弹性体共混改性聚丙烯的增韧机理

阐述了以聚丙烯（ＰＰ）／高密度聚乙烯（ＨＤＰＥ）为复合基体，苯乙烯－丁二烯－苯乙烯（ＳＢＳ）为增韧剂经三元共混所得的性能优异的一类新材料．从三个层次（形貌结构转变、宏观力学响应和裂尖过程区演化）系统地探讨了其增韧机理．结果表明由形貌结构控制和对早期体膨胀变形抑制可造成裂尖平面应变区的超钝化从而达到增韧．     

裂尖超钝化:实验、理论与数值模拟

本文报道了在改性聚丙烯裂尖平面应变段发生超钝化的实验发现。利用环向冷拉模型,可说明裂尖超钝化的形成取决于冷拉传播速率与加载率之比。裂尖超钝化可使材料韧性,尤其是冲击韧性的改善,达到一个新的水平。本文在超弹性-粘塑性各向异性损伤的有限变形本构模型下进行了详尽的数值计算。模拟结果成功地再现了裂尖超钝化的基本特征。     

EPOXY RESIN TOUGHENED BY THERMOPLASTICS

Two kinds of tough ductile heatresisting thermoplastic, namely bisphenol A polysulfone (PSF) and polyethersulfone (PES) were used to toughen thermoset epoxy resin. A systematic study on the relationship between the molecular weight and the terminal group of the thermoplastic modifier and the fracture toughness of the modified resin was carried out. The morphology of PSF modified epoxy resin was surveyed. With the same kind of PSF the structure of the epoxy resin and the toughening effect of PSF was also investigated. The fractography of PSF, particle modified epoxy was examined in detail with SEM. The contribution of every possible energy absorption process has been discussed. Crack pinning mechanism seems to be the most important toughening mechanism for tough ductile thermoplastic PSF particle modified epoxy system.