Environmental impact assessment using the evidential reasoning approach

Environmental impact assessment (EIA) problems are often characterised by a large number of identified environmental factors that are qualitative in nature and can only be assessed on the basis of human judgments, which inevitably involve various types of uncertainties such as ignorance and fuzziness. So, EIA problems need to be modelled and analysed using methods that can handle uncertainties. The evidential reasoning (ER) approach provides such a modelling framework and analysis method. In this paper the ER approach will be applied to conduct EIA analysis for the first time. The environmental impact consequences are characterized by a set of assessment grades that are assumed to be collectively exhaustive and mutually exclusive. All assessment information, quantitative or qualitative, complete or incomplete, and precise or imprecise, is modelled using a unified framework of a belief structure. The original ER approach with a recursive ER algorithm will be introduced and a new analytical ER algorithm will be investigated which provides a means for using the ER approach in decision situations where an explicit ER aggregation function is needed such as in optimisation problems. The ER approach will be used to aggregate multiple environmental factors, resulting in an aggregated distributed assessment for each alternative policy. A numerical example and its modified version are studied to illustrate the detailed implementation process of the ER approach and demonstrate its potential applications in EIA.     

Lasting chemiluminescence of 3-indoleglyoxylyl chloride and its enhancement.

The chemiluminescence (CL) intensities of various indole derivatives substituted with a glyoxylyl group at the 3-position and a hydroxyl group at the 5-position of the indole ring were compared upon the addition of H2O2 in alkaline media. The CL intensities of 3-indoleglyoxylyl chloride, 3-indoleglyoxylic acid, 5-hydroxyindole and 5-benzyloxyindole in CH3CN were 5.9-, 48-, 5.9- and 3.3-fold stronger than that of 3-methylindole. A lasting CL of 3-indoleglyoxylyl chloride was found. Under appropriate conditions, the CL emission reached a maximum within 10 min after the addition of H2O2 in the presence of NaOH, and the intensity was retained for 25 min. One of the final products via the CL reaction of 3-indoleglyoxylyl chloride was indole-3-carboxylic acid. 3-Indoleglyoxylyl chloride emitted light by decompositions via both dioxetane and dioxetanedione. An enhancement effect of beta-cyclodextrin and bovine serum albumin on the CL of 3-indoleglyoxylyl chloride was also found.     

Mathematical modelling of the oxidation of nickel titanium alloys

A one-dimensional bulk reaction model for the oxidation of nickeltitanium is formulated, with preferential oxidation of titaniumbeing included. The modelling is directed at the better understandingof the dominant mechanisms involved in the oxidation processand their significance for the biocompatibility of the alloy.Two different regimes for the relative diffusivities of oxygenand the metals are investigated. By assuming fast bulk reactions,different asymptotic structures emerge in different parameterregimes and the resulting models take the form of moving boundaryproblems. Different profiles of nickel concentration are obtained:in particular a nickel-rich layer (observed in practice) ispresent below the oxide/metal interface for the case when oxygenand the metals diffuse at comparable rates.     

Investigation into the ROMP copolymerization of peptide‐ and PEG‐functionalized norbornene derivatives

The ring‐opening metathesis polymerizations (ROMP), using RuCl₂ (PCy₃)₂CHPh, of a series of peptide‐functionalized norbornene derivatives have been investigated. Incorporation of a PEG‐monomer was found to prevent premature precipitation of polymer strands during the course of polymerization reactions and yield water compatible polymers in high conversions. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 3178–3190, 2007     

Optical Tunnelling from One-Dimensional Square-Well Potentials

The authors study a one-dimensional model for optical tunnellingwith a refractive index in the shape of a square well. The relevanceof the model and its limiting cases are discussed. The mainresult is the leading behaviour of the exponentially small imaginarypart of the eigenvalue which determines the radiation loss.The leading behaviour of the imaginary part is calculated usingBerry's formula which controls the asymptotic expansion of theAiry function Bi(z) to better-than-exponential accuracy.     

Differential geometry and morphology of graphitic carbon materials

The topological defects (pentagons and heptagons) in a hexagonal graphitic network give rise to a non-zero curvature in the three-dimensional structure formed by the network. The curvature is quantized due to the hexagonal symmetry of graphite. We clarify how the topological defects affect the graphitic carbon morphology, invoking the knowledge of differential geometry.     

Fully-developed pipe and planar flows of multimode viscoelastic fluids

Two solutions are presented for fully-developed pipe and planar flows of multimode viscoelastic models. The fluids have a Newtonian solvent contribution and the polymer modes are described by the Phan-Thien—Tanner (PTT), the FENE-P or the Giesekus equation. The first solution is exact and can handle any number of modes, but is only semi-analytical. The second solution, which is presented only for the PTT model with a linear stress coefficient and the FENE-P model, can also handle any number of modes. It is based on a truncated series expansion and is completely analytical, but provides only an approximated solution. The complexity of the multimode solutions is investigated first with the exact semi-analytical method and it is shown that at high Deborah number flows the high-order stresses can become as important as the stress of the first mode. It is also under these conditions that the approximated analytical solution deviates from the exact semi-analytical solution. A criterion for the accurate use of the approximated solution is presented. Fortran codes are provided to obtain these solutions at the internet address at the end.