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溶剂气浮法去除水中腐殖酸的动力学和热力学初步研究 总被引:5,自引:1,他引:4
研究了溶剂气浮法去除水中的腐殖酸,该技术可以作为生物处理后的填埋渗出液的后处理方法。腐殖酸通过与表面活性剂十六烷基三甲基溴化铵生成离子缔合物气浮进入有机溶剂异戊醇而从水中去除。大于计量比的表面活性剂的量在10 m in之内可达92%的去除率。气浮速率在一定程序上随着气流速率的增加而增加,基本上与有机溶剂的体积无关。同时,还考察了电解质、乙醇及溶液的pH值对水中腐殖酸的溶剂气浮过程的影响。研究表明,该溶剂气浮过程遵从一级动力学。气浮过程的表观活化能作为一个特征参数被提出来,其值为2.87 kJ/mol。 相似文献
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The title compound(C26H18N4O4) has been synthesized via a three-component reaction and it was characterized by means of IR and 1H NMR.Its crystal and molecular structures were determined by X-ray diffractometry.It belongs to the triclinic system,space group P1 with a = 7.7288(15),b = 11.168(2),c = 12.645(3) ,α = 107.02(3),β = 90.85(3),γ = 101.93(3)°,V = 1017.9(3) 3,Mr = 450.44,Z = 2,Dc = 1.470 g/cm3,λ = 1.54178 ,μ = 0.836 mm-1,F(000) = 468,the final R = 0.0488 and wR = 0.1180.A total of 11903 reflections were collected,of which 3642 were independent(Rint = 0.0377) and 3025 were observed with I > 2σ(I). 相似文献