Development of a modified beta-cyclodextrin based fluorosensor for dipyridamole

2,6-O-diethyl-β-cyclodextrins were prepared and immobilized onto silica gel to develop a fluorosensor for dipyridamole. The analytical performance characteristics of the proposed sensor for analysis of dipyridamole were as follows: the detection limit was 0.8 nmol/L with a relative standard deviation of 1.4% for 10 determinations of 50 nmol/L of dipyridamole. The modification of β-CD improved the sensitivity and selectivity for measuring dipyridamole. The recommended method has been successfully tested for the determination of dipyridamole in clinical samples (urine and pharmaceutical preparations). Received: 23 January 1997 / Revised: 14 April 1997 / Accepted: 21 April 1997     

Influence of extended π-conjugation units on carrier mobilities in conducting polymers

Carrier mobilities in thin films of copolymers with repeat units consisting of oligothiophenes bridged by Si atoms are measured over a range of doping levels, where the numbers of thienylenes in the repeat unit are 7, 8, 10, 12, and 14. The mobilities for these polymer films increased with the increase in doping level and the mobility enhancement followed an increasing order of the π-conjugation length. The magnitude of the mobility increase for the Si polymer comprising 14 thiophene units reached ca. 10⁴, implying that this π-conjugation length is almost sufficient to reproduce transport properties of polythiophenes.     

Sparse representation-based classification algorithm for optical Tibetan character recognition

A sparse representation-based two-phase classification algorithm is proposed for off-line handwritten Tibetan character recognition. The first phase realizes coarse classification with the K-NN classifier by finding the K nearest neighbours of a test sample in the dictionary constructed by K-SVD with samples of all classes, and the classes of these neighbours are regarded as the candidate classes of the test sample. The second phase performs fine classification with the sparse representation classifier by sparsely representing the test sample with all elements of the dictionary constructed by K-SVD with samples of all candidate classes, and the test sample is finally classified into the candidate class with the maximal contribution in sparse representation. Experiments on the Tibetan off-line handwritten character database show that an optimal recognition rate of 97.17% has been reached and it is 2.12% higher than that of K-NN.     

Discussion again of the magnetic and transport property of Ag-doped LaMnO3

Samples La_1−aAg_aMnO₃ (0.05?a?0.50) were sol–gel fabricated. A part of Ag was found to dissociate and run off the samples in sintering process when sintering temperature exceeds 700 °C, resulting in a composite of La_1−xAg_xMnO₃ and MnO₂/Mn₂O₃. The magnetic and transport properties of the composite have been studied. The sample with the nominal composition La_0.7Ag_0.3MnO₃ was found to show the greatest magnetoresistance in the sample group. Detailed analysis on average Mn valence reveals a composite of (La_0.985Ag_0.015MnO₃)_0.776[(MnO₂)_0.590(Mn₂O₃)_0.410]_0.224. Its MR ratio at room temperature exceeds 24% under a field of 1.8 T. A conductivity leap has been observed around a=0.30. It suggests a kind of field-induced fluctuation in percolation in the samples investigated.     

Measurements of decays into and

Based on a sample of 5.8×10⁷ J/ψ events taken with the BESII detector, the branching fractions of J/ψ→2(π⁺π⁻)η and J/ψ→3(π⁺π⁻)η are measured for the first time to be (2.26±0.08±0.27)×10⁻³ and (7.24±0.96±1.11)×10⁻⁴, respectively.     

Coherent electron transport in a helical nanotube

The quantum dynamics of carriers bound to helical tube surfaces is investigated in a thin-layer quantization scheme. By numerically solving the open-boundary Schrödinger equation in curvilinear coordinates, geometric effect on the coherent transmission spectra is analysed in the case of single propagating mode as well as multimode. It is shown that, the coiling endows the helical nanotube with different transport properties from a bent cylindrical surface. Fano resonance appears as a purely geometric effect in the conductance, the corresponding energy of quasibound state is obviously influenced by the torsion and length of the nanotube. We also find new plateaus in the conductance. The transport of double-degenerate mode in this geometry is reminiscent of the Zeeman coupling between the magnetic field and spin angular momentum in quasi-one-dimensional structure.     

High-bandwidth and low-loss photonic crystal power-splitter with parallel output based on the integration of Y-junction and waveguide bends

A 1×2 power-splitter with parallel output that exhibits high-bandwidth and low-loss splitting for TE-polarized light is designed based on a photonic crystal slab in a silicon-on-insulator (SOI) material. The high performance is achieved by the integration of a Y-junction and 60° waveguide bends, which is designed to ensure single-mode operation, and keep the output channels of the power-splitter be parallel to the input channel. With a three-dimensional finite-difference time-domain (3D-FDTD) technique, ultralow-loss output of the optimized power-splitter with normalized transmission above 45% (in the range 3.216±0.18 dB) is obtained in the high-bandwidth range 1472–1634 nm, which covers the entire C-band of optical communication. In addition, the simulation results demonstrate that when the manufacture error of the lattice shift (dx) is in the range of ±10 nm, the disturbance of the transmission and the bandwidth are 1.52% and 6.79%, respectively. Both the specific result and the general idea of integration design are promising in the optical integrated circuit (OIC) and integrated optical devices in the future.     

Real-time surface profile measurement using a feedback type of sinusoidal phase modulating interferometer

In this paper, we propose a sinusoidal phase modulating (SPM) interferometer that is insensitive to external disturbances, and its measuring principle is analyzed theoretically. In the SPM interferometer, the interference signal is detected by a high-speed image sensor based on a low-speed CCD and a signal processing circuit is used to obtain the phase of each point on the surface. Therefore, the surface profile can be measured real-time. The experiments measuring the surface profile of a wedge-shaped optical flat show that the measurement time of the SPM interferometer is less than 10 ms, the repetitive measurement accuracy is 4.2 nm. The results show that the impacts of nonlinear distortion of the piezoelectric transducer (PZT) and part external disturbance are removed.     

Surface-enhanced Raman scattering effect of gold nanoparticle arrays: The influence of annealing temperature,excitation power and array thickness

Gold nanoparticle arrays are fabricated for surface-enhanced Raman scattering (SERS) and the effect of the annealing temperature, the thickness of nanoparticle array and the exciting power on the SERS signals are investigated. The particle distribution and particle size are dense and uniform on the glass substrate when the 10 nm gold film was annealed at 250 °C and strong SERS signals for Rhodamine 6G were achieved via a 532 nm excitation with a 10 mW power. The SERS signal at 1650 cm⁻¹ is enhanced more than 10 times as compared to that of the gold film without annealing. The strong SERS behavior of gold nanoparticle arrays may broaden the SERS applications in biomedical and analytical chemistry.