全文获取类型
收费全文 | 16140篇 |
免费 | 1067篇 |
国内免费 | 885篇 |
专业分类
化学 | 4827篇 |
晶体学 | 70篇 |
力学 | 1011篇 |
综合类 | 136篇 |
数学 | 8116篇 |
物理学 | 3932篇 |
出版年
2024年 | 148篇 |
2023年 | 236篇 |
2022年 | 389篇 |
2021年 | 452篇 |
2020年 | 565篇 |
2019年 | 504篇 |
2018年 | 480篇 |
2017年 | 548篇 |
2016年 | 537篇 |
2015年 | 433篇 |
2014年 | 788篇 |
2013年 | 1569篇 |
2012年 | 1030篇 |
2011年 | 857篇 |
2010年 | 707篇 |
2009年 | 981篇 |
2008年 | 1064篇 |
2007年 | 908篇 |
2006年 | 768篇 |
2005年 | 718篇 |
2004年 | 544篇 |
2003年 | 451篇 |
2002年 | 453篇 |
2001年 | 299篇 |
2000年 | 318篇 |
1999年 | 330篇 |
1998年 | 322篇 |
1997年 | 257篇 |
1996年 | 206篇 |
1995年 | 143篇 |
1994年 | 139篇 |
1993年 | 115篇 |
1992年 | 104篇 |
1991年 | 48篇 |
1990年 | 50篇 |
1989年 | 48篇 |
1988年 | 47篇 |
1987年 | 38篇 |
1986年 | 35篇 |
1985年 | 72篇 |
1984年 | 82篇 |
1983年 | 30篇 |
1982年 | 52篇 |
1981年 | 45篇 |
1980年 | 27篇 |
1979年 | 56篇 |
1978年 | 31篇 |
1977年 | 15篇 |
1976年 | 14篇 |
1973年 | 10篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
1.
《Expositiones Mathematicae》2022,40(4):910-919
This paper proves such a new Hilbert’s Nullstellensatz for analytic trigonometric polynomials that if are analytic trigonometric polynomials without common zero in the finite complex plane then there are analytic trigonometric polynomials obeying in , thereby not only strengthening Helmer’s Principal Ideal Theorem for entire functions, but also finding an intrinsic path from Hilbert’s Nullstellensatz for analytic polynomials to Pythagoras’ Identity on . 相似文献
2.
A kinetic model which describes Ostwald's rule of stages, during the process of crystal growth from solution, is reported here. Reaction equations for stages are given where the stages convert from one to another. The final stage reacts to release a portion of solute back into solution, while the remainder converts to the final equilibrium form. Additionally, a remnant of the solute that was not consumed by any of the transitional stages, ultimately is converted into the final product. This particular model was motivated by a recent report for Boc-diphenylalanine self-assembly where the dissolved peptide was observed to go through two polymorphic stages before reaching the equilibrium supramolecular assembly [A. Levin et al., Nat. Commun. 5, 5219, (2014)]. Kinetic data for the concentration of solute present during the process are listed in the above-mentioned report. We show here how the model, for , describes the time-dependent behavior of the solute decay during the growth process. After comparing the model to the experimental data, we are able to report values for all of the rate constants and propose a rule whereby the relative magnitudes of these constants can be used to predict whether a supersaturated substance will noticeably pass through transitional stages or simply convert from solute to the equilibrium solid form. 相似文献
3.
4.
The present work describes an exciting method for the selective and sensitive determination of calcitonin in human blood serum samples. Adopting the surface molecular imprinting technique, a calcitonin-imprinted polymer was prepared on the surface of the zinc oxide nanostructure. Firstly, a biocompatible tyrosine derivative as a monomer was grafted onto the surface of zinc oxide nanostructure followed by their polymerization on vinyl functionalized electrode surface by activator regenerated by electron transfer–atom transfer radical polymerization (ARGET–ATRP) technique. Such sensor can predict the small change in the concentration of calcitonin in the human body and it may also consider to be as cost-effective, renewable, disposable, and reliable for clinical studies having no such cross-reactivity and matrix effect from real samples. The morphologies and properties of the proposed sensor were characterized by scanning electron microscopy, cyclic voltammetry, difference pulse voltammetry and chronocoulometry. The linear working range was found to be 9.99 ng L−1 to 7.919 mg L−1 and the detection limit as low as 3.09 ± 0.01 ng L−1 (standard deviation for three replicate measurements) (S/N = 3). 相似文献
5.
Aluminum is one of the most toxic metals causing a variety of neurologic diseases, especially Alzheimer's disease. It is impossible to avoid contact with aluminum because of its existence in food to medications. Therefore, removal of aluminum from the blood or wastewater is urgently important. The cost-effective and easy-to-prepare adsorbents are needed to get efficient aluminum removal. For that purpose, the poly(2-hydroxyethylmethacrylate-co-acrylic acid), poly(HEMA-co-AA), microparticles was synthesized to remove aluminum in a very short interaction time. The achievement of the desired polymeric structure was confirmed via Fourier transform infrared spectroscopy (FTIR), scanning electron microscope (SEM) and transmission electron microscope (TEM), etc. Additionally, particle features such as swelling ratio, size, and surface area were determined. The microparticles synthesized in this study have been determined with very good adsorption capacity even in small aluminum concentrations. 相似文献
6.
S. Sathiyaraj Mahalingam Vanjinathan G. Libni K. Subalakshmi J. Senthil Selvan 《高分子科学杂志,A辑:纯化学与应用化学》2017,54(12):978-985
Hyperbranched poly(aryl-ether-urea)s with phenyl, N,N-dimethylamino ethyl and polyethylene oxide end-groups linked through urethane group – HBPEU-1, HBPEU-2 and HBPEU-3 respectively – were synthesized from an AB2-type blocked isocyanate monomer and characterized by FT-IR, 1H-NMR, SEC-MALLS, TGA and DSC techniques. The molecular weight of the polymers were found to be ranged from 4.9 × 103 ? 1.96 × 104 g/mol. The TGA results showed that the polymers decompose between 175°C – 220°C. In the DSC curves, HBPEU-1 and HBPEU-3 showed Tg at 160°C and 53°C respectively, whereas HBPEU-2 did not showed clear Tg. All the three polymers were converted into polymer electrolytes by doping with LiI/I2. The doped polymers showed remarkably high ionic conductivity, up to 222 – 277 times compared to the un-doped polymers and the highest conductivity was observed with doped HBPEU-2. The TiO2 based dye-sensitized solar cells (DSSCs) were fabricated using the doped polymer electrolytes and their performance was tested; HBPEU-2 showed good performance by yielding energy conversion efficiency (η) of 4.5%. 相似文献
7.
As alternative to the usual assumptions of Boussinesq, we propose, for heated gases, a new approximation called polytropic approximation. With this approximation the quantities of corresponding state are related by a polytropic law of exponent χ of which we neglect the variability in space-time derivations in the equations governing the flow considered. As application, we used this new proposition to solve numerically a heated gas flow in an annular cavity of rotor-stator type. We expose here the numerical method and some results of the polytropic approximation with comparison to results of Boussinesq approximations. To cite this article: S. Benjeddou et al., C. R. Mecanique 332 (2003). 相似文献
8.
In static and dynamic analysis of a large complex structure, one may merely be interested in the stresses and displacements
at some important locations. A new solution technique for structural analysis with FEM is proposed in this paper by which
those important unknowns are separated from the rest. In static analysis the important unknows can be found directly. In dynamic
analysis all mass and exciting forces can be condensed onto a small number of predetermined points in order to make the dynamic
analysis much simplified. A large scale problem can be solved with a small capacity computer quickly. 相似文献
9.
The fundamental assumption of the paper is that the extra stress tensor of an electrorheological fluid is an isotropic tensor valued function of the rate of strain tensor D and the vector n (which characterizes the orientation
and length N of the fibers formed by application of an electric field). The resulting constitutive equation for is supplemented by the solution of the previously studied time evolution equation for n. Plastic behavior for the shear and normal stresses is predicted. Anticipating that the action of increasing shear rate
is i) to orient the fibers more and more in the direction of flow and ii) simultaneously to break up the fibers leads to the conclusion that for
the same behavior is encountered as without an electric field. Using realistically possible approximation formulas for the dependence of
and N on
leads to the Bingham behavior for
and power law behavior for large shear rates.
相似文献
Basim Abu-JdayilEmail: |
10.
Christophe Felder Constantin Oltean Mikhail Panfilov Michel Buès 《Comptes Rendus Mecanique》2004,332(3):223-229
The investigation of non-reactive miscible solute dispersion in a vertical Hele–Shaw cell is considered. An asymptotic method is used to extend Taylor model to the case of the fluid density, the dynamic viscosity and the molecular diffusion coefficient are solute concentration-dependent. It is demonstrated that the averaged variables over the gap are governed by a convection–dispersion equation in which the dispersion tensor is concentration-dependent. To cite this article: C. Felder et al., C. R. Mecanique 332 (2004). 相似文献