A Novel Three—dimensional Framework with Tunnels Based on the Cobalt—containing Molybdenum Phosphate Moieties

IntroductionThedesignandsynthesisoforganic inorganichybridma terialsareofgreatinterestinmaterialscienceowingtotheirextensiveapplicationsincatalysis ,sorptionandelectricalconductivity.1 4 Exploitationofhydrothermaltechniquesanduseoforganicstructure directingagentshavebeenprovedfruitfulmethodsintheproductionoforganic inorganichybridmaterials.5,6 Metaloxideclustersbasedonanionicmolybde numphosphatesareoneofexcellentsubfieldswithabundantstructures.Itiswellknownthatmolybdenumphosphatesathydrotherma…     

还原态WO_3/Al_2O_3,NiO/Al_2O_3和NiO-WO_3/Al_2O_3催化剂上H_2,CO,O_2的吸附特性

在加氢精制和许多其它催化过程中,Mo,W是主要的活性组分,Co,Ni通常作为助剂,有关Co-Mo体系的研究文献报导很多~[1.2], 但由于钨较难还原和硫化,关于     

基于甲胺客体调制的混价态甲酸铁框架的构筑与磁电行为研究

N-型亚铁磁体可以在场冷时呈现负磁化行为,但在1 T强场场冷时依然能够保持负磁化行为的化合物却很罕见.本工作以CH3NH3+为客体阳离子,成功构筑了一例红砷镍矿(49.66)(412.63)结构的混价态甲酸铁化合物[CH3NH3]n[FeIIIFeII(HCO2)6]n (1),在1 T强场下呈现负磁化行为. 1中甲酸根采用反,反模式连接FeII和FeIII形成三维阴离子框架,八面体配位构型的FeII和FeIII分别处于(49.66)和(412.63)节点,而CH3NH3+则填充在框架空隙中平衡电荷.量热、介电和单晶X-射线衍射测试结果表明, 1中存在由CH3NH3+无序-有序转变诱导的结构相变并伴随介电弛豫.磁性研究表明FeII和FeIII之间存在较强的反铁磁耦合,但在冷却过程中FeII和FeIII构成的亚晶格磁有序程度存在较大差异,且具有较小自旋的FeII磁矩先于FeIII磁矩有序且平行于外加磁场,导致温度进一步降低时1呈现出负磁化行为,这表明1是一例罕见的N-型亚铁磁体.此外, 1在1 T外加冷却场中依然能保持负磁化行为,表明1中存在较强的磁各向异性.值得注意的是,在100 Oe...     

Hydrothermal Synthesis and Properties of Open-Framework Mixed-valence Iron Phosphates IIIII21.543FeFe(PO) with Three-dimensional Structure

Introduction The metal phosphates have attracted much attention because of their potential applications in catalysis, sorp-tion, and magnetic properties.1-5 A large number of metal phosphates6-10 with 1-D chain, 2-D layer and 3-D open-framework have been synthesized under mild hydrothermal conditions in the presence of organic amines. Chiral open-framework phosphates have been synthesized in the presence of chiral metal complexes and chiral structure-directing agents.11-15 In the past years,…     

稀土-荧光素双重荧光响应pH探针分子的合成与荧光性质研究

将含有8-氨基喹啉与荧光素衍生物缩合的席夫碱QZ1与铕髥的TTA(噻吩基三氟乙酰丙酮)化合物作为基本原料合成了新的铕髥-荧光素化合物Eu-QZ1,并对其进行了光谱表征。化合物Eu-QZ1在470 nm光的激发下产生荧光素的特征绿色荧光(530 nm)。在从碱到酸(pH从9.0到6.0)滴定过程中该荧光的强度增强了接近5倍,其pKa值计算为7.30。在370 nm光的激发下,Eu-QZ1发射稀土铕髥离子的特征红色荧光(主峰位于612 nm)。在从酸到碱(pH从5.5到8.5)滴定过程中,该荧光的强度增强了接近10倍,其pKa值计算为7.39。这些结果表明Eu-QZ1是1个高灵敏度双荧光响应的pH探针。细胞试验表明Eu-QZ1具有良好的细胞通透性,能够在红光和绿光两个位置标记海拉细胞中的pH范围。