全文获取类型
收费全文 | 43933篇 |
免费 | 4189篇 |
国内免费 | 3829篇 |
专业分类
化学 | 16618篇 |
晶体学 | 283篇 |
力学 | 3023篇 |
综合类 | 237篇 |
数学 | 2715篇 |
物理学 | 10571篇 |
综合类 | 18504篇 |
出版年
2024年 | 129篇 |
2023年 | 403篇 |
2022年 | 862篇 |
2021年 | 1026篇 |
2020年 | 1130篇 |
2019年 | 978篇 |
2018年 | 901篇 |
2017年 | 1086篇 |
2016年 | 1299篇 |
2015年 | 1472篇 |
2014年 | 2050篇 |
2013年 | 2677篇 |
2012年 | 2407篇 |
2011年 | 2832篇 |
2010年 | 2228篇 |
2009年 | 2470篇 |
2008年 | 2529篇 |
2007年 | 2861篇 |
2006年 | 2746篇 |
2005年 | 2381篇 |
2004年 | 2105篇 |
2003年 | 1899篇 |
2002年 | 1810篇 |
2001年 | 1425篇 |
2000年 | 1287篇 |
1999年 | 1112篇 |
1998年 | 1017篇 |
1997年 | 984篇 |
1996年 | 831篇 |
1995年 | 749篇 |
1994年 | 699篇 |
1993年 | 571篇 |
1992年 | 561篇 |
1991年 | 452篇 |
1990年 | 391篇 |
1989年 | 361篇 |
1988年 | 322篇 |
1987年 | 214篇 |
1986年 | 152篇 |
1985年 | 109篇 |
1984年 | 74篇 |
1983年 | 26篇 |
1982年 | 76篇 |
1981年 | 43篇 |
1980年 | 47篇 |
1979年 | 31篇 |
1978年 | 26篇 |
1977年 | 17篇 |
1976年 | 32篇 |
1973年 | 14篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
201.
纪桂花 《山东理工大学学报:自然科学版》2002,16(2):28-30
介绍一种新型湿式净化秸秆气化燃气的方法及基本原理 ,并讨论分析了其对秸秆燃气热值的影响 . 相似文献
202.
《厦门大学学报(自然科学版)》2002,(Z1)
In 1982, Professor Fang Guoliang found the “Non full resonance“ phenomenon in a tool system while he use the thin-long tool ultrasonically machining deep-small hole. He called it as “local resonance“. Also this “Non full resonance“ phenomenon was discovered in the ultrasonic drilling and the ultrasonic honing system later. To its mechanism, professor Fang thought that the coupling of long-thin tool bar and driving system is weak, so the tool bar can vibrate independently, but the quantitative relation betwe... 相似文献
203.
Conductive composite films of poly(styrene‐co‐n‐butylacrylate) copolymers filled with low‐density, Ni‐plated core‐shell polymeric particles were prepared and their behaviors of positive temperature coefficient of resistance (PTCR) were investigated. When the conductive fillers in the composite film were loaded beyond the critical volume, 10 up to 25 vol %, composite films exhibited a unique electrical resistant transition behavior, which the electrical resistance rapidly increased by several orders of magnitude at the critical temperature. The PTCR transition temperature, in general, occurred before the glass transition temperature of polymer matrix. Further increased the conductive filler loading to 30 vol %, the overpacked conduction paths were formed in the entire composite and the PTCR effects became blurred. While the composite film treated with thermal cycle several times from room temperature up to 120 °C, the electrical resistivity increased accompanied with the shift of the PTCR transition to lower temperature. The reason might have been caused by the formed interfacial cracks within the composite film. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 322–329, 2007 相似文献
204.
Brad M. Rosen Virgil Percec 《Journal of polymer science. Part A, Polymer chemistry》2007,45(21):4950-4964
Atom transfer radical polymerization (ATRP) and single electron‐transfer living radical polymerization (SET‐LRP) both utilize copper complexes of various oxidation states with N‐ligands to perform their respective activation and deactivation steps. Herein, we utilize DFT (B3YLP) methods to determine the preferred ligand‐binding geometries for Cu/N‐ligand complexes related to ATRP and SET‐LRP. We find that those ligands capable of achieving tetrahedral complexes with CuI and trigonal bipyramidal with axial halide complexes with [CuIIX]+ have higher energies of stabilization. We were able to correlate calculated preferential stabilization of [CuIIX]+ with those ligands that perform best in SET‐LRP. A crude calculation of energy of disproportionation revealed that the same preferential binding of [CuIIX]+ results in increased propensity for disproportionation. Finally, by examining the relative energies of the basic steps of ATRP and SET‐LRP, we were able to rationalize the transition from the ATRP mechanism to the SET‐LRP mechanism as we transition from typical nonpolar ATRP solvents to polar SET‐LRP solvents. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 4950–4964, 2007 相似文献
205.
本文在分别简要介绍HP-IB接口、HP3562A和HP9000/320及其控制之后,较详细地讨论了HP-IB接口总线控制HP3562A和进行数据传输的四种有效方法,并给出了程序实例。本文所述的方法同样适用于对其它HP-IB(GP_IB)仪器的控制。 相似文献
206.
J.-L. Garden 《Thermochimica Acta》2007,452(2):85-105
What is really measured in dynamic calorimetric experiments is still an open question. This paper is devoted to this question, which can be usefully envisaged by means of macroscopic non-equilibrium thermodynamics. From the pioneer work of De Donder on chemical reactions and with other authors along the 20th century, the question is tackled under an historical point of view. A special attention is paid about the notions of frequency dependent complex heat capacity and entropy production due to irreversible processes occurring during an experiment. This phenomenological approach based on thermodynamics, not widely spread in the literature of calorimetry, could open significant perspectives on the study of macro-systems undergoing physico-chemical transformations probed by dynamic calorimetry. 相似文献
207.
Kan‐Yi Pu Yi Chen Xiao‐Ying Qi Chun‐Yang Qin Qing‐Quan Chen Hong‐Yu Wang Yun Deng Qu‐Li Fan Yan‐Qin Huang Shu‐Juan Liu Wei Wei Bo Peng Wei Huang 《Journal of polymer science. Part A, Polymer chemistry》2007,45(16):3776-3787
In this contribution, we demonstrate a new effective methodology for constructing highly efficient and durable poly(p‐phenyleneethynylene) (PPE) containing emissive material with nonaggregating and hole‐facilitating properties through the introduction of hole‐transporting blocks into the PPE system as the grafting coils as well as building the energy donor–acceptor architecture between the grafting coils and the PPE backbone. Poly(2‐(carbazol‐9‐yl)ethyl methacrylate) (PCzEMA), herein, is chosen as the hole‐transporting blocks, and incorporated into the PPE system as the grafting coils via atom transfer radical polymerization. The chemical structure of the resultant copolymer, PPE‐g‐PCzEMA, was characterized by NMR and gel permeation chromatography, showing that the desirable copolymer was obtained with the narrow polydispersity. The increased thermal stability of PPE‐g‐PCzEMA was confirmed by thermogravimetric analysis and differential scanning calorimetry along with its macroinitiator. The optoelectronic properties of this copolymer were studied in detail by ultraviolet‐visible absorption, photoluminescence emission and excitation spectra, and cyclic voltammogram (CV). The results indicate that PPE‐g‐PCzEMA exhibits the solid‐state luminescent property dominated by individual lumophores, and also the energy transfer process from the PCzEMA blocks to the PPE backbone with a relatively higher energy transfer efficiency in the solid‐state compared to that of the solution state. Additionally, the hole‐injection property is greatly facilitated due to the presence of PCzEMA, as confirmed by CV profiles. All these data indicate that PPE‐g‐PCzEMA is a good candidate for use in optoelectronic devices. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 3776–3787, 2007 相似文献
208.
209.
林支桂 《数学物理学报(B辑英文版)》1998,(3)
1IntroductionInthispaper,weconsidertheinitial-boundaryvalueproblem,where"o(x)isnon-negativesmoothfunctionsatisfying"o.(0)=0,"o.(1)=1'Whenconsideringtheblow-upofsolution,thefollowingproblemarisenaturally:Doesblow-upoccur?Howdoesthesolutionapproachtheblow-uptime'!Andwilersisthehotspotlocated(blow-upset)?WelookattheheatequationwithanonlillearboundaryconditiollHerefiisaboundeddomaininR",p>1isarealnumber.IthasbeenknownforalongtimethattheDroblelil(1.1).(1.2)withAL(~,0)--'no(x)doesnothaveaglobals… 相似文献
210.
For the Boltzmann equation with small transfer of momentum, we derive a system of nonlinear integral-differential equations describing the logarithmic asymptotics of the solution to the Cauchy problem in the domain at the distanceO(1) from the support of the initial condition.Translated fromMatematicheskie Zametki, Vol. 64, No. 1, pp. 73–94, July, 1998.This research was partially supported by INTAS-RFBR under grant No. 95-91 in the case of the first author, and by INTAS under grant No. 96-0698 in the case of the second author. 相似文献