ON THE OPTIIMAL REACTIONS ASSEMBLAGE OF COMPLEX REACTION SYSTEMS

In this paper, the author analyzes distinguishing features of complex reaction systems and single reversible reaction, and optimizes complex reaction systems starting from set theory.The method of constructing the optimal reactions assemblage and calculating the potential maximum equilibrium yield (PMEY) of objective products is proposed here. This paper points out clearly that the euqilibrium yield of objective products calculated by means of conventional method is the global equilibrium yield (GEY).It is not the thermodynamic constraint, and could be exceeded by observed yield of objective products; only PMEY is the thermodynamic constraint. It gives information on potential and possible optimal yield and thereby improving production. This paper also points out the way in which the real complex reaction system approached the optimal reactions assemblage. The new concept of PMEY and optimal reaction assemblage proposed by this Paper is universally applicable for the important complex reaction systems, such as the pyrolysis of alkane to produce ethylene, steam reforming of methane to produce syngas, production of formaldehyde from methanol, epoxidation of ethylene to produce ethylene oxide, hydrogenation of benzene to produce cyclohexane.     

塑料闪烁体的辐照特性

利用⁶⁰Co放射源分别对3种塑料闪烁体(BC-408, EJ-200, BC-404)进行辐照损伤研究, 比较辐照前后的透射谱、发射谱及光产额的变化, 发现3种闪烁体在低剂量具有较好的抗辐照性能; 当照射剂量超过1.44×10⁴Gy时,透射谱明显变坏, 光输出减少很严重, 但发射谱却保持不变.     

具有高机械强度的掺Er~(3 )∶TeO_2-Nb_2O_5玻璃的光谱性质研究

熔制了掺铒碲铌玻璃样品(100-X)TeO2-XNb2O5(X=5,10,15,20mol%),测试了其密度、折射率、转变温度、析晶温度、维氏机械强度、吸收光谱、荧光光谱、荧光寿命等参量。利用Judd-Ofelt和McCumber理论分别计算了铒离子强度参量Ωt(t=2,4,6)和受激发射截面σemi的大小,研究了掺铒碲铌玻璃样品光谱参量对Nb2O5成分的依赖性,并与典型的碲锌钠玻璃(75TeO2-20ZnO-5Na2O)在热学、机械强度、光谱性质和放大品行四个方面进行了比较.     

Variation of interband interaction strength in odd-A nuclei

Bandcrossing in 31 rotational bands of 25 different odd-A nuclei in the rare-earth region has been analysed by using a two-band mixing formalism with a constant band interaction within the framework of the effective decoupling picture. The interband interaction strengthV between the one-quasiparticle band and the three-quasiparticle band exhibits a variation with the neutron number which is not different from the oscillatory behaviour observed in even-even nuclei and does not show signs of any appreciable phase shifting as predicted by theory. However, the overall range of variation ofV is greater than that observed in even-even systems.     

粘结开裂破坏框架柱性能的研究

本文以试验结果为基础,通过轴压力、配筋、配箍、加载方向的变化,分析了这些因素对产生粘结开裂破坏框架柱性能的影响,并给出了产生粘结开裂破坏的m值下限。     

利用单元状态的改变模拟采场破坏规律

采用能较好反映混凝土等脆性材料破坏特征的五参数Wilianm-Warnke强度准则破坏模型，利用有限单元法单元“处死”的功能模拟回采过程和相似材料模拟试验研究，初步总结出缓倾斜厚煤层悬移支架放顶煤顶板活动及矿压显现规律，为缓倾斜厚煤层悬移支架放顶煤制定较为合理的方案、安全技术措施等提供重要的依据和指导作用。     

Strength of cylinder joint adhesively bonded by coupling

Summary A method of joining two metal cylindrical shafts with adhesive coupling is proposed. Two cylindrical shafts with the same diameter are connected by bonding through a cylindrical coupling with epoxy resin. The strength of the shaft joint under tensile loading and torsional loading is investigated analytically and experimentally. The stress and strain distributions of the shaft joint is analyzed by the finite element method. The analyzed strain distributions in the joint are compared with experimental values. The joint strength is predicted by applying the strength laws of shafts, coupling, adhesive layer and adhesive interface between shaft and adhesive coupling. The effects of the coupling dimension on the joint strength are examined. It is shown that the adhesive shaft joint can transfer the load by which the cylindrical shafts are plastically deformed.This paper was refined by the author, K. Ikegami, during statying at Technische Universität München under the support of Deutscher Akademischer Austauschdients. The author is grateful to Professor Lippmann of Technische Universität München who is the host professor of the support.     

Carbon–epoxy composites based on fibers coated with nylon 6,6: hygrothermal ageing versus interlaminar shear strength

Carbon fibers were coated in situ with a thin film of polyhexamethylene adipamide by an interfacial polycondensation technique. The modified fibers were used for the preparation of epoxy-based unidirectional composites. Specimens of these materials were immersed in water until equilibrium conditions were attained. The weight gain at equilibrium was determined as a function of the immersion temperature, the fiber volume fraction and the polyamide content deposited on the fibers. Water penetration in specimens made with uncoated carbon fibers increases when the volume fraction decreases. Introduction of the polyamide interlayer initially increases the water absorption, but reduces it at higher immersion temperatures and/or higher polyamide contents. The treated specimens were subjected to the short beam test to determine the interlaminar shear strength (ILSS). The data show that the ILSS decreases with water penetration but increases when the immersion temperature increases from 40 to 70°C. The overall performance encountered is discussed in terms of the possible roles of the polyamide interphase while taking into account mechanisms concerned with matrix plasticization, interphase degradation and residual stress relaxation.     

非破损检测结构混凝土推定强度的可靠性分析

现行常用的非破损检测结构混凝土抗压强度技术规程中只给出了结构混凝土推定强度的计算方法,其计算结果的可信程度并不能确定.运用概率论知识,引入置信区间的概念,利用非中心t分布建立数学模型,对规程中推定强度进行概率分析,计算其置信度,以供工程实践参考.