The method of concentrating a substance from a solution in a stationary sorbent layer and its theoretical basis

The principle of concentrating a substance from a mixture flow in a stationary sorbent layer of infinite length that was previously developed for gas chromatography is extended to liquid chromatography. Translated fromIzevestiya Akademii Nauk. Seriya Khimicheskaya, No. 5, pp. 1063–1065, May, 1997.     

Radical copolymerization of 2‐trifluoromethylacrylic monomers. II. Kinetics,monomer reactivities,and penultimate effect in their copolymerization with norbornenes and vinyl ethers

Radical copolymerizations of electron‐deficient 2‐trifluoromethylacrylic (TFMA) monomers, such as 2‐trifluoromethylacrylic acid and t‐butyl 2‐trifluoromethylacrylate (TBTFMA), with electron‐rich norbornene derivatives and vinyl ethers with 2,2′‐azobisisobutyronitrile as the initiator were investigated in detail through the analysis of the kinetics in situ with ¹H NMR and through the determination of the monomer reactivity ratios. The norbornene derivatives used in this study included bicyclo[2.2.1]hept‐2‐ene (norbornene) and 5‐(2‐trifluoromethyl‐1,1,1‐trifluoro‐2‐hydroxylpropyl)‐2‐norbornene. The vinyl ether monomers were ethyl vinyl ether, t‐butyl vinyl ether, and 3,4‐dihydro‐2‐H‐pyran. Vinylene carbonate was found to copolymerize with TBTFMA. Although none of the monomers underwent radical homopolymerization under normal conditions, they copolymerized readily, producing a copolymer containing 60–70 mol % TFMA. The copolymerization of the TFMA monomer with norbornenes and vinyl ethers deviated from the terminal model and could be described by the penultimate model. The copolymers of TFMA reported in this article were evaluated as chemical amplification resist polymers for the emerging field of 157‐nm lithography. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 1478–1505, 2004     

Influence of preparation methods on structure and properties of PA6/PA66 blends: A comparison of melt‐mixing and in situ blending

The blends composed of polyamide 6 (PA6) and polyamide 66 (PA66) were obtained using two different preparation methods, one of which was the melt‐mixing through a twin‐screw extruder and the subsequent injection molding; and the other, the in situ blending through anionic polymerization of ε‐caprolactam in the presence of PA66. For the former, there existed a remarkable improvement in toughness but a drastic drop in strength and modulus; however, for the latter, a reverse but less significant trend of mechanical properties change appeared. Various characterizations were conducted, including the analyses of crystalline morphology, crystallographic form, and crystallization and melting behaviors using polarized optical microscopy (POM), wide‐angle X‐ray diffraction (WAXD), and differential scanning calorimetry (DSC), respectively; observation of morphology of fractured surface with scanning electron microscope (SEM); measurement of glass transition through dynamic mechanical analysis (DMA); and the intermolecular interaction as well as the interchange reaction between the two components by Fourier transform infrared spectrometry (FT‐IR) and ¹³C solution NMR. The presence and absence of interchange reaction was verified for the in situ and melt‐mixed blends, respectively. It is believed that the transreaction resulted in a drop in glass transition temperature (T_g) for the in situ blends, contrary to an increase of T_g with increasing PA66 content for the melt‐mixed ones. And the two kinds of fabrication methods led to significant differences in the crystallographic form, spherulite size and crystalline content and perfection as well. Accordingly, it is attempted to explain the reasons for the opposite trends of changes in the mechanical properties for these two blends. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 1176–1186, 2007     

Some remarks on the Jensen-Hadamard inequalities and applications

We provide some inequalities and integral inequalities connected to the Jensen-Hadamard inequalities for convex functions. In particular, we give some refinements to these inequalities. Some natural applications and further extensions are given.

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Sunto Forniamo alcune diseguaglianze e diseguaglianze integrali connesse alle dise-gueglianze di Jensen-Hadamard per funzioni convesse. In particolare, diamo qualche miglioramento di queste diseguaglianze. Alcune applicazioni naturali ed ulteriori estensioni sono date.

     

高校文科数学教育的课程价值及其实现

数学教育是数学文化的教育．文科数学教育的价值取向必须体现育人为本的课程设计观和服从于文科专业培养目标的宗旨．在文科数学教育的实践中，要从文科专业的学科性质、课程体系、培养目标上明确文科数学教育的课程定位、教师职责和改革目标，使文科数学教育切入到文科专业人才培养模式的改革之中。     

论江西与浙江思想观念接轨

江西省推出的加快与浙江思想观念、企业机制、发展环境、人的素质“四个接轨”的新战略部署中，思想观念的接轨是前提和关键。先进浙江人在思想观念和精神品质上有许多优点，如政府的市场意识、领导的服务思想、企业的信用观念、群众的创业胆略、社会的变革认同、整体的实干精神等。江西人要走好传统人精神与现代创新理念相结合的思想接轨之路。     

Effective-field theory and the nuclear many-body problem

We review many-body calculations of the equation of state of dilute neutron matter in the context of effective-field theories of the nucleon-nucleon interaction.     

Vehicle density and velocity estimation on highways for on-ramp metering control

A scheme for vehicle density and velocity estimation in a stretch of highway based on a modified cell transmission model [C. F. Daganzo, Transportation Research, Part B, 28B(4),269–287, 1994. Elsevier is presented. The scheme is intended for use with on-ramp metering control algorithms, providing local knowledge of densities and velocities that is helpful to improve on-ramp metering control performance. Estimation of density is obtained by nonlinear estimators, while velocity estimation is obtained by gradient algorithms. There is one density–velocity estimator for free traffic flow and other for congested traffic flow. Both estimator schemes work in parallel. The final estimation of density and velocity results from a convex combination of the predictions of the two estimators. This combination depends on occupancy or density measurements at the boundaries of the stretch and is produced by a fuzzy inference system. Stability and convergence of the density and velocity estimation scheme is proved by Lyapunov based techniques. Simulation results comparing measured and estimated traffic data are presented. They confirm good performance of the estimators. Research sponsored by grants UNAM PAPIIT IN110403 and CONACYT 47583.     

Binding energy of impurity states in an inverse parabolic quantum well under magnetic field

 We have investigated the effects of the magnetic field which is directed perpendicular to the well on the binding energy of the hydrogenic impurities in an inverse parabolic quantum well (IPQW) with different widths as well as different Al concentrations at the well center. The Al concentration at the barriers was always x_max=0.3. The calculations were performed within the effective mass approximation, using a variational method. We observe that IPQW structure turns into parabolic quantum well with the inversion effect of the magnetic field and donor impurity binding energy in IPQW strongly depends on the magnetic field, Al concentration at the well center and well dimensions.     

Laser spectroscopy of high spin isomers – a review

This review summarizes the experimental data on charge radii differences among ground state and high spin isomeric states determined by high-resolution laser spectroscopic methods. A comparison is presented between radii changes obtained from the isomeric shifts in the atomic spectra and from the quadrupole moments of both ground and isomeric states under the assumption that the radii changes are determined by the difference of the quadrupole deformations. Special attention is paid to isomers arising from the break-up of nucleon pairs and isomers of odd–odd nuclei. The characteristic features of the radii changes for isomeric states of different origin are discussed.