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Hexahydrobenzo[b]furan-3-one(3) and hexahydro-1H-3-indolone (4) are potentially useful intermediates for total synthesis of natural products, such as the hexahydrobenzofuran unit (5) of avermectins and pancracine (6). Anionic cyclization approach toward (3) and (4) have been developed. Their application to the total synthesis of (5) and (6) will be presented. 相似文献
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