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排序方式： 共有115条查询结果，搜索用时 15 毫秒
1.
Pei Chen Xi Su Chuanzhe Wang Dr. Guang Zhang Dr. Ting Zhang Prof. Gang Xu Prof. Long Chen 《Angewandte Chemie (International ed. in English)》2023,62(40):e202306224
The emergence of two-dimensional conjugated metal–organic frameworks (2D c-MOFs) with pronounced electrical properties (e.g., high conductivity) has provided a novel platform for efficient energy storage, sensing, and electrocatalysis. Nevertheless, the limited availability of suitable ligands restricts the number of available types of 2D c-MOFs, especially those with large pore apertures and high surface areas are rare. Herein, we develop two new 2D c-MOFs (HIOTP-M, M=Ni, Cu) employing a large p-π conjugated ligand of hexaamino-triphenyleno[2,3-b:6,7-b′:10,11-b′′]tris[1,4]benzodioxin (HAOTP). Among the reported 2D c-MOFs, HIOTP-Ni exhibits the largest pore size of 3.3 nm and one of the highest surface areas (up to 1300 m2 g−1). As an exemplary application, HIOTP-Ni has been used as a chemiresistive sensing material and displays high selective response (405 %) and a rapid response (1.69 min) towards 10 ppm NO2 gas. This work demonstrates significant correlation linking the pore aperture of 2D c-MOFs to their sensing performance. 相似文献
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On this paper, we investigate the algorithm and efficiency of simulation of optical devices using parallel computing method, implement some real wavelength division multiplexing (WDM) components such as resonators to test the method's possibility and efficiency. 相似文献
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In this study,the three dimensional nanoscale organization in the photoactive layers of poly(3-hexylthiophene) (P3HT) and a methanofullerene derivative (PCBM) is revealed by transmission electron tomography.After annealing treatment,either at elevated temperature or during slow solvent evaporation,nanoscale interpenetrating networks are formed with high crystalline order and favorable concentration gradients of both components through the thickness of the photoactive layer.Such a tailored morphology acco... 相似文献
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为了满足航天器桌面散态匹配试验测试需求,研制一种基于PC104总线的执行机构等效装置,详细阐述了等效装置的功能、工作原理、硬件电路设计、软件设计思想,该系统采用模块化、可配置软件架构设计,实现了正常、应急多测试工况一体化设计;应用严格的窗口比较器硬件电路设计技术,实现信号电压幅值的高精度采集,确保输入信号的可靠判定;利用FPGA技术突破信号脉宽高精度采集和信号延时高精度可控等关键技术,该系统实现了输入信号幅值、脉宽的实时采集、存储与显示,并按照事先设定的工作模式及配置参数,完成不同测试工况下输出信号的模拟反馈。试验结果表明,系统稳定可靠,人机界面友好,满足航天器多测试工况控制时序和功能检查需求。 相似文献
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超导量子干涉器件(Superconducting Quantum Interference Device,简称SQUID)是一种高灵敏度的矢量磁探测器.本文采用低温超导SQUID作为传感器,搭建了一套三轴矢量磁场稳定装置.该系统由两个三轴SQUID磁强计模块、比例积分微分(PID)控制器和反馈线圈组组成.在该系统的矢量稳场下,磁场波动峰峰值在有效带宽内可以降低四个数量级,可达pT量级,稳场效果显著.此技术可以满足大部分需要稳定磁场,如高灵敏度磁传感器的标定等应用场合. 相似文献
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Dr. Heng Xu Dr. Guanxing Xu Dr. Bingji Huang Dr. Jiabiao Yan Dr. Min Wang Prof. Lisong Chen Prof. Jianlin Shi 《Angewandte Chemie (International ed. in English)》2023,62(20):e202218603
Electricity generation and chemical productions are both critically important for the sustainable development of modern civilization. Here, a novel bifunctional Zn-organic battery has been established for the concurrent enhanced electricity output and semi-hydrogenations of a series of biomass aldehyderivatives, for the high value-added chemical syntheses. Among them, the typical Zn-furfural (FF) battery equipped with Cu foil-supported edge-enriched Cu nanosheets as cathodic electrocatalyst (Cu NS/Cu foil), provides a maximum current density and power density of 14.6 mA cm−2 and 2.00 mW cm−2, respectively, and in the meantime, produces high value product, furfural alcohol (FAL). The Cu NS/Cu foil catalyst exhibits excellent electrocatalytic performance of ≈93.5 % conversion ratio and ≈93.1 % selectivity for FF semi-hydrogenation at a low potential of -1.1 V vs. Ag/AgCl by using H2O as H source, and shows impressive performance for various biomass aldehyderivatives semi-hydrogenation. 相似文献
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The synthesis of 14-epi-19-nor-22-oxa-1α,25(OH)2D3 5 was started from diol 8 via Fall's method, oxidation, epimerization, protection, coupling with the 19-nor-A-ring 7, and then deprotection of the hydroxyl functions. 相似文献
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