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确定主环是命名复杂桥环化合物的难点所在。我们介绍一种"剪断最短桥,显露最大环"的方法,可以帮助学生快速准确地确定最大环的位置,从而对复杂桥环化合物命名。 相似文献
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Strain and interfacial engineering to accelerate hydrogen evolution reaction of two-dimensional phosphorus carbide 下载免费PDF全文
Hydrogen,regarded as a promising energy carrier to alleviate the current energy crisis,can be generated from hydrogen evolution reaction(HER),whereas its efficiency is impeded by the activity of catalysts.Herein,effective strategies,such as strain and interfacial engineering,are imposed to tune the catalysis performance of novel two-dimensional(2D)phosphorus carbide(PC)layers using first-principle calculations.The findings show that P site in pristine monolayer PC(ML-PC)exhibits higher HER performance than C site.Intriguingly,constructing bilayer PC sheet(BL-PC)can change the coordinate configuration of P atom to form 3-coordination-P atom(3-co-P)and 4-coordination-P atom(4-co-P),and the original activity of 3-co-P site is higher than the 4-co-P site.When an external compressive strain is applied,the activity of the 4-co-P site is enhanced whereas the external strain can barely affect that of 3-co-P site.Interestingly,the graphene substrate enhances the overall activity of the BL-PC because the graphene substrate optimizes the?GH*value of 4-co-P site,although it can barely affect the HER activity of 3-co-P site and ML-PC.The desirable properties render 2 D PC-based material promising candidates for HER catalysts and shed light on the wide utilization in electrocatalysis. 相似文献
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IntroductionInrecentyears,agreatdealofattentionhasbeendirectedtowardsfullcoupledthermo_hydro_mechanicalanalysisindeformingporousmediaduetoextractionofundergroundfluids(water,petroleum ,naturalgas)inreservoir,environmentandconstructionengineering (Lewisan… 相似文献
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Mechanism analysis and improved model for stick-slip friction behavior considering stress distribution variation of interface 下载免费PDF全文
Jingyu Han 《中国物理 B》2022,31(3):34601-034601
Studying the evolution of interface contact state, revealing the "black box" behavior in interface friction and establishing a more accurate friction model are of great significance to improve the prediction accuracy of mechanical system performance. Based on the principle of total reflection, a visual analysis technology of interface contact behavior is proposed. Considering the dynamic variation of stress distribution in interface contact, we analyze the nonlinear characteristics of contact parameters in different stages of stick-slip process using the above-mentioned experimental technology. Then, we find that the tangential stiffness of the interface is not a fixed value during the stick-slip process and the stress distribution variation is one of the important factors affecting the tangential stiffness of interface. Based on the previous experimental results, we present an improved stick-slip friction model, considering the change of tangential stiffness and friction coefficient caused by the stress distribution variation. This improved model can characterize the variation characteristics of contact parameters in different stages of stick-slip process, whose simulation results are in good agreement with the experimental data. This research may be valuable for improving the prediction accuracy of mechanical system performance. 相似文献
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