碳还原锆英石分离SiO2和ZrO2

进行了配碳量，温度，时间和颗粒大小及试样形式对碳还原锆英石中ＳｉＯ２的实验研究，得到相应脱硅率的影响规律，理论上，脱硅率的极大值可达到９７．２２％，碳还原锆石的表现反应活化能，在１６００～２０００℃温度范围内为２８２．０４ｋｊ／ｍｏｌ。锆英石被碳还原的限制环节是锆英石的热分解，而不是它裂解成ＳｉＯ２之后再与碳的反应。     

Rutile U-Pb age for the ultra-high pressure eclogite from the dabie Mountains,central China:Evideence for rapid cooling

The U-Pb isotope compositions of rutile, omphacite and garnet in the eclogite from the Jinheqiao area in the Southern Dabie ultrahigh-pressure metamorphic zone were analyzed. The consistent high precision U-Pb age (218 ±(1.2) Ma of rutile in eclogite from the Dabie Mountains was obtained by two ways of isochron and common Pb correction based on the composition of omphacite. This proves that the omphacite in eclogite has a U/Pb ratio (μ = 2.8) low enough to be used for common Pb correction in the analyses of rutile. Under the rapid cooling condition (40℃/Ma) the closure temperature for U-Pb diffusion in rutile is about 470℃. Thus, this U-Pb age of rutile proves that 218 Ma should be the cooling age of eclogite at 470℃ instead of the peak metamorphic age.     

Timing and history of marine hydrocarbon accumulation in Tarim craton

<正> Based on the analyses of hydrocarbon inclu-sions, K-Ar dating of authigenic illites and oil/gas-watercontact retrospection as well as other methods, the marineprimary reservoirs in the cratonic region of the Tarim Basinare found to have been formed in the late Caledonian toearly Hercynian, late Hercynian, and Himalayan, and oil andgas adjusted and redistributed in the Yanshanian (Jurassic toCretaceous) and Himalayan (Tertiary). The analyses alsoshow that the remaining primary oil accumulations aremostly formed in the late Hercynian, and the secondary oilreservoirs resulted from the adjustment and redistribution ofthe earlier accumulations during the Yanshanian and Hima-layan (especially late Himalayan), of which the Himalayan isalso the major stage of gas accumulation. The primary oilreservoirs formed in the late Hercynian mostly occur withinthe Paleozoic formation, whereas the secondary reservoirsformed in the Himalayan in the Mesozoic. The late adjust-ment and redistribution of reservoirs in the craton region ofthe Tarim Basin is ubiquitous because of the intensified tec-tonic movements since the Mesozoic, especially Cenozoic andintrusion of the high- to over-mature gas. Furthermore, thelower amplitude of reservoirs in the craton region also makesthem easier to be adjusted and redistributed. Therefore, theremaining paleo-uplift and palaeo-slope developed in rela-tively stable tectonic regions are the main potential areas forthe middle-large marine reservoirs in the Tarim Basin.     

An in situ zircon Hf isotopic,U-Pb age and trace element study of banded granulite xenolith from Hannuoba basalt： Tracking the early evolution of the lower crust in the North China craton

Backscattered electron images, in situ Hf isotopes, U-Pb ages and trace elements of zircons in a banded granulite xenolith from Hannuoba basalt have been studied. The results show that the banded granulite is a sample derived from the early lower crust of the North China craton. It is difficult to explain the petrogenesis of the xenolith with a single process. Abundant information on several processes, however, is contained in the granulite. These processes in-clude the addition of mantle material, crustal remelting, metamorphic differentiation and the delamination of early lower crust. About 80% of zircons studied yield ages of 1842 ±40 Ma, except few ages of 3097-2824 Ma and 2489-2447 Ma. The zircons with ages older than 2447 Ma have high εHf (up to +18.3) and high Hf model age (2.5-2.6 Ga), indicating that the primitive materials of the granulite were derived mainly from a depleted mantle source in late Archean. Most εhf of the zircons with early Proterozoic U-Pb age vary around zero, but two have     

Genesis of zircon and its constraints on interpretation of U-Pb age

Zircon U-Pb dating is the most commonly used method for isotopic geochronology. However, it has been a difficult issue when relating zircon U-Pb ages to metamorphic conditions in complex metamorphic rocks. Much progress has been made in the past decade with respect to the genesis of zircon and its constraints on interpretation of U-Pb age. Three methods have been proposed to link zircon U-Pb age to metamorphic conditions: ( i ) internal structure; ( ii ) trace element feature; (iii) mineral inclusion composition. Magmatic zircon shows typical oscillatory zoning and/or sector zoning, whereas metamorphic zircon has internal structures such as no zoned, weakly zoned, cloudy zoned, sector zoned, planar zoned, and patched zoned ones. Zircons formed in different geological environments generally have characteristic internal structures. Magmatic zircons from different rock types have variable trace element abundances, with a general trend of increasing trace element abundances in zircons from ultramafic through mafic to granitic rocks. Zircons formed under different metamorphic conditions have different trace element characteristics that can be used to relate their formation to metamorphic conditions. It is an effective way to relate zircon growth to certain P-T conditions by studying the trace element partitioning between coexisting metamorphic zircon and garnet in high-grade metamorphic rocks containing both zircon and garnet. Primary mineral inclusions in zircon can also provide unambiguous constraints on its formation conditions. Therefore, interpretation of zircon U-Pb ages can be constrained by its internal structure, trace element composition, mineral inclusion and so on.     

Rutile U-Pb age for the ultrahigh pressure eclogite from the Dabie Mountains,central China: Evidence for rapid cooling

The U-Pb isotope compositions of rutile, omphacite and garnet in the eclogite from the Jinheqiao area in the Southern Dabie ultrahigh-pressure metamorphic zone were analyzed. The consistent high precision U-Pb age (218 ± 1.2) Ma of rutile in eclogite from the Dabie Mountains was obtained by two ways of isochron and common Pb correction based on the composition of omphacite. This proves that the omphacite in eclogite has a U/Pb ratio (m = 2.8) low enough to be used for common Pb correction in the analyses of rutile. Under the rapid cooling condition (40℃/Ma) the closure temperature for U-Pb diffusion in rutile is about 470℃. Thus, this U-Pb age of rutile proves that 218 Ma should be the cooling age of eclogite at 470℃ instead of the peak metamorphic age.     

Hf isotope composition of zircons and implication for the petrogenesis of Yajiangqiao granite,Hunan Province,China

In the peralumineous granite of Yajiangqiao zircon population can be divided into two groups (i.e. Zircon Ⅰ and Zircon Ⅱ), which were formed in magmatic chamber and in emplacement place, respectively. The Hf isotope compositions of two stages of zircon show that the host magma was essentially derived from crustal material by melting. However, some higher 176Hf/177Hf ratios indicate that the granitic zircons should contain fine crystal of zircon formed in mantle-derived magma. In fact, the backscattered electron imaging and the electron microprobe analysis reveal that there is another type of zircon included within Zircon Ⅰ, which is quite different from Zircon Ⅰ and Zircon Ⅱ in morphology and chemistry. They are considered to be the product of the mantle-derived magma intruded into the granitic magma chamber at the beginning of anatexis. Thus,it is suggested that the formation of Yajiangqiao granite is related to the underplating of mantle magma.     

～4.1 Ga xenocrystal zircon from Ordovician volcanic rocks in western part of North Qinlin80rosenic Belt

High-precision U-Pb dating by in situ LA-ICP-MS yields an age of 4079±5 Ma for a xenocrystal zircon from Ordovician volcanics of the Caotangou Group in western part of the North Qinling Orogenic Belt. As a result, the North Qinling Orogenic Belt becomes one of a few localities in the world that contain Hadean age records （4276±6 Ma and 4404±8 Ma detrital zircons from Jack Hill of the Yilgarn craton, 4016 Ma Acasta gneisses of the Wopmay Orogeny and Burang quartzite with detrital zircon of 4103 Ma in Tibet）. It is also the first report of the Hadean age in Phanerozoic volcanics. The finding of the 4.1 Ga xenocrystal zircon provides not only the geochronological record of the oldest crustal materials in China, but also the condition for further search for rocks forming in the region during the early time of the Earth＇s evolution. Thirty-six zircon U-Pb dates from the Ordovician volcanic rocks are subgrouped into seven generations that represent different tectono-magmatic events in the North Qinling Orogenic Belt. Among them, two periods of 0.9--1.5 Ga and 0.4--0.5 Ga are consistent with Mesoproterozoic and Early Paleozoic orogenies, respectively.     

Spectroscopic study of BixEu1−xVO4 and BiyGd1−yVO4 mixed oxides

The mixed oxides Bi_xEu_1−xVO₄ and Bi_yGd_1−yVO₄ crystallize in a zircon-type structure, for 0 <x < 0.6 and 0 < y < 0.64, and in a fergusonite-type structure, for 0.94 < x < 1 and 0.93 < y < 1. A process of competition between the dominant and the constrained effects of the lone-pair 6s² of Bi³⁺ is discussed. The diffuse reflectance spectroscopic studies of these mixed oxides are presented. The observed broad bands are attributed to charge transfer processes and the sharp peaks in the Bi_xEu_1−xVO₄ spectra are ascribed to intra-configurational 4f – 4ftransitions of the Eu³⁺ ion. The broad absorption shift in BiLnVO₄ (Ln : Eu and Gd) compounds to the longer wavelengths range, when Bi is introduced in the LnVO₄ lattice, is ascribed to charge transfer processes in a Bi-VO₄ center and are interpreted assuming a Jahn-Teller effect in the excited state of Bi³⁺. The concept of an internal pressure of Bi³⁺ ions is also used to explain the broad A-band shifts.