Oligosiloxane Functionalized with Pendant (1,3‐Bis(9‐carbazolyl)benzene) (mCP) for Solution‐Processed Organic Electronics

A new oligosiloxane derivative (ODCzMSi) functionalized with the well‐known 1,3‐bis(9‐carbazolyl)benzene (mCP) pendant moiety, directly linked to the silicon atom of the oligosiloxane backbone, has been synthesized and characterized. Compared to mCP, the attachment of the oligosiloxane chain significantly improves the thermal and morphological stabilities with a high decomposition temperature (T_d=540 °C) and glass transition temperature (T_g=142 °C). The silicon–oxygen linkage of ODCzMSi disrupts the backbone conjugation and maintains a high triplet energy level (E_T=3.0 eV). A phosphorescent organic light‐emitting diode (PhOLED) using iridium bis(4,6‐difluorophenyl)pyridinato‐N,C² picolinate (FIrpic) as the emitter and ODCzMSi as the host shows a relatively low turn‐on voltage of 5.0 V for solution‐processed PhOLEDs, maximum external quantum efficiency of 9.2 %, and maximum current efficiency of 17.7 cd A^?1. The overall performance of this device is competitive with the best reported solution‐processed blue PhOLEDs. Memory devices using ODCzMSi as an active layer exhibit non‐volatile write‐once read‐many‐times (WORM) characteristics with high stability in retention time up to 10⁴ s and a low switch on voltage. This switching behaviour is explained by different stable conformations of ODCzMSi with high or low conductivity states which are obtained under the action of electric field through a π–π stacking alignment of the pendant aromatic groups. These results with both PhOLEDs and memory devices demonstrate that this oligosiloxane–mCP hybrid structure is promising and versatile for high performance solution‐processed optoelectronic applications.     

一种新的蠕虫检测和控制方法

在分析网络蠕虫连接请求和网络正常连接请求差异的基础上,提出一种新的蠕虫检测和控制方法.该方法针对网络蠕虫攻击特定端口以及攻击地址发散的特性,采用基于端口的多工作集区分网络蠕虫连接请求和网络正常连接请求,在蠕虫控制中使用多延迟队列处理可疑连接请求,避免了不同端口流量之间的相互影响;针对网络正常连接请求的暂时突发特征,利用令牌桶控制多延迟队列的输出,缩短了正常连接请求在延迟队列中的停留时间.测试表明,在主机感染了蠕虫后,新方法将误报率从85%降低到12%,对正常连接请求的平均延迟时间从95.4s降低到5.6s.     

实用型平面双包络环面蜗杆传动的参数化建模

在环面蜗杆螺旋线参数方程的建模基础上,论证并分析构建了平面包络环面蜗杆产形齿的特征模型,按此模型在MDT6.0环境中实现了平面包络环面蜗杆的三维建模.进而又分析讨论了平面二次包络环面蜗轮的特征模型与实体构建,实现了"平面二次包络环面蜗杆传动的参数化建模".该方法简洁实用,三维实体具有真实的运动型面,能为数控加工提供精确的坐标参数,也能为平面二次包络环面蜗杆传动的性能优化奠定良好的基础.     

Temperature‐Induced Transformation from Large Compound Vesicles to Worm‐like Aggregates by ABC Triblock Copolymer

Two triblock polymers, tetraaniline‐block‐poly(N‐isopropyl acrylamide)‐block‐poly(hydroxyethyl acrylate) (TA‐b‐PNIPAM‐b‐PHEA) and TA‐b‐PHEA‐b‐PNIPAM, were synthesized with unambiguous structure by a two step method. The difference of these two diblock polymers is the connection order of carboxyl group to block, e.g., carboxyl group to PNIPAM block for PNIPAM‐b‐PHEA and to PHEA block for PHEA‐b‐PNIPAM. Secondly, block tetraaniline was linked to the diblock polymer through amidation to yield the corresponding triblock copolymer. Both of them have almost the identical chemical compositions. The only difference is the connection order of each block in the triblock polymers. When they were self‐assembled at 45°C in a suitable solution, both of their aggregates have spherical shape with slight defects on their surface with the average diameter of about 400 nm. However, when their aggregate dispersion was cooled down to 20°C, only TA‐b‐PHEA‐b‐PNIPAM's morphology changed, forming worm‐like aggregates with the diameter of about 100–200 nm transformed from spherical aggregates. Both amphiphilic property and position of each block in this triblock copolymer are very essential for this morphology transformation. Since the worm‐like aggregates presented here by our group have hollow structure inside, its controlled release properties for doxorubicin were evaluated. Drug release experiment indicated that along with the temperature changes, the rearrangement of the intermediate layer structure caused morphology change in aggregate, thus accelerating the speed of drug release.     

环面滚珠蜗轮磨削问题的探讨

本文介绍了适合磨削环面滚珠蜗轮的磨具、磨削方法以及相应的磨削装置。根据齿轮啮合原理和滚珠螺旋传动的设计准则可知,采用该方法磨削的环面滚珠蜗轮与滚珠之间可达到或接近滚珠螺旋传动的最佳接触。     

蜗杆副材料ZQSn_（12－2）－S16MnCr的摩擦学性能

对１０组不同的蜗杆副材料组合进行了摩擦学性能研究．在无润滑和常温条件下，得到了不同速度和载荷时的摩擦学参数及摩擦表面的电子显微镜照片．经分析，给出了摩擦学性能的比较结果，表明ＺＱＳｎ１２－２－Ｓ１６ＭｎＣｒ为最佳蜗杆副新材料组合．     

锥面包络圆柱蜗杆传动可控失配修形的研究

对锥面包络圆柱蜗杆传动（ZK蜗杆传动）进行了可控修形，分析了修形传动的基本原理。提出了通过改变蜗杆齿面接触的位置及曲率修正量来改变传动的齿面接触状态的方法，修形加工可通过改变砂轮的几何尺寸及安装参数来实现。     

锥面包络环面蜗杆与直廓环面蜗轮失配啮合传动的研究

提出了用锥面和直线分别展成蜗杆和蜗轮滚，获得失配点啮合环面蜗杆传动的方法。分析了该失配合传动的基本原理。求解了蜗轮融的齿面接触状态和加工工艺参数。结果表明失配啮合传动呆实现良好的点接触。     

抵御蠕虫攻击的一种方法-Honeypot系统

Internet大面积遭受蠕虫攻击的事件时有发生，针对这种问题，引入Honeypot技术，结合入侵检测系统(IDS)、数据挖掘提出了一种解决办法：将Honeypot置于DMZ中，利用其欺骗地址空间技术覆盖服务器中没有用到的IP地址，捕获蠕虫；IDS监控流入网络的数据包，对入侵作出反映；系统日志异地保存。该系统能有效抵御目前已经出现的蠕虫攻击，同时对新出现的目前未知的蠕虫攻击也有很好的防御效果。     

基于选择性随机扫描的蠕虫传播模型

分析了蠕虫病毒在一个封闭的计算机群中传播的过程,提出了一个离散的蠕虫传播模型,并且把该模型和CodeRedv2蠕虫的真实传播数据进行了比较,通过比较发现该模型较好地反映了随机扫描蠕虫的传播规律·进一步把该模型做了推广,考虑选择性随机扫描(Selective-randomscan)蠕虫的传播规律,通过推广后的模型可以发现,在一个封闭的计算机群中,各个小网络中的易感主机数变化越大,蠕虫传播的速度越快·