｇｏｆａｌｔｅｒｎａｔｉｎｇｆｅｒｒｏｃｅｎｅａｎｄｏｒｇａｎｏｓｉｌａｎｅｕｎｉｔｓ .Ｈｉｇｈｍｏｌｅｃｕｌａｒｗｅｉｇｈｔｐｏｌｙ(ｆｅｒｒｏｃｅｎｙｌｅｎｅｓｉｌａｎｅｓ)ｗａｓｆｉｒｓｔｓｙｎ ｔｈｅｓｉｚｅｄｖｉａｔｈｅｒｍａｌｒｉｎｇ ｏｐｅｎｉｎｇｐｏｌｙｍｅｒｉｚａｔｉ…