Diterpenes based on the dolabellane skeleton from dictyota dichotoma

From a variety of Dictyota dichotoma we have isolated, in addition to previously reported dolabellane (6-8) and perhydroazulene diterpenes (9,10), four new diterpenoids (2-5). Their structure have been elucidated by spectral analysis and chemical degradation. All the new dolabellane derivatives possess antimicrobial activity against gram-positive and gram-negative organisms.     

Grafting amount and structural characteristics of microcrystalline cellulose functionalized with different aminosilane contents

Cellulose - Microcrystalline cellulose (MCC) has unique properties and its use as reinforcement for polymer composites has been increasing. However, the intrinsic incompatibility with most polymers...     

Outer product analysis of electronic nose and visible spectra: application to the measurement of peach fruit characteristics

Visual aspect and aroma are among the most important features of fruit that determine consumer preferences. Electronic nose and spectroscopic techniques have shown positive results in evaluating some basic analytical parameters of fruit and global features such as the cultivar.In this paper, we illustrate and discuss a study aimed at evaluating the improvement derived by the fusion of visible spectra and electronic nose data. These experiments were performed on a population of yellow peaches belonging to two cultivars. Each sample was measured by visible optical spectroscopy and by electronic nose. In addition, a number of reference parameters were also measured by conventional destructive methodologies.Collected data were analysed individually and then fused together in order to classify the two cultivars and to estimate the reference parameters. Data fusion was performed building the outer product matrix for each measurement. The set of matrices was then successively unfolded and analysed by conventional chemometrics tools.Results were improved using outer products, for instance in classification average percentage errors of 25, 10, and 7 for electronic nose, spectra, and outer product, respectively was achieved. Regression analysis provides the evidence of a substantial orthogonal appearance of the datasets, which offer former hidden information on fruit classification.     

Integrable model for interacting electrons in metallic grains.

We find an integrable generalization of the BCS model with nonuniform Coulomb and pairing interaction. The Hamiltonian is integrable by construction since it is a functional of commuting operators; these operators, which therefore are constants of motion of the model, contain the anisotropic Gaudin Hamiltonians. The exact solution is obtained diagonalizing them by means of Bethe ansatz. Uniform pairing and Coulomb interaction are obtained as the "isotropic limit" of the Gaudin Hamiltonians. We discuss possible applications of this model to a single grain and to a system of few interacting grains.     

Halo-carbonyl complexes of palladium,platinum and gold

In this review we summarize some recent literature data concerning synthetic procedures, properties, structure, reactivity and applications of halo-carbonyl complexes of palladium, platinum and gold, taking into consideration that the organometallic chemistry of these metals, with a particular attention to the halo-carbonyls, has been reviewed 20 years ago [F. Calderazzo, J. Organomet. Chem. 400 (1990) 303]. A brief overview of the early studies is provided.     

Storage impulsive processes in the merging phase space

The storage impulsive processes given by a sum of random variables on a superposition of two renewal processes are considered on increasing time intervals. The averaging, diffusion approximation, and large deviation problem are studied in the series scheme with a small parameter series under suitable scaling.     

Natural Pseudo-Distance and Optimal Matching between Reduced Size Functions

This paper studies the properties of a new lower bound for the natural pseudo-distance. The natural pseudo-distance is a dissimilarity measure between shapes, where a shape is viewed as a topological space endowed with a real-valued continuous function. Measuring dissimilarity amounts to minimizing the change in the functions due to the application of homeomorphisms between topological spaces, with respect to the L _∞-norm. In order to obtain the lower bound, a suitable metric between size functions, called matching distance, is introduced. It compares size functions by solving an optimal matching problem between countable point sets. The matching distance is shown to be resistant to perturbations, implying that it is always smaller than the natural pseudo-distance. We also prove that the lower bound so obtained is sharp and cannot be improved by any other distance between size functions.