排序方式: 共有318条查询结果,搜索用时 15 毫秒
1.
采用液相合成法成功合成了一种新型的ZnCo金属有机骨架(MOF)纳米晶原位生长于NiMoO4纳米线(NWs)表面的复合材料NiMoO4 NWs@ZnCo MOF。经350 ℃低温热处理(所得产物命名为NiMoO4 NWs@ZnCo MOF(350))后,仍旧较好地保持了前驱体的结构和形貌,但在ZnCo MOF内部出现了极少量的Co3O4相,证明发生了轻微热解。化学键C—O—Mo和相异质界面处产生的大量氧空位可以成为活性位点的来源。新的Co3O4相的形成也导致异相界面的进一步增加。此外,少量的热解使核壳结构表面更加粗糙、疏松和多孔,产生更高的比表面积、更快的离子扩散路径和更好的导电性。因此经惰性玻碳电极测试,在10 mA·cm-2电流密度下电催化剂表现出360 mV的低过电位,并保持了30 000 s的长期催化稳定性。 相似文献
2.
A modified glassy carbon (GC) electrode was developed for the amperometric detection of biogenic amines, particularly histamine. The electrode was modified with the co‐enzyme pyrroloquinoline quinone (PQQ) by entrapment during electropolymerziation of pyrrole to form polypyrrole (PPy). This method formed a thin film on the electrode surface possessing very good stability with a shelf‐life exceeding one month without loss of signal. Optimal conditions for the PQQ/PPy electrode were determined and a linear response was found for histamine in phosphate buffer (pH 6) at +550 mV from 40 to 170 mg L?1 with a limit of detection (S/N≥3) of 38 mg L?1. The practical linear range offered by this method suggests ideal use for spoilage detection in fermented foods. 相似文献
3.
Two‐Dimensional Core‐Shelled Porous Hybrids as Highly Efficient Catalysts for the Oxygen Reduction Reaction
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Kai Yuan Dr. Xiaodong Zhuang Haiyan Fu Dr. Gunther Brunklaus Dr. Michael Forster Prof. Dr. Yiwang Chen Prof. Dr. Xinliang Feng Prof. Dr. Ullrich Scherf 《Angewandte Chemie (International ed. in English)》2016,55(24):6858-6863
Two‐dimensional (2D) transition‐metal dichalcogenides (TMDs) have drawn much attention due to their unique physical and chemical properties. Using TMDs as templates for the generation of 2D sandwich‐like materials with remarkable properties still remains a great challenge due to their poor solvent processability. Herein, MoS2‐coupled sandwich‐like conjugated microporous polymers (M‐CMPs) with high specific surface area were successfully developed by using functionalized MoS2 nanosheets as template. As‐prepared M‐CMPs were further used as precursors for preparation of MoS2‐embedded nitrogen‐doped porous carbon nanosheets, which were revealed as novel electrocatalysts for oxygen reduction reaction with mainly four‐electron transfer mechanism and ultralow half‐wave potential in comparison with commercial Pt/C catalyst. Our strategy to core–shelled sandwich‐like hybrids paves a way for a new class of 2D hybrids for energy conversion and storage. 相似文献
4.
Interface Engineering of MoS2/Ni3S2 Heterostructures for Highly Enhanced Electrochemical Overall‐Water‐Splitting Activity
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Dr. Jian Zhang Dr. Tao Wang Dr. Darius Pohl Dr. Bernd Rellinghaus Dr. Renhao Dong Dr. Shaohua Liu Dr. Xiaodong Zhuang Prof. Xinliang Feng 《Angewandte Chemie (International ed. in English)》2016,55(23):6702-6707
To achieve sustainable production of H2 fuel through water splitting, low‐cost electrocatalysts for the hydrogen‐evolution reaction (HER) and the oxygen‐evolution reaction (OER) are required to replace Pt and IrO2 catalysts. Herein, for the first time, we present the interface engineering of novel MoS2/Ni3S2 heterostructures, in which abundant interfaces are formed. For OER, such MoS2/Ni3S2 heterostructures show an extremely low overpotential of ca. 218 mV at 10 mA cm?2, which is superior to that of the state‐of‐the‐art OER electrocatalysts. Using MoS2/Ni3S2 heterostructures as bifunctional electrocatalysts, an alkali electrolyzer delivers a current density of 10 mA cm?2 at a very low cell voltage of ca. 1.56 V. In combination with DFT calculations, this study demonstrates that the constructed interfaces synergistically favor the chemisorption of hydrogen and oxygen‐containing intermediates, thus accelerating the overall electrochemical water splitting. 相似文献
5.
Theoretical Modelling and Facile Synthesis of a Highly Active Boron‐Doped Palladium Catalyst for the Oxygen Reduction Reaction
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Tat Thang Vo Doan Jingbo Wang Kee Chun Poon Desmond C. L. Tan Bahareh Khezri Prof. Richard D. Webster Prof. Haibin Su Prof. Hirotaka Sato 《Angewandte Chemie (International ed. in English)》2016,55(24):6842-6847
A highly active alternative to Pt electrocatalysts for the oxygen reduction reaction (ORR), which is the cathode‐electrode reaction of fuel cells, is sought for higher fuel‐cell performance. Our theoretical modelling reveals that B‐doped Pd (Pd‐B) weakens the absorption of ORR intermediates with nearly optimal binding energy by lowering the barrier associated with O2 dissociation, suggesting Pd‐B should be highly active for ORR. In fact, Pd‐B, facile synthesized by an electroless deposition process, exhibits 2.2 times and 8.8 times higher specific activity and 14 times and 35 times less costly than commercial pure Pd and Pt catalysts, respectively. Another computational result is that the surface core level of Pd is negatively shifted by B doping, as confirmed by XPS, and implies that filling the density of states related to the anti‐bonding of oxygen to Pd surfaces with excess electrons from B doping, weakens the O bonding to Pd and boosts the catalytic activity. 相似文献
6.
直接甲醇燃料电池作为未来清洁的动力能源,由于具有下列优点:操作温度低(<100℃)、燃料易储存和运输、能量效率高、污染低和燃料启动快而受到人们广泛的关注。阳极电催化剂是直接甲醇燃料电池最重要的组成部分。本文综述了近三年来直接甲醇燃料电池阳极电催化剂最新的研究进展,主要对催化剂制备方法、新型碳载体材料、催化剂类型作了详细的评述,展望了未来甲醇电催化氧化催化剂的发展,指出了电催化剂面临的问题。 相似文献
7.
Sebastian Wöllner Timothy Nowak Dr. Gui-Rong Zhang Dr. Nils Rockstroh Dr. Hanadi Ghanem Prof. Dr. Stefan Rosiwal Prof. Dr. Angelika Brückner Prof. Dr. Bastian J. M. Etzold 《ChemistryOpen》2021,10(5):600-606
Electrocatalytic oxidation of 5-hydroxymethylfurfural (HMF) offers a renewable approach to produce the value-added platform chemical 2,5-furandicarboxylic acid (FDCA). The key for the economic viability of this approach is to develop active and selective electrocatalysts. Nevertheless, a reliable catalyst evaluation protocol is still missing, leading to elusive conclusions on criteria for a high-performing catalyst. Herein, we demonstrate that besides the catalyst identity, secondary parameters such as materials of conductive substrates for the working electrode, concentration of the supporting electrolyte, and electrolyzer configurations have profound impact on the catalyst performance and thus need to be optimized before assessing the true activity of a catalyst. Moreover, we highlight the importance of those secondary parameters in suppressing side reactions, which has long been overlooked. The protocol is validated by evaluating the performance of free-standing Cu-foam, and CuCoO modified with NaPO2H2 and Ni, which were immobilized on boron-doped diamond (BDD) electrodes. Recommended practices and figure of merits in carefully evaluating the catalyst performance are proposed. 相似文献
8.
Research progress of Pt and Pt-based cathode electrocatalysts for proton-exchange membrane fuel cells
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Proton-exchange membrane fuel cells (PEMFCs) have been widely used commercially to solve the energy crisis and environmental pollution. The oxygen reduction reaction (ORR) at the cathode is the rate-determining step in PEMFCs. Platinum (Pt) catalysts are used to accelerate the ORR kinetics. Pt's scarcity, high cost, and instability in an acidic environment at high potentials seriously hinder the commercialization of PEMFCs. Therefore, studies should explore electrocatalysts with high catalytic activity, enhanced stability, and low-Pt loading. This review briefly introduces the research progress on Pt and Pt-based ORR electrocatalysts for PEMFCs, including anticorrosion catalyst supports, Pt, and Pt-based alloy electrocatalysts. Advanced preparation technology and material characterization of Pt-based ORR electrocatalysts are necessary to improve the performance and corresponding reaction mechanisms. 相似文献
9.
Liang‐Xin Ding Prof. Dr. Gao‐Ren Li Zi‐Long Wang Zhao‐Qing Liu Prof. Dr. Hong Liu Prof. Dr. Ye‐Xiang Tong 《Chemistry (Weinheim an der Bergstrasse, Germany)》2012,18(27):8386-8391
Bimetallic core‐shell nanostructures are emerging as more important materials than monometallic nanostructures, and have much more interesting potential applications in various fields, including catalysis and electronics. In this work, we demonstrate the facile synthesis of core‐shell nanotube array catalysts consisting of Pt thin layers as the shells and Ni nanotubes as the cores. The porous Ni@Pt core‐shell nanotube arrays were fabricated by ZnO nanorod‐array template‐assisted electrodeposition, and they represent a new class of nanostructures with a high electrochemically active surface area of 50.08 m2 (g Pt)?1, which is close to the value of 59.44 m2 (g Pt)?1 for commercial Pt/C catalysts. The porous Ni@Pt core‐shell nanotube arrays also show markedly enhanced electrocatalytic activity and stability for methanol oxidation compared with the commercial Pt/C catalysts. The attractive performances exhibited by these prepared porous Ni@Pt core‐shell nanotube arrays make them promising candidates as future high‐performance catalysts for methanol electrooxidation. The facile method described herein is suitable for large‐scale, low‐cost production, and significantly lowers the Pt loading, and thus, the cost of the catalysts. 相似文献
10.
Dr. Min‐Rui Gao Zhao‐Yang Lin Dr. Jun Jiang Dr. Chun‐Hua Cui Ya‐Rong Zheng Prof. Dr. Shu‐Hong Yu 《Chemistry (Weinheim an der Bergstrasse, Germany)》2012,18(27):8423-8429
We report a first solution strategy for controlled synthesis of Adams’ catalyst (i.e., α‐PtO2) by a facile and totally green approach using H2PtCl6 and water as reactants. The prepared α‐PtO2 nanocrystals (NCs) are ultrasmall in size and have very “clean” surfaces, which can be reduced to Pt NCs easily in ethanol under ambient conditions. Such Adams’ catalysts have been applied as electrocatalysts beyond the field of heterogeneous catalysis. Noticeably, the water‐only synthesized α‐PtO2 NCs and their derivative Pt NCs all exhibit much higher oxygen reduction reaction (ORR) activities and stabilities than that of the state‐of‐art Pt/C electrocatalysts. This study provides an example on the organics‐free synthesis of α‐PtO2 and Pt NCs as promising cathode catalysts for fuel cell applications and, particularly, this simple, straightforward method may open a new way for the synthesis of other “clean” functional nanomaterials. 相似文献