左消半群M与幂单半群B的Schǔzenberger积

本文讨论了每个元都有幂等元作为右单位元的左消半群与幂单半群N的Schuzenberger积M◇N的ρ类，证明了这种半群M与N的Schuzenberger积M◇N的ρ类是右E一半适合半群和弱E-headged半群．     

Raman and infrared studies of NaLa(MoO4)2:Nd3+

The polarized Raman and i.r. (powder) spectra of 0.5 mole % neodymium doped NaLa(MoO₄)₂ have been analysed on the basis of C_4h crystal symmetry. Group theoretically predicted fundamentals have been observed. The frequencies and intensities are not altered due to doping.     

Influence du cuivre sur la substitution des énolates stables par divers halogénures allyliques

The allylic substitution, by a variety of allylic halides, of stable enolates derived from diethyl malonate, ethyl cyanoacetate, ethyl acetoacetate and acetylacetone has been investigated. The yields and regioselectivity of these reactions are strongly influenced by cuprous ions (and their ligands).     

Regioselective electroreduction of 6h-1,3-thiazines. Comparison with chemical reductions I - investigation of 2-phenyl-6H-1,3-thiazines

The electrochemical reduction of 2-phenyl-6H-1,3-thiazines carried out at a mercury cathode in acetate buffer + ethanol (1:1) has been studied : - In the case of compounds monoactivated at carbon 5 (R⁵ = CHO or COCH₃) either hydrodimers (resulting from coupling at C-2), 3,6-dihydro-2H-1,3-thiazines (reduction of the imine bond) or tetrahydrothiazines can be obtained. - Diactivated 6H-1,3- thiazines (R⁴ = CO₂Et, R⁵ = CHO or COCH₃) successively lead to 5,6-dihydro-4H-1,3-thiazines (reduction of the ethylenic bond) and tetrahydrothiazines. - The reduction of a 6H-1,3-thiazine bearing only one withdrawing group at carbon 4 gives rise to a ring opening. At the same time, the action of various chemical reducing agents has been examined : the reduction of the imine bond is performed using NaBH₃CN while NaBH₄ or LiAlH₄ leads to the reduction of the substituents on the heterocyole.     

2+1维de-Sitter时空中光线的轨迹

通过求解2+1维de-Sitter时空中零测地线方程得到光线的轨迹方程,对轨迹方程进行分析发现其不存在封闭的轨迹解.     

Comparison of shear banding in BMGs due to thermal-softening and free volume creation

This paper reports a comparative study of shear banding in BMGs resulting from thermal softening and free volume creation. Firstly, the effects of thermal softening and free volume creation on shear instability are discussed. It is known that thermal softening governs thermal shear banding, hence it is essentially energy related. However, compound free volume creation is the key factor to the other instability, though void-induced softening seems to be the counterpart of thermal softening. So, the driving force for shear instability owing to free volume creation is very different from the thermally assisted one. In particular, long wave perturbations are always unstable owing to compound free volume creation. Therefore, the shear instability resulting from coupled compound free volume creation and thermal softening may start more like that due to free volume creation. Also, the compound free volume creation implies a specific and intrinsic characteristic growth time of shear instability. Finally, the mature shear band width is governed by the corresponding diffusions (thermal or void diffusion) within the band. As a rough guide, the dimensionless numbers: Thermal softening related number B, Deborah number (denoting the relation of instability growth rate owing to compound free volume and loading time) and Lewis number (denoting the competition of different diffusions) show us their relative importance of thermal softening and free volume creation in shear banding. All these results are of particular significance in understanding the mechanism of shear banding in bulk metallic glasses (BMGs). Supported by the Chinese Academy of Sciences under the project “Multi-Scale Complex System” (Grant No. KJCX-SW-L08), the National Natural Science Foundation of China (Grant Nos. 10725211 and 10721202), and the Doctorial Start-up Fund of Hunan University of Science and Technology (Grant No. E50840)     

Growth and micromagnetic simulation of magnetite nanoparticles

Magnetite nanoparticles with different sizes and different assemblies were synthesized via hydrothermal method.Micromagnetic simulation shows the magnetite nanocubes with different sizes have different energy states,which determines the assembly mode.Magnetite nanocubes with the side length of 30-60 nm tended to be dispersed while both nanochains and dispersed nanoparticles were found to grow for the nanocubes with the side length less than 30 nm,which can be explained in the fact that the above two assembl...     

光栅减反层太阳能电池光电转换效率的研究

运用时域有限差分方法,研究了光栅减反层结构对太阳能电池光电转换效率及储能效果的影响.具体从光栅形状、高度以及光栅表面金属薄膜厚度出发.结果表明经光栅减反层优化表面结构的太阳能电池的光电转换效率显著增大,储能效果大大得到提升.尤其是三角形光栅太阳能电池.随着镀层厚度的增加,储能效果增加,但当薄膜厚度过厚时,储能效果反而降低.     

新型氨基甲酸含氮杂环甲基酯的合成及生物活性研究

常规加热或微波照射下, 含氮杂环1与多聚甲醛反应以良好的产率生成含氮杂环基甲醇3, 反应物物质的量的比、反应温度等对反应产率有影响, 微波条件下的反应时间比常规加热下大大缩短. 化合物3和异氰酸酯4在常规加热或微波照射下生成相应的氨基甲酸含氮杂环甲基酯5a～5m. 反应温度、反应物物质的量的比、反应时间、微波辐射功率等对反应产率都有一定的影响, 与常规加热相比微波条件下的反应时间大大缩短. 化合物5的结构经过IR, ¹H NMR, MS, 元素分析测定, 部分化合物经过¹³C NMR测定. 测定了化合物5的杀虫和除草活性, 结果表明其杀虫活性较低, 除草活性高于杀虫活性, 5a, 5d, 5e和5m对苋菜和黄瓜的防除率高达100%.     

单轴荷载下饱水岩石静态和动态抗压强度的细观力学分析

由于单轴荷载下饱水岩石的动态力学特性与静态力学特性存在很大差异,从宏观上进行力学分析存在局限性。根据岩石受压全应力应变曲线的细观机制,分析了静态及动态单轴荷载条件下孔隙水影响饱水岩石裂纹扩展的情况。在静态单轴压缩条件下,初始裂隙受压使自由水产生孔隙水压力,自由水对翼裂纹有向外挤压的应力,促进裂纹扩展。在动态单轴压缩条件下,自由水会产生粘结力,抑制裂纹扩展。根据翼裂纹受压扩展原理,推导出饱水单轴条件下动态抗压强度、静态抗压强度的计算公式,在相同断裂韧度下,饱水岩石静态抗压强度风干岩石静态抗压强度饱水岩石动态抗压强度。对自然风干和饱水砂岩进行单轴静态、动态压缩实验,结果与理论模型的结果相符。