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1.
    
《中国化学快报》2023,34(6):107893
Rational regulation of stable graphitic carbon nitride (CN) for superior peroxymonosulfate (PMS) activation is important in the catalytic degradation of water contaminants. In this work, the copper oxide and oxygen co-doped graphitic carbon nitride (CuO/O-CN) was prepared via one-step synthesis and applied in activating PMS for oxytetracycline (OTC) degradation, displaying superior catalytic performance. Systematic characterization and theoretical calculations indicated that the synergistic effect between the oxygen site of CN and CuO can modulate the electronic structure of the whole composite further facilitating the formation of non-radical 1O2 and various reactive radicals. Results of the influencing factor experiments revealed that CuO/O-CN has a strong resistance to the environmental impact. The degradation efficiency of OTC in the real water environment even exceeded that in the deionized water. After four successive runs of the optimal catalyst, the OTC removal rate was still as high as 91.3%. This work developed a high-efficiency PMS activator to remove refractory pollutants via both radical pathway and non-radical pathway, which showed a promising potential in the treatment of wastewaters.  相似文献   
2.
We consider the existence of multiple positive solutions of the singular boundary value problem for the Sturm-Liouville equation with impulses on the half line. By applying the fixed-point index theorem of a cone map, existence and multiplicity results about positive solutions are obtained. Our results improve and generalize some well-known results. An example is presented to demonstrate applications of our main results.  相似文献   
3.

In this paper, we investigate the modified function projective lag synchronization for two different stochastic chaotic systems using adaptive control method. We design an adaptive controller to make the mean square of synchronization error convergence to an arbitrarily small bound around zero depending on the controller feedback gain according to the Lyapunov stability theory. One example is presented to demonstrate the effectiveness of the proposed controller.

  相似文献   
4.
根据区域产业分工理论,运用区位商测定区域专业化程度.然后,基于复杂系统结构熵理论,从产业在区际和区内聚集分布信息出发,融合行业路径和地区路径分析法于一体,提出并证明了可以用区位结构熵全面衡量产业在空间上的分布状况.在此基础上,构建一维区域分工指数,综合测定区域分工水平.最后,以我国工业空间分布为例,例证了该方法是合理的、可行的,具有一定的推广和应用价值.  相似文献   
5.
对于不小于7素数p,设1≤k≤p-1,则使用同余方法可证明方程n=pkp-1d(n)无正整数解,从而pkp-1不是优美指数,进而可以肯定"存在无穷多个正整数不是优美指数".  相似文献   
6.
    
Efficient charge transfer and excellent surface water oxidation kinetics are key factors in determining the photoelectrochemical (PEC) water splitting performance in photoelectrodes. Herein, a bilayer TiO2/α-Fe2O3 nanorod (NR) arrays photoanode was prepared with deposited Cu-doped NiOx (Cu : NiOx) hole transport layer (HTL) and Co−Pi oxygen evolution reaction (OER) cocatalyst for PEC water oxidation. The hierarchical TiO2/α-Fe2O3 composite obtained by a secondary hydrothermal process exhibited an inapparent bilayer structure by embedding the underlayer TiO2 NR arrays at the bottom part of the post-grown α-Fe2O3 NR arrays. The underlayer TiO2 NRs acted as an effective shuttling pathway for transferring photoelectrons generated in the upper hematite light absorber layer. A p-type inter-Cu : NiOx HTL was introduced to form a build-in p–n electric field between Cu : NiOx and α-Fe2O3 NRs, which improved the hole extraction from α-Fe2O3 to Co−Pi OER catalyst. As expected, the as-engineered TiO2/α-Fe2O3/Cu : NiOx/Co−Pi photoanode displayed an excellent photocurrent density of 2.43 mA cm−2 at 1.23 V versus the reversible hydrogen electrode (VRHE), up to 4.05 and 2.23 times greater than those of the bare α-Fe2O3 (0.60 mA cm−2) and TiO2/α-Fe2O3, respectively. The results demonstrate that the bottom-up engineering of electron-hole transport channels and cocatalyst modification is an attractive maneuver to enhance the PEC water oxidation activity in hematite and other photoanodes.  相似文献   
7.
    
The shortcomings of poor charge transfer ability and slow surface water oxidation kinetics in the single component photoanode limit the performances of photocatalytic water splitting. Herein, a α-Fe2O3/rGO/NiFe-LDH composite photoanode was designed for enhancing photoelectrochemical (PEC) water oxidation activity. The rGO nanosheets serve as an efficient electron transfer mediator for promoting charge transport and separation. The NiFe-LDH is well anchored on rGO nanosheets and provides additional active sites for accelerating water oxidation reaction kinetics. By the virtue of synergistic effect between rGO and NiFe-LDH, the composite photoanode achieves a pronounced photocurrent density of 1.46 mA/cm2 at 1.23 VRHE (V vs. reversible hydrogen electrode), which is 2.86 times of α-Fe2O3. Moreover, the onset potential exhibits a significant cathodic shift of 230 mV. This work provides a valuable strategy for the design of photoanode with light absorber, rGO electron transfer mediator and other cocatalysts to achieve efficient and stable PEC water splitting.  相似文献   
8.
    
《Discrete Mathematics》2021,344(12):112598
We study the Ihara zeta function of the complement of a semiregular bipartite graph. A factorization formula for the Ihara zeta function is derived via which the number of spanning trees is computed. For a class of complements of semiregular bipartite graphs, it is shown that they have the same Ihara zeta function if and only if they are cospectral.  相似文献   
9.
An improved purification of the triplet Greenberger-Horne-Zeilinger (GHZ) state is demonstrated for the electron-spin-entangled state in the quantum-dot (QD) and micro-cavity coupled systems. In order to distill the maximally entangled GHZ state efficiently, we designate a deterministic entanglement purification protocol (EPP) by using a pair of the triplet-electron-spin-entangled systems. It is based on the elegant parity-check operations performed in the cavity-spin-coupling system with the assistance of an ancillary single photon. With the current and feasible technology, the maximally entangled GHZ states can be achieved as much as flexible for the long-distance quantum communications since only single-photon detection and single-electron detection are required in practice.  相似文献   
10.
炭纤维增强双基体炭/碳化硅(C/C-SiC)制动材料的性能   总被引:1,自引:1,他引:0  
李专  肖鹏  熊翔  朱苏华 《摩擦学学报》2010,30(3):273-278
以针刺炭纤维整体毡为预制体,采用呋喃树脂加压浸渍、加压固化和炭化制得密度为1.45g/cm3的多孔体C/C材料,然后熔融渗硅制得密度为2.37g/cm3的炭纤维增强双基体炭/碳化硅(C/C-SiC)材料.结果表明:熔融渗硅中反应生成的SiC基体主要分布在胎网层、针刺纤维附近以及无纬布层的纤维束间;C/C-SiC材料的弯曲强度为165MPa,垂直和平行于无纬布铺层方向的压缩强度分别为210和196MPa;C/C-SiC材料的摩擦性能稳定,平均动摩擦系数为0.38,静摩擦系数为0.40,和对偶件的线磨损率分别为5.3和3.7μm/(面.次),其磨损过程是由磨粒磨损、黏着磨损和氧化磨损共同作用的结果.  相似文献   
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