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The solid state reaction of 3-methyl-1-phenyl-5-pyrazolone (MPP) with aromatic aldehydes and ke-tones benzil derivatives and imides,and the solid state Michael addition reaction of MPP with 4-arylidene-3-methyl-1-phenyl-5-pyrnzolone 2 were investigated.Some new solid state reactions between the reactants were found,from which a series of new compounds were obtained The structures of the products were identified by IR,1H NMR,MS,elemental analyses and also by X-ray crystal analysis,and the reaction mechanism of MPP with aromatic aldehydes and ketones was proposed 相似文献
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本文研究了乙酰基香豆素及其衍生物与吲哚的混晶在微环境影响下的固相光反应,并用固体紫外光谱、固体荧光光谱和X-射线粉末衍射技术考察了混晶的特征。实验结果表明,3-乙酰基香豆素及其7-乙酰氧基、7-苯甲酰氧基、5,6-苯并和6-溴衍生物与吲哚的固相光反应分别得到1:2缩合产物1~5,而6-硝基衍生物与吲哚的固相光反应却得到开环脱羰加成产物6。通过IR、MS、^1H NMR和元素分析结果确定了这六个新产物的结构。固体光谱的测试结果表明,取代乙酰基香豆素与吲哚间混晶的形成,分子间存在相互作用,使分子所处的微环境条件发生了变化。 相似文献
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Synthesis and characterization of thermally crosslinked polyimide with second-order nonlinear optical chromophore 总被引:3,自引:0,他引:3
Incomparisonwithinorganicnonlinearoptic(NLO)materials,organicpolymericNLOmaterialshavemanyadvantages,suchasliablemoleculardesignandoptimization,largernonresonanceNLOcoefficiency,lowerdielectricconstant,goodworkingability,opticaltransparencyandresistancea… 相似文献
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Lewis酸与Chalcone配合物固相光化学反应的研究李晓陆,王永梅,孟继本(南开大学化学系,天津,300071)关键词Lewis酸,Chalcone,配合物,固相光化学反应晶体结构是决定固相光化学反应能否发生的关键因素,即分子的排列方式不同,其固... 相似文献
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Solid state Michael addition reaction of indole with α,β-unsaturaled carbonyl compounds was carried out,by which a series of compounds containing three different heterocyclic groups binding to one carbon atom were obtained.In the presence of Lewis acid,indole could undergo the solid state condensation reaction with aromatic ketones and aldehydes or quinones.The solid state reaction showed higher selectivity and yield than solution reaction The structures of products were identified by IR,1H NMR,MS,elemental analysis and X-ray crystal analysis.The reaction mechanism was also proposed. 相似文献
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芳香醛与3—甲基—1苯基—5—吡唑啉酮固相缩合反应的研究 总被引:7,自引:0,他引:7
研究了芳香醛与3-甲基-1-苯基-5-吡唑啉酮在室温固相、熔融状态及Lewis酸催化下的缩合反应,分别得到4,4'-甲太-双(3-甲基-1-苯基-5-吡唑啉酮)2-4-芳甲太-3-甲基-1-苯基-5-吡唑啉1.实验表明,在固体状态下,2主要以烯醇式存在,受势时或在溶液中两者可相互转化。 相似文献