An Unusual Reductive Ring-opening Reaction of Phthalimide with Sodium Hydride in DMF

An unusual reductive ring-opening reaction of phthalimide with sodium hydride in anhydrous DMF was observed for the first time. The presumed mechanism was described in detail.     

基于粗糙集理论的知识约简及应用实例

在保持分类能力不变的前提下 ,通过利用粗糙集理论中的知识约简方法 ,在保护知识库分类不变的条件下 ,删除其中不相关或不重要的知识 ,从而导出问题的决策 .利用基于决策表的粗糙集模型算法 ,实例分析如何数字化表示决策表 ,并对其进行属性约简和属性值的约简 ,从而提取决策规则 .     

Karhunen–Loeve representations of turbulent channel flows using the method of snapshots

For three‐dimensional flows with one inhomogeneous spatial coordinate and two periodic directions, the Karhunen–Loeve procedure is typically formulated as a spatial eigenvalue problem. This is normally referred to as the direct method (DM). Here we derive an equivalent formulation in which the eigenvalue problem is formulated in the temporal coordinate. It is shown that this so‐called method of snapshots (MOS) has some numerical advantages when compared to the DM. In particular, the MOS can be formulated purely as a matrix composed of scalars, thus avoiding the need to construct a matrix of matrices as in the DM. In addition, the MOS avoids the need for so‐called weight functions, which emerge in the DM as a result of the non‐uniform grid typically employed in the inhomogeneous direction. The avoidance of such weight functions, which may exhibit singular behaviour, guarantees satisfaction of the boundary conditions. The MOS is applied to data sets recently obtained from the direct simulation of turbulence in a channel in which viscoelasticity is imparted to the fluid using a Giesekus model. The analysis reveals a steep drop in the dimensionality of the turbulence as viscoelasticity is increased. This is consistent with the results that have been obtained with other viscoelastic models, thus revealing an essential generic feature of polymer‐induced drag reduced turbulent flows. Published in 2006 by John Wiley & Sons, Ltd.     

空间有源消声的微机控制

本文讨论用通用微机控制空间有源消声．以修正的PID（比例、积分、微分）算法加上逻辑判断构成的控制软件，使得系统收敛迅速，跟踪速度快，消声效果令人满意，而且系统工作稳定可靠，     

Balance constraints reduction of large-scale linear programming problems

This paper describes a method and the corresponding algorithms for simplification of large-scale linear programming models. It consists of the elimination of the balance constraints (i.e. constraints with zero RHS term). The idea is to apply some linear transformations to the original problem in order to nullify the balance constraints. These transformations are able to simultaneously eliminate more balance rows. The core of this contribution is the introduction of the reduction matrix and the associated theorems on the equivalent linear programs (original and reduced). The numerical experiments with this method of simplification proved this approach to be beneficial for a large class of LP problems.This research work was done while the first author was at Duisburg University, Mess-, Steuer und Regelungstechnik, Germany, under the greatly appreciated financial assistance given by the Alexander-von-Humboldt Foundation.     

Zn^2＋在电解还原铕（Ⅲ）过程中的催化行为研究

本文报道微量Zn~(2+)在电解还原铕(Ⅲ)离子过程中的催化作用,研究结果表明:当阴极中含Zn~(2+)时,铕(Ⅲ)离子将缩短到达定量还原的时间,用循环伏安法监控电极过程的结果表明:电极过程是准一级的催化过程。     

An ASE Reduction Filter Using Cascaded Optical Fiber Grating Couplers in EDFA Repeater

A new configuration for an ASE reduction filter in EDFA repeaters for WDM optical transmission systems using optical fiber grating couplers (FGCs) was proposed and first demonstrated. The filtering characteristics of the proposed filter for amplified single wavelength signal and 2-channel WDM signals using EDFA were identified. It was found that the filter was effective to improve SNR in optical domain by reducing ASE noise. The required FGC characteristics for the filter were theoretically predicted under the condition that the total filter loss did not exceed 3 dB. More than 70% of drop efficiency was required in each FGC for the application of the proposed filter to an 8-channel WDM system using EDFA repeaters.     

Reductions of interval noncooperative games

Noncooperative games of a finite number of persons with interval-valued payoff functions are considered. The concept of an equilibrium situation is introduced. A reduction of such games to deterministic noncooperative games is proposed. Properties of the reduced games are discussed. Interval antagonistic and bimatrix games are examined, and illustrative examples are considered.     

阴极还原处理对多孔硅发光性能的影响

对经过阴极还原处理后的多孔硅样片进行了光致发光测试和稳定性测试.实验结果表明这种处理能明显改善多孔硅的发光稳定性,使其表面结构更加稳定.利用原子力显微镜对不同还原时间的多孔硅微结构及形貌进行了比较,在一定范围内随着还原时间的增长多孔硅表面粗糙度增大,PL谱增强.     

新型金属杂冠醚配合物18-MC-6[Mn6(4-Amashz)6(DMF)6]·12DMF的合成

合成了一种新型金属杂冠醚配合物[Mn6(4-amashz)6(DMF)6]·12DMF,并用X射线衍射法对其结构进行了表征.研究了该化合物修饰金电极催化氧还原的性质,结果表明,该化合物具有平面碟状结构,对在碱性溶液中的氧有显著的催化还原作用.