首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   11篇
  免费   0篇
化学   3篇
力学   1篇
数学   2篇
物理学   5篇
  2022年   1篇
  2021年   1篇
  2017年   1篇
  2013年   2篇
  2012年   2篇
  2004年   1篇
  2003年   1篇
  1995年   1篇
  1991年   1篇
排序方式: 共有11条查询结果,搜索用时 46 毫秒
1.
Kinetics and Catalysis - A new ruthenium(II) cage complex with polar terminal groups in the apical substituents has been synthesized; the molecular design of the complex contributes to the...  相似文献   
2.
The influence of process features in the fabrication of angle transducers (deviation from uniform distribution of mechanical stresses/strains over their transmitting/receiving surface) on the acoustic field of excited surface waves has been investigated. Calculation was carried out within the parabolic approximation by replacing a real angle transducer of surface waves with a linear source located on the surface of a waveguide (control object) with a nonuniform (cosine) distribution of stress amplitudes. The expressions for the stress (strains) at an arbitrary observation point for a point receiver (reflector) and for the stress averaged over the receiver plane are obtained in complex form. The coordinate dependences of the stress amplitudes and phases have been calculated for typical technological modes; the calculation results are presented as plots. It is shown that the effect of deviations from uniform distribution is strongest in the transition (from the near-to far-field) zone, where nonuniformity of displacements of 10–15% at the edges of a piezoelectric cell causes a change in their amplitude by 15–30% in comparison with uniform distribution; this must be taken into account when estimating diffraction corrections. The possibilities of experimentally verifying the degree of nonuniformity of the stress distribution over the angle-transducer surface are discussed.  相似文献   
3.
The effect of the viscosity of a fluid on the propagation of the zero mode of a horizontally polarized normal wave in a thin (compared to the wavelength) waveguide immersed in the fluid is studied. It is shown that, to a first approximation in the ratio of the shear impedance of the fluid to the shear impedance of the waveguide, the wave amplitude decays exponentially as a function of the distance at a damping coefficient proportional to the square root of the shear viscosity of the fluid. The decrease in the wave amplitude induced by the shear viscosity of the fluid is numerically estimated, and the results obtained point to the possibility of developing a method for its measurement at a high accuracy. This method was developed and tested on a waveguide in the form of an aluminum ribbon 0.3 mm thick and 14 cm long at a frequency of 2 MHz. The decrease in the signal amplitude when the waveguide is immersed in distilled water (tabulated shear viscosity is 1.05 × 10?3 Pa s) is found to be 0.42 dB as compared to the amplitude in the unloaded waveguide, which can be considered as the sensitivity of the experimental setup. A method for calibrating the sensor is described. The shear viscosities of solutions of saccharose in distilled water are measured, and the experimental results agree well with the theoretical estimates.  相似文献   
4.
Template cross-linking of nioxime using equimolar amounts of boric and 4-vinylphenylboronic acids on an iron(II) ion as a matrix gave a mixture of mono- and divinyl-terminated clathrochelate products, which were chromatographically isolated in moderate yields and characterized by X-ray diffraction. The target complex FeNx3(BOCH3)(4-BC6H4CH=CH2) with non-equivalent capping groups was also obtained in a low yield using a transmetallation (re-boronation) of its dimethoxyboron-capped clathrochelate precursor. Re-boronation of the monomethoxyboron-capped cage complex with benzene-1,4-diboronic acid as a bifunctional Lewis-acidic agent afforded mainly the clathrochelate product of its 1:1 re-boronation having a terminal B(OH)2 group. The iron(II) clathrochelate with labile triethylantimony capping groups underwent a transmetallation on the surface of silica gel giving an immobilized Sb, Si-capped macrobicyclic intermediate. Its desorption with 4-vinylphenylboronic acid unexpectedly gave the monovinyl-terminated iron(II) semiclathrochelate as the major product, isolated in a high yield; it was X-ray structurally characterized. The geometry of FeN6-coordination polyhedra of the above semi- and clathrochelates is intermediate between a trigonal prism and a trigonal antiprism; that of the monocapped iron(II) semiclathrochelate is more TAP-distorted and its pseudoencapsulated iron(II) ion is shifted from the center of this polyhedron by 0.02 Å in the direction of the capping boron atom.  相似文献   
5.
A synthetic strategy for obtaining structurally flexible hybrid iron(II) carboranoclatrochelates functionalized with biorelevant groups, based on a combination of a 1,3-dipolar cycloaddition reaction with nucleophilic substitution of an appropriate chloroclathrochelate precursor, was developed. In its first stage, a stepwise substitution of the dichloroclathrochelate precursor with amine N-nucleophiles of different natures in various solvents was performed. One of its two chlorine atoms with morpholine or diethylamine in dichloromethane gave reactive monohalogenoclathrochelate complexes functionalized with abiorelevant substituents. Further nucleophilic substitution of their remaining chlorine atoms with propargylamine in DMF led to morpholine- and diethylamine-functionalized monopropargylamine cage complexes, the molecules of which contain the single terminal C≡C bond. Their “click” 1,3-cycloaddition reactions in toluene with ortho-carborane-(1)-methylazide catalyzed by copper(II) acetate gave spacer-containing di- and tritopic iron(II) carboranoclatrochelates formed by a covalent linking between their different polyhedral(cage) fragments. The obtained complexes were characterized using elemental analysis, MALDI-TOF mass, UV-Vis, 1H, 1H{11B}, 11B, 11B{1H}, 19F{1H} and 13C{1H}-NMR spectra, and by a single crystal synchrotron X-ray diffraction experiment for the diethylamine-functionalized iron(II) carboranoclathrochelate. Its encapsulated iron(II) ion is situated almost in the center of the FeN6-coordination polyhedron possessing a geometry intermediate between a trigonal prism and a trigonal antiprism with a distortion angle φ of approximately 28°. Conformation of this hybrid molecule is strongly affected by its intramolecular dihydrogen bonding: a flexibility of the carborane-terminated ribbed substituent allowed the formation of numerous C–H…H–B intramolecular interactions. The H(C) atom of this carborane core also forms the intermolecular C–H…F–B interaction with an adjacent carboranoclathrochelate molecule. The N–H…N intermolecular interaction between the diethylamine group of one hybrid molecule and the heterocyclic five-membered 1H-[1,2,3]-triazolyl fragment of the second molecule of this type caused formation of H-bonded carboranoclathrochelate dimers in the X-rayed crystal.  相似文献   
6.
Movement of an ideal compressed liquid in a specially shaped chamber is considered. The possibility is demonstrated of obtaining with a point explosion shock waves with a front close to planar. The solution is performed by a break-up-discontinuity method.Translated from Teoreticheskaya i Prikladnaya Mekhanika, No. 18, pp. 127–129, 1987.  相似文献   
7.
The sources of systematic errors in measuring the amplitude and propagation velocity of normal waves are analyzed. Criteria are proposed for estimating the distances beyond which a wave can be considered a normal wave. The measurement method and corresponding experimental setup are described. Experimental estimates are obtained for the distances necessary for the formation of symmetric zero modes of horizontally polarized normal waves and Lamb waves in thin strips at frequencies of 1.8 and 2.5 MHz.  相似文献   
8.
Ascent of a large-scale thermal in a standard atmosphere is calculated with the use of the Reynolds equations and the k model of turbulence, which takes into account temperature inhomogeneity and vorticity of the flow, and the Euler equations. Results of numerical calculations of a flow examined experimentally are presented. Gas-dynamic and turbulent flow parameters obtained in calculations and experiments are compared.  相似文献   
9.
To compute the current in a perforated pipe during an underwater electric surge we use the model of a porous pipe. The computations are carried out numerically in the one-dimensional formulation taking account of the nonisoentropic nature of the process. The results of test computations are analyzed. One figure. Bibliography: 7 titles. Translated fromTeoreticheskaya i Prikladnaya Mekhanika, No. 22, pp. 89–93 1991.  相似文献   
10.
This paper reports on the results of investigations into the photoconducting properties of amorphous molecular semiconductors based on films of two types: (i) poly(styrene) films doped with epoxypropylcarbazole (EPC) and a cationic polymethine dye (PD1) and (ii) poly(styrene) films doped with tetranitrofluorenone (TNF) and an anionic polymethine dye (PD2). Films of the first type possess p-type conductivity, whereas films of the second type exhibit n-type conductivity. It is found that, for films with n-type conductivity, unlike films with p-type conductivity, the activation energy of photogeneration of mobile charge carriers decreases with a decrease in the optical wavelength in the absorption range of the dyes. The possible mechanisms of the influence of the photoexcitation energy on the initial distance between charge carriers in electron-hole pairs are analyzed. The inference is made that, when the excess thermal energy of excited dye molecules dissipates at a low rate, the distance between the photogenerated electrons and photogeneration centers increases as compared to the distance between the photogenerated holes and photogeneration centers due to the electron-nucleus interaction.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号