一个组合分布模型及其参数估计

本文根据极值分布理论,提出了一个由原始分布和尾分布组成的组合分布模型,研究了组合分布模型中原始分布和尾分布的确定方法,建立了组合分布模型参数估计的加权最优化模型,实例计算说明,组合分布较好地反映了风险变量极值事件的风险。     

Precise lattice parameter measurements in CsCl-Br solid solutions between room temperature and 90°K by powder x-ray diffraction

Solid solutions of CsCl-Br in five different concentrations were prepared in sealed quartz tubes by heating the mixture to 1123°K for 6–8 hr and quenching to room temperature. X-ray diffractograms were taken at eight different temperatures between room temperature and 90°K for these solid solutions using the YPC50NM powder diffractometer and a continuous flow cryostat. The observed lattice parameters for each sample at each temperature obtained from the powder diffractograms were then extrapolated to give the true lattice parameters using the least square method with Nelson-Riley extrapolation scheme. The values of the true lattice parameters at each concentration and at each temperature were tabulated and the results discussed. It is shown that the lattice parameters vs temperature for some concentrations exhibit an anomalous behaviour. Contribution No. 691     

Adaptive Interpolation by Scaled Multiquadrics

We present an adaptive method to extract shape-preserving information from a univariate data sample. The behavior of the signal is obtained by interpolating at adaptively selected few data points by a linear combination of multiquadrics with variable scaling parameters. On the theoretical side, we give a sufficient condition for existence of the scaled multiquadric interpolant. On the practical side, we give various examples to show the applicability of the method.     

新型连续装载机工作机构的图解设计法

本文介绍了新型连续装载机工作机构图解设计的一般规律,对某些技术参数的确定作了初步探讨。     

Pb-Sn-Bi三元系α相固溶体的点阵参数

应用X射线衍射法测定了Pb-Sn-Bi三元系Pb基α相固溶体的点阵参数,发现点阵间距与成分呈线性变化,对两批实验数据分别进行回归分析,得到点阵参数-浓度关系的统一解析式: α=0.49495X_(Pb)+0.47813X_(Sn)+0.50629X_(Bi)。其F检验置信度大于99.9％,残余标准差σ=6.4×10~(-5) nm,分析点阵畸变的影响因素表明尺寸效应是控制固溶体点阵行为的主要因素。     

异种钢焊接接头过渡层影响因素的研究

本文根据回归正交优化法原理,用电孤焊试验研究了异种钢焊接接头过渡层的影响因素。通过实测与计算,获得过渡层为零时,最佳匹配的焊接规范参数,为消除过渡层的有害影响探讨了新的途径。     

散射体系A+BC的平-振能量传递

用Alhassid与Levine所提出的动力学李代数的方法(简称A-L理论),研究了含有二级非简谐的共线散射体系A+BC的平-振能量传递问题,计算了散射过程含有主要动力学参量的跃迁矩阵和跃迁几率的解析表示式.     

The Ring of Invariants of Three (3 × 3)-Matrices over a Field of Prime Characteristic

We find a minimal system of generators and a homogeneous system of parameters for the algebra of invariants of three matrices of third order over a field of an arbitrary characteristic.     

Activation energies for metastable to stable phase transition of 4,4'-di-n-heptyl- oxyazoxybenzene

Complexes of adenine, AdH, with cobalt, nickel and copper chlorides were prepared and their thermodynamic functions were determined. The complexing processes are endothermic in nature. The thermal behaviour of complexes was followed up by using TG and DTA analyses. The stoichiometry of thermal decomposition of the investigated complexes was suggested. This revised version was published online in August 2006 with corrections to the Cover Date.     

Sterically stabilized emulsion polymerization of styrene: Pseudo‐semicontinuous approach

The sterically stabilized emulsion polymerization of styrene initiated by a water‐soluble initiator at different temperatures has been investigated. The rate of polymerization (R_p) versus conversion curve shows the two non‐stationary‐rate intervals typical for the polymerization proceeding under non‐stationary‐state conditions. The shape of the R_p versus conversion curve results from two opposite effects—the increased number of particles and the decreased monomer concentration at reaction loci as the polymerization advances. At elevated temperatures the monomer emulsion equilibrates to a two‐phase or three‐phase system. The upper phase is transparent (monomer), and the lower one is blue colored, typical for microemulsion. After stirring such a multiphase system and initiation of polymerization, the initial coarse polymer emulsion was formed. The average size of monomer/polymer particles strongly decreased up to about 40% conversion and then leveled off. The initial large particles are assumed to be highly monomer‐swollen particles formed by the heteroagglomeration of unstable polymer particles and monomer droplets. The size of the “highly monomer” swollen particles continuously decreases with conversion, and they merge with the growing particles at about 40–50% conversion. The monomer droplets and/or large highly monomer‐swollen polymer particles also serve as a reservoir of monomer and emulsifier. The continuous release of nonionic (hydrophobic) emulsifier from the monomer phase increases the colloidal stability of primary particles and the number of polymer particles, that is, the particle nucleation is shifted to the higher conversion region. Variations of the square and cube of the mean droplet radius with aging time indicate that neither the coalescence nor the Ostwald ripening is the main driving force for the droplet instability. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 804–820, 2003