ZnS:Mn、Cu粉末直流电致发光器件直流和交流电致发光一致性的研究

本文研究了粉末直流电致发光(DCEL)器件在直流(DC)和交流(AC)电压下光电特性的关联和区别及其物理机制.实验发现,在DC和AC条件下DCEL器件的阻抗特性之间没有任何有规律的关联,而AC条件下的激发电流IA和亮度BA以及DC条件下的亮度BD和发光效率ηD四个参量之间则表现出某种程度的一致性,但AC条件下的发光效率ηA与上述四个参量之间却表现出某种相反和相对立的关系.DCEL器件的光电特性具有强烈非线性和对电压方向的非对称性.正半周(或DC条件下)DCEL器件是在高电场和低电流激发下的发光.对发光起主要作用的是电场强度.在负半周时则是低电场和大电流激发下的发光.对发光起主要作用的是激发电流而不是电场强度.在AC条件下依材料、工艺、形成条件和工作电压的不同,DCEL器件可能更多地显示出正半周,负半周或两半周综合的光电特性.上述观点可以解释本文的实验结果.     

焊接热循环和拘束应变对粗晶区组织和性能的影响

籍助于热模拟技术、光学金相和透射电子显徽镜、微型拉伸和冲击试验研究了焊接热循环和拘束应变对ＥＨ３６ＭＯＤ控轧钢焊接粗晶区的显微组织和力学性能的影响。试验结果表明，在２种热循环制度下，粗晶区具有不同的显微组织，当ｔ８／５＝６ｓ时，以下贝氏体和板条马氏体为主，而ｔ８／５＝５０ｓ时，则以先共析铁素体和上贝氏体为主。拘束应变的存在，不仅可细化粗晶区的奥氏体晶粒，而且可使组织形态及其相对量发生改变，相应地提     

环筒件扩挤复合成形新技术的试验研究

本文提出了一种可用于生产环筒类锻件的新工艺———扩挤复合成形技术。并采用模拟试验方法研究了该工艺中金属的流动规律和主要工艺参数对成形的影响。优化出合理的冲头工作角和扩挤变形比例，为该工艺应用于实际生产提供了科学依据。     

新型套筒自动机的设计

综合国内外套筒圈制工艺的优点，制定了新型套筒自动机的圈制工艺方案，研制了新的凸轮控制系统，使整机质量提高，且明显降噪减振。     

精细饰纹件等离子熔射快速制造技术研究

提出了精细饰纹件等离子熔射快速制造技术．在大量实验基础上，着重研究精细饰纹熔射成形及后处理过程中的关键技术问题，详细分析和评价了基模特性、射流特性、粉末特性、熔射枪结构、熔射工艺参数等重要因素对熔射成形件质量的影响，给出了射流图像采集方法、粉末飞行速度和温度的数值模拟模型及测量技术方案，最后进行了典型精细饰纹件的熔射成形实验．研究结果表明：等离子熔射成形技术可以快速制造精细饰纹件，实现成形与加工一体化，且工艺简单、成本低，是极具发展潜力的制造方法．     

煤焦中矿物质行为与灰熔融温度的关系

在1000-1600℃制焦温度下，借助于扫描电子显微镜研究了扎莱诺尔、后布连、东胜、西山、沈北、沈阳和阳泉7种煤焦中的矿物质行为。研究结果表明，高温热处理后焦中的矿物质变化行为与相应煤的灰熔点密切相关。当制焦温度接近或超过相应煤灰的熔融温度时，焦中的矿物质出现了明显的迁移倾向，从初始的随机分散分布发展列团聚，温度越高，矿物质的分布改变也越大，由矿物质团聚的颗粒尺寸也随之增大。     

提高列表曲线加工精度的计算机辅助加工

列表曲线在数控加工过程中存在编程繁琐,计算量大且加工精度不高等缺点,提出通过修改插补原理,用计算机辅助编程的方法来提高列表曲线的加工精度。经实际应用,不仅提高了加工效率,而且使加工精度得到提高。     

四点弯曲COD值在评定构件安全的设计曲线中的应用

本文探讨了四点弯曲COD试验值在评定结构安全上的应用。指出,由于该种情况下COD的发生发展机理与宽板拉伸试验时相一致,同时能自动考虑焊缝匹配影响,因此在评定结构安全性上较三点弯曲CDD试验更为合理。     

Chemical, spectroscopic characterization, DFT studies and initial pharmacological assays of a silver(I) complex with N-acetyl-l-cysteine

A new silver(I) complex with N-acetyl-l-cysteine (NAC) of composition AgC₅H₈NO₃S·H₂O was synthesized and characterized by a set of chemical and spectroscopic measurements. Solid-state ¹³C nuclear magnetic resonance (SSNMR) and infrared (IR) analyses indicate the coordination of the ligand to Ag(I) through the sulfur atom. The Ag-NAC complex is slightly soluble in dimethyl sulfoxide. It is insoluble in water, methanol, ethanol, acetone and hexane. Antibacterial activity of the silver complex with N-acetyl-l-cysteine (Ag-NAC) was evaluated by antibiogram assays using the disc diffusion method. The compound showed an effective antibacterial activity against Staphylococcus aureus (Gram-positive), Escherichia coli and Pseudomonas aeruginosa (Gram-negative) bacterial cells. Biological analysis for evaluation of a potential cytotoxic effect of Ag-NAC was performed using HeLa cells derived from human cervical adenocarcinoma. The complex presented a significant cytotoxic activity, inducing 80% of cell death at a concentration of 200 μmol L⁻¹.     

Influence of ultrasonic vibration on micro-extrusion

Micro-forming is a miniaturization technology with great potential for high productivity. Some technical challenges, however, need to be addressed before micro-forming becomes a commercially viable manufacturing process. These challenges include severe tribological conditions, difficulty in achieving desired tolerances, and short tool-life due to inability of available die materials to withstand the forces exerted on miniature dies and punches. Some of these problems can be mitigated using ultrasonic technology.The principal objectives of this work were to investigate the possibility of applying ultrasonic vibrations in the micro-forming process, to design a set of tooling for ultrasonic micro-extrusion and to observe experimentally how ultrasonic oscillations influences the forming load and the surface finish. The test results showed a significant drop on the forming load when ultrasonic vibrations were imposed, and also a significant improvement in the surface of the micro-formed parts. Based on the preliminary test results, the study demonstrated high potential for using ultrasonic oscillations as a way to overcome the difficulties brought by the miniaturization.