Electroluminescence of a Multi-Layered Organic Light-Emitting Diode Utilizing Trans-4-[p-[N-methyl-N-(hydroxymethyl)amino]styryl]-N-Methylphridinium Tetraphenylborate as the Active Layer

Employing an organic dye salt of trans-4-[p-[N-methyl-N-(hydroxymethyl)amino]styryl]-N-methylphridinium tetra\-phenylborate (ASPT) as the active layer, 8-hydrocyquinoline aluminium (Alq₃) as the electron transporting layer and N,N’-diphenyl-N,N’-bis(3-methylphenyl)-[1,1’-biphenyl]-4,4’-diamine (TPD) as the hole transporting layer, respectively, we fabricate a multi-layered organic light-emitting diode and observe the colour tunable electroluminescence (EL). The dependence of the EL spectra on the applied voltage is investigated in detail, and the recombination mechanism is discussed by considering the variation of the hole-electron recombination region.     

Prisoner＇s Dilemma Game with Heterogeneous Influential Effect on Regular Small-World Networks

The effect of heterogeneous influence of different individuals on the maintenance of co-operative behaviour is studied in an evolutionary Prisoner＇s Dilemma game with players located on the sites of regular small-world networks. The players interacting with their neighbours can either co-operate or defect and update their states by choosing one of the neighbours and adopting its strategy with a probability depending on the pay off difference. The selection of the neighbour obeys a preferential rule： the more influential a neighbour, the larger the probability it is picked. It is found that this simple preferential selection rule can promote continuously the co-operation of the whole population with the strengthening of the disorder of the underlying network.     

Microwave-Assisted Soluble Polymer-supported Synthesis of Peptoids

Libraries of peptide-like compounds are attractive sources of binding agents for proteomics applications. The synthesis of oligomeric combinatorial libraries of peptidomimetics is usually more straightforward than the creation of large libraries of more "drug-like" molecules. Herein we report synthesis of peptoids on soluble high loading Noncross-linked polystyrene. The synthesis route consists of: (a) preparation "soluble wang resin" from non-crosslinked polystyrene and 4-hydroxybenzyl alcohol via ether linkage, (b) an esterification step performed by the addition of bromoacetyl bromide to "soluble wang resin" and (c) a nucleophilic displacement of bromide with a primary amine.     

ELECTRON PARAMAGNETIC RESONANCE STUDIES OF SINGLE CRYSTAL SODIUM HEXAMOLYBDOCHROMATE (Ⅲ)Cr~(3+)/Na_3(AlMo_6O_(24)H_6)·8H_2O

An X-band EPR study on a Na_3(CrMo_6O_(24)H_6)·8H_2O single crystal diluted by its isomor-phic compound Na_3(AlMo_6O_(24)H_6)·8H_2O at room temperature is reported. Using the least squares-fitting method to simulate the EPR data for principal planes, the Hamiltonian parameterswere obtained. The principal values of the g tensors are g_(ZZ) = 1.904, g_(XX)= 1.973, g_(YY)=1.933. The zero field splitting tensor parameters are D = 0.275 cm~(-1), E = 0.05 cm~(-1). The fielddependence of Cr~(3+) energy levels with field at different angles from the principal axes whenthe field is along the principal planes is calculated based on these experimental parameters.The isofrequency plots of calculated field vs. angle are also shown. They agree well with theexperimental results.     

~(14)N ENDOR Study on Bis(2-Hydroxylphenyl Ketoxime)-~(63)Cu(Ⅱ) Complex

The ENDOR spectrum of ~(14)N-~(63)Cu-HAP complex in DMSO/EtOH (5:1) freezing solution at 20 K has been studied using orientational selective method in this paper. The anisotropic superhyperfine coupling tensor and qusdrupole coupling tensor of ligand ~(14)N nucleus, and the superhyperfine coupling tensor of various ~1H nuclei have been measured precisely. Comparing the superhyperfine coupling tensor of ~(14)N-nucleus with previous work shows that the analytical method of spectrum is reasonable and the data are reliable in our previous work.     

悬浮液进样-火焰原子吸收光谱法测定怀山药中铜

怀山药、怀地黄、怀牛膝、怀菊花合称"四大怀药",是享誉海内外的名贵中药材,其中怀山药作为药食同源的滋补佳品,近年来被作为食品原料和成品在市场广泛流通.作为食品,其中金属元素铜是必测项目.食品中铜的测定,普遍采用原子吸收光谱法,样品的预处理有干法(灰化)、湿法(加酸消化)及微波消化法,前两种方法消化时间长、操作环节多,被测元素丢失或被污染的机会多;后种方法溶样不完全,重现性易受影响.     

偏序集上的滤子极大理想

在偏序集上引入并考察了滤子极大理想的概念,证明了相应的存在性定理。引入并考察了伪极大元和伪既约元的概念,利用图表的形式对连续格中各种类型的既约元和素元之间的关系进行了归纳总结,完善了文献《Continuous Lattices and Domains》(作者:G.Gierz,et al)中的一个图表的相关内容,填补了在分配的连续格情形该图表的一个未知内容,部分地回答了该文献中的一个问题。     

桑蚕种良卵率调查中样本间卵粒数的偏差控制方法

桑蚕种良卵率是蚕种质量检验的重要指标,控制样本间卵粒数的偏差是保证良卵率准确性的关键。通过对桑蚕卵粒重的调查分析,得出其分布服从正态分布。若从一批蚕种中抽取1g卵作为样本,则来自同一总体的2个样本的卵粒数之差不超过16粒,其置信概率为95%;当置信概率取99%时,两个样本的卵粒数之差不超过21粒。文章为蚕业生产提供了一种实用的克卵粒数偏差控制方法。     

PVC/MBS/纳米 BaSO4 复合材料的制备及其性能

采用熔融共混法制备聚氯乙烯(PVC)/甲基丙烯酸甲酯-丁二烯-苯乙烯共聚物(MBS)/纳米重晶石(nano-BaSO4)三元复合材料,考察其力学性能和热稳定性能,并用扫描电镜观察冲击断面的形态.结果表明:MBS 与 nano-BaSO4 可协同增韧 PVC;当 MBS、nano-BaSO4 的含量分别为 10%、1%时,材料的韧性和刚性可同时得以改善,其冲击断面表现出典型的韧性断裂特征;热重分析显示添加 1%nano-BaSO4 可显著提高 PVC/MBS 的热稳定性能,其第一降解阶段的初始分解温度和最快分解温度分别提高了 10℃和14℃.     

STUDY ON PREPARATION OF UV CROSS-LINKING FILMS OF POLYURETHANE-LiClO4 COMPLEXES AND THEIR IONIC CONDUCTIVITY

The complexes of polyurethane containing double bonds with LiClO₄ were formed, and cross-linked films were produced by UV radiation, All of the films were uniform, transparent, flexible and smooth-faced with a considerable mechanical strength. The ionic conductivities of the films of several series of polymers with different molecule weights of PEG segment were measured, of which the highest is 8.09×10^-5S·cm^-1 at 300K under anhydrous atmosphere. Also the conductivity is deeply influenced by the molecule weight of the soft segment PEG of the polyurethane and the content of LiClO₄. The transport number of Li⁺ is about 0.57. Structure characteristic measurement much as DSC, XRD, IR etc., have been done and the conductive mechanism is discussed.