排序方式： 共有25条查询结果，搜索用时 15 毫秒
1.
《Journal of organometallic chemistry》2002,641(1-2):15-25
Dimetal tetracarboxylates, M2(O2CR)4, where R=alkyl and M=Mo or W, can be linked in a perpendicular or parallel manner through the agency of a variety of ligands to give ‘dimers of dimers’ [M2(O2CR)3]2(bridge), or extended chains. A ring of formula [M2(O2CR)2(bridge)]4 is an alternative to a chain [M2(O2CR)3]2(bridge)2]∞ and ‘molecular squares’ of formula [(RNCHNR)2M2(bridge)]4 have recently been reported by Cotton and Murillo, where M=Mo and Rh and R=p-MeOC6H4. The electronic coupling between the M2 units manifests itself in electrochemical data and in the electronic spectra of the compounds. The electronic coupling occurs by M2δ to ligand π-conjugation and specific examples are illustrated for the bridging ligands oxalate, perfluoroteraphthalate, 1,8-anthracenedicarboxylate and 2,7-dioxynaphthyridine. Correlations of a variety of spectroscopic data and computations employing density functional theory are presented. 相似文献
2.
Iridium oxide supported on Vulcan XC-72 carbon black (IrO2/C) as a cathode catalyst for polymer electrolyte fuel cell (PEFC) has been characterized by transmission electron microscopy (TEM) and X-ray diffraction (XRD) measurement. The IrO2 particles were 8-160 nm in diameter. The oxygen electroreduction activity was studied by cyclic voltammetry (CV). It was found that IrO2/C had high oxygen reduction reaction (ORR) activity. The performance of the membrane electrode assemble (MEA) was also tested in a single PEFC and showed that IrO2/C catalyst would be potential candidates for use as cathode catalyst in PEFC. 相似文献
3.
Yuichi Tominaga Takuya Kubo Kenji Sueyoshi Ken Hosoya Koji Otsuka 《Journal of polymer science. Part A, Polymer chemistry》2013,51(15):3153-3158
To synthesize the novel molecular‐ and pH‐stimulus‐responsive hydrogel, we prepared poly(ethylene glycol)‐based hydrogel containing ionic groups. We evaluated the fundamental swelling/shrinking properties of the hydrogels synthesized by various conditions. Decreasing the molecular weight of a crosslinker provided the increasing of the equilibrium swelling ratio. Also, the equilibrium swelling ratio was changed by the introduction of functional ionic monomers and its compositions. Furthermore, the swelling/shrinking behaviors of the hydrogels were affected by the environmental condition of aqueous solution, in fact the hydrogels were considerably shrunk (to one‐fifth volume) using a di‐ionic solute in the aqueous solution through the ionic interactions between the hydrogel and the solutes. Additionally, the specific shrinking to diamine compounds was also observed in response to pH change. These results clearly show the swelling/shrinking responsibility of the hydrogels toward the molecular recognitions and its pH conditions. © 2013 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2013, 51, 3153–3158 相似文献
4.
A cumulative damage theory is presented for multilevel cyclic loading. Both the crack initiation and propagation stages are included in this method. The criterion is based on the concept of the total strain energy density as a damage parameter. The effect of the mean stress/strain on the damage accumulation is also included in this formulation. It is shown that a number of earlier proposed models can be derived as a particular case of the present criterion. The predicted results are compared with the experimental data of two, three, five and six steps cyclic loading histories. A good agreement is noted between the predicted and experimental results. 相似文献
5.
The traction force of a tracked unmanned ground vehicle (UGV) depends on the soil thrust generated by the shearing action on the soil-track interface. In the development of soil thrust, because the continuous-track system consists of a number of single-track systems connected to each other, interference occurs between the adjacent single-track systems through the surrounding soil. Thus, the total soil thrust of the continuous-track system is not equal to the sum of the soil thrust of each single-track system, and the interference effect needs to be carefully considered. In this study, model track tests were conducted on model single-, double-, and triple-track systems according to relative density of soil and shape ratio (i.e., the length of the track plate to grouser depth). The test results indicated that the interference effect reduced soil thrust due to the overlapping shear zones between adjoining single-track systems. The loss of soil thrust increased as the relative density of the soil increased and the shape ratio decreased. Based on these findings, a soil thrust multiplier that can be utilized to assess the soil thrust of a continuous-track system was developed. 相似文献
6.
The cone index (CI), as an indicator of the soil strength, is closely related to the traction performance of tractors. This study evaluates the traction performance of a tractor in terms of the CI during tillage. To analyze the traction performance, a field site was selected and divided into grids, and the CI values at each grid were measured. The CI maps of the field sites were created using the measured CI. The traction performance was analyzed using the measured traction load. The traction performance was grouped at CI intervals of 400 kPa to classify it in terms of the CI. When the CI decreased, the engine speed and tractive efficiency (TE) decreased, while the engine torque, slip ratio, axle torque, traction force, and dynamic traction ratio (DTR) increased. Moreover, the DTR increased up to approximately 13%, and the TE decreased up to 9%. The maximum TE in the DTR range of 0.45–0.55 was higher than approximately 80% for CI values above 1500 kPa. The DTR and TE results obtained in terms of the CI can help efficiently design tractors considering the soil environmental conditions. 相似文献
7.
Brahim Aïssa Zéhira Hamoudi Hiro Takahashi Kazuyuki Tohji Mohamed Mohamedi My Ali El Khakani 《Electrochemistry communications》2009,11(4):862-866
We report the first direct laser based synthesis of carbon nanohorns onto carbon microfibrous, for the straightforward fabrication, of free-standing (binderless) electrodes. These carbon nanohorns have diameters as small as 2–4 nm and were found to cover uniformly the microfibrous substrates. The carbon nanohorns-based electrodes developed here are shown to open new prospects for the development of advanced electrochemical power sources. In particular, their possible applications in either lithium-ion batteries or supercapacitors or fuel cell technologies are demonstrated. 相似文献
8.
9.
10.