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Er~(3 ),Ho~(3 )和Tm~(3 )在硫氧化钆中的余辉发光 总被引:4,自引:0,他引:4
非放射性长余辉磷光粉作为美化和清洁光源在发光陶瓷、交通安全标志、紧急突发事件的照明设施、工艺美术涂料等众多领域得到越来越广泛的应用,引起人们的重视.到目前为止,文献报道的稀土长余辉磷光体的激活离子主要有铕离子(Eu3+和Eu2+[1-4]、三价铈离子(Ce3+)[5]、三价铽离子(Tb3+)[6]、三价镨离子(Pr3+)[7]、三价钐离子(Sm3+)[8].Ho3+,Er3+,Tm3+等稀土离子作为红外上转换发光材料的激活离子[9~12],而关于它们的长余辉发光的报道极少.最近,雷炳富等在Tm3+离子[13]激活的硫氧化钇体系中发现了长余辉发光.在此,我们通过高温固相法合成了Er3+,Ho3+和Tm3+掺杂的硫氧化钆长余辉磷光粉,观察到该体系中迄今未见文献报道的Er3+,Ho3+和Tm3+离子的长余辉发光. 相似文献
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沉淀法合成纳米晶长余辉材料Y2O2S∶Eu3+,Ti 总被引:2,自引:0,他引:2
The long-lasting phosphorescent materials, yttrium oxysulfides doped by Eu and Ti, were systhesized by coprecipitation with their subsequent thermal decomposition in the presence of sulphur. The products were characterized by XRD, TEM, phosphorescent spectra, and thermoluminescence. The XRD results indicate that the lowest synthesis temperature is 700 ℃. From the TEM, the average diameter of particles was in the range of 60~120 nm, and augmented with the increase of temperature. The materials under UV excitation presented well afterglow from the transition of 5D0,1 → 7FJ of Eu3+, and the persistent time was about 2 h. The long-lasting afterglow mechanism was discussed, too. 相似文献
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Er3+,Ho3+和Tm3+在硫氧化钆中的余辉发光 总被引:1,自引:0,他引:1
The new Er^3 , Ho^3 and Tm^3 doped gadolinium oxysulfide phosphors with the long afterglow emission were synthesized by solid-state reaction method. The synthesized phosphors were characterized by X-ray diffraction. The excitation and photolumineseenee spectra, afterglow spectra and afterglow decay curve were examined by fluorescence spectroscopy. The afterglow spectra of Gd2O2S:Er^3 , Mg, Ti showed typical transitions of Er^3 at 528(2H11/2→4I15/2), 548 (^4S3/2 →^4I15/2) and 669 nm (^4F9/2→^4I15/2). In the afterglow spectra of Gd2O2S: Ho^3 , Mg, Ti,typical transitions of Ho^3 at 546 nm (^5S2→^5I8), 651 and 661 nm (^2F5→^5I8) were observed. In Gd2O2S:Tm^3 , Mg,Ti, the afterglow emission at 800 nm (^1G4→^3H5) of Tm^3 was seen. The meehnism and model of afterglow energy transfer were proposed. 相似文献
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A novel 40-Gb/s constant envelope optical frequency shift keying (FSK) transmitter and the transmission characteristics are investigated both by simulation and experiment. Meanwhile, to increase the spectrum efficiency of FSK, we propose a novel optical minimum-shift keying (MSK) scheme and analyze its per-formance compared with other MSK schemes and other traditional modulation formats. Simulation and experimental results show that the novel FSK scheme could be a potential candidate for the future high speed transmission and label switching systems. And the novel MSK scheme deserves future deep research for its potential excellent performance. 相似文献
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为了在保持帧结构完整性的同时,低代价地传输管理和控制信号,提出面向高速频分复用相干无源光网络(FDM-CPON)的两种传输管理和控制信号传输机制,即数字端辅助管理和控制通道(AMCC)和数据通道的相加和相乘。通过将AMCC传输的通断键控(OOK)信号映射为数据通道信号幅值的变化,完成数据通道信号幅值再调制,成功将AMCC与数据通道相结合,实现了管理和控制信号与数据通道信号的同步传输。实验结果表明,在基于16QAM传输20 km光纤的200 Gbit/s FDM-CPON系统中,当AMCC的带宽和调制因子(MI)相同时,乘性AMCC对于信号性能的影响更小,自身传输信号的质量也更高。在AMCC的MI为26.1%、带宽为24.4 MHz时,乘性AMCC对信号灵敏度的惩罚比加性AMCC小3 dB。以上研究为未来高速相干频分复用无源光网络AMCC传输与系统设计提供重要参考。 相似文献
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相干且频率锁定的正交多载波光源产生技术在光通信领域有着诸多应用,能广泛用于微波光子学、全光信号处理以及波分复用(WDM)技术和正交频分复用(OFDM)技术.互联网数据业务的快速增长使得超宽带大容量骨干网传输技术越来越受到世界各国的重视,而要实现Tb/s超大容量传输,目前使用的最主要的方法是光的波分复用(WDM)或正交频分复用(OFDM)技术.作为实现光WDM或OFDM的一项关键技术,相干和频率锁定的正交多波长光源技术引起了国内外各大科研机构的强烈关注.介绍了国内外多载波技术的现状以及多载波产生的多种方案,并对每一个方案进行了对比分析,为未来的研究提供了一些参考. 相似文献
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The generation of coherent optical subcarriers based on a concatenated dual-drive Mach-Zehnder intensity modulator(IM) and two phase modulators(PMs) is proposed and experimentally demonstrated.The modulation index and DC bias of PM+IM modulation are theoretically investigated.Theoretical analysis and numerical study are also carried out to examine the proposed scheme.We use 25-GHz RF synchronous sinusoidal signals to drive cascaded two-stage PMs and IM,through which we generate 28 subcarriers with peak power fluctuations less than 4 dB.The measured tone-to-noise ratio of the subcarrier is higher than 40 dB.The experimental results show that for 100-Gb/s polarization multiplexing QPSK signal,the receiver sensitivity of the back-to-back signal is -28.6 dBm,and the power penalty is lower than 1 dB after 100-km transmission at the BER of 1×10-9. 相似文献