首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   136144篇
  免费   11108篇
  国内免费   8932篇
化学   47900篇
晶体学   2014篇
力学   6348篇
综合类   1719篇
数学   42226篇
物理学   55977篇
  2023年   627篇
  2022年   849篇
  2021年   2343篇
  2020年   1972篇
  2019年   2276篇
  2018年   2045篇
  2017年   1966篇
  2016年   2096篇
  2015年   1876篇
  2014年   3307篇
  2013年   5637篇
  2012年   3725篇
  2011年   4544篇
  2010年   4955篇
  2009年   10106篇
  2008年   11135篇
  2007年   9762篇
  2006年   8608篇
  2005年   6219篇
  2004年   5940篇
  2003年   5860篇
  2002年   8880篇
  2001年   5438篇
  2000年   4915篇
  1999年   4584篇
  1998年   3958篇
  1997年   2989篇
  1996年   2756篇
  1995年   3021篇
  1994年   2922篇
  1993年   2327篇
  1992年   1861篇
  1991年   1377篇
  1990年   1140篇
  1989年   988篇
  1988年   956篇
  1987年   757篇
  1986年   508篇
  1985年   1375篇
  1984年   976篇
  1983年   695篇
  1982年   1006篇
  1981年   1149篇
  1980年   1021篇
  1979年   929篇
  1978年   830篇
  1977年   694篇
  1976年   654篇
  1974年   397篇
  1973年   533篇
排序方式: 共有10000条查询结果,搜索用时 52 毫秒
1.
郑凌玲 《化学教育》2022,43(10):100-106
深挖高职院校公选课“生活中的化学”的育人元素,精心设计教学内容,运用课堂主题辩论、趣味生活实验的设计与展示、探秘生活中的化学等理论知识传授与课内外实践相结合的教学方式,实现全过程育人,充分展现了公选课在立德树人方面的价值。  相似文献   
2.
In this paper we consider minimizers of the functionalmin{λ1(Ω)++λk(Ω)+Λ|Ω|,:ΩD open} where DRd is a bounded open set and where 0<λ1(Ω)λk(Ω) are the first k eigenvalues on Ω of an operator in divergence form with Dirichlet boundary condition and with Hölder continuous coefficients. We prove that the optimal sets Ω have finite perimeter and that their free boundary ΩD is composed of a regular part, which is locally the graph of a C1,α-regular function, and a singular part, which is empty if d<d, discrete if d=d and of Hausdorff dimension at most dd if d>d, for some d{5,6,7}.  相似文献   
3.
4.
CRANAD-2 is a fluorogenic curcumin derivative used for near-infrared detection and imaging in vivo of amyloid aggregates, which are involved in neurodegenerative diseases. We explore the performance of CRANAD-2 in two super-resolution imaging techniques, namely stimulated emission depletion (STED) and single-molecule localization microscopy (SMLM), with markedly different fluorophore requirements. By conveniently adapting the concentration of CRANAD-2, which transiently binds to amyloid fibrils, we show that it performs well in both techniques, achieving a resolution in the range of 45–55 nm. Correlation of SMLM with atomic force microscopy (AFM) validates the resolution of fine features in the reconstructed super-resolved image. The good performance and versatility of CRANAD-2 provides a powerful tool for near-infrared nanoscopic imaging of amyloids in vitro and in vivo.  相似文献   
5.
6.
Far-red emitting fluorescent labels are highly desirable for spectral multiplexing and deep tissue imaging. Here, we describe the generation of frFAST (far-red Fluorescence Activating and absorption Shifting Tag), a 14-kDa monomeric protein that forms a bright far-red fluorescent assembly with (4-hydroxy-3-methoxy-phenyl)allylidene rhodanine (HPAR-3OM). As HPAR-3OM is essentially non-fluorescent in solution and in cells, frFAST can be imaged with high contrast in presence of free HPAR-3OM, which allowed the rapid and efficient imaging of frFAST fusions in live cells, zebrafish embryo/larvae, and chicken embryos. Beyond enabling the genetic encoding of far-red fluorescence, frFAST allowed the design of a far-red chemogenetic reporter of protein–protein interactions, demonstrating its great potential for the design of innovative far-red emitting biosensors.  相似文献   
7.
In this work, a vanillin complex is immobilized onto MCM-41 and characterized by FT-IR, X-ray diffraction, scanning electron microscopy, energy dispersive spectroscopy, thermogravimetric analysis, and BET techniques. This supported Schiff base complex was found to be an efficient and recoverable catalyst for the chemoselective oxidation of sulfides into sulfoxides and thiols into their corresponding disulfides (using hydrogen peroxide as a green oxidant) and also a suitable catalyst for the preparation of 2,3-dihydroquinazolin-4(1H)-one derivatives in water at 90°C. Using this protocol, we show that a variety of disulfides, sulfoxides, and 2,3-dihydroquinazolin-4(1H)-one derivatives can be synthesized in green conditions. The catalyst can be recovered and recycled for further reactions without appreciable loss of catalytic performance.  相似文献   
8.
9.
We consider concentrated vorticities for the Euler equation on a smooth domain Ω?R2 in the form of
ω=j=1NωjχΩj,|Ωj|=πrj2,Ωjωjdμ=μj0,
supported on well-separated vortical domains Ωj, j=1,,N, of small diameters O(rj). A conformal mapping framework is set up to study this free boundary problem with Ωj being part of unknowns. For any given vorticities μ1,,μN and small r1,,rNR+, through a perturbation approach, we obtain such piecewise constant steady vortex patches as well as piecewise smooth Lipschitz steady vorticities, both concentrated near non-degenerate critical configurations of the Kirchhoff–Routh Hamiltonian function. When vortex patch evolution is considered as the boundary dynamics of ?Ωj, through an invariant subspace decomposition, it is also proved that the spectral/linear stability of such steady vortex patches is largely determined by that of the 2N-dimensional linearized point vortex dynamics, while the motion is highly oscillatory in the 2N-codim directions corresponding to the vortical domain shapes.  相似文献   
10.
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号