Rheological properties and the interface in polycarbonate/impact modifier blends: Effect of modifier shell molecular weight

Core-shell impact modifiers are used to enhance the impact strength of thermoplastics such as polycarbonate. The shell of the modifier is designed specifically to interact with the matrix polymer because interfacial adhesion between the modifier and matrix is important in improving the impact strength. Several methods have been proposed to study the interactions at the modifier/matrix interface. One measure of this interaction is the strength of lap joints. The degree of interactions at the interface can be characterized as the thickness of the interfacial region where the chains of the two polymers mix. Yet another aspect is related to the effect of interfacial interactions on the dynamic mechanical properties of the blend. Previous studies have shown that the viscoelastic properties of these blends deviate from the emulsion models that have been proposed for such blends. The deviation of the measured viscoelastic behavior of these blends compared to that predicted by the models has been attributed to the formation of network structure of particles in the blend. The formation of the network structure is a consequence of larger effective volumes of the particles due to interactions at the interface with the matrix. This study provides a means of using rheological properties and the emulsion models to estimate the extent of interaction at the modifier/matrix interface. In blends used in this study it can be shown that the interactions between the modifier and matrix extend far beyond the boundary between the two and the estimated effective volume fraction of modifier is much larger than the actual modifier content in the blend. The effective volume fraction is frequency dependent and decreases with increasing frequency. The data suggest that beyond certain frequencies the modifier no longer interacts with the matrix and the system has properties similar to the matrix with holes. The data are presented which indicate that, within the range studied, lower modifier shell molecular weight results in a higher level of interaction with polycarbonate. © 1998 John Wiley & Sons, Inc. J Polym Sci B: Polym Phys 36: 1095–1105, 1998     

Carbon dioxide–poly(vinylidene fluoride) interactions at high pressure

The article reports on the behaviour of poly(vinylidene fluoride) in carbon dioxide at 42°C and 80°C and in a pressure range of 0.1–30 MPa. Experimental techniques for the measurement of gas mass uptake and polymer dilatation are described and the corresponding data are reported as mass sorption and dilatation isotherms, respectively. The mass uptake experiment was also used to follow the evolution of the coefficient of diffusion of carbon dioxide into the polymer as a function of pressure or concentration. An analysis for the calculation of the partial molar volume of carbon dioxide as a function of pressure is also given, which shows that the ‘apparent’ partial molar volume of the carbon dioxide decreases with pressure to very low values, at high pressure. The computed values are significantly less than those for either the liquid or the solid phases of pure carbon dioxide, and also lower than some data previously reported for silicone elastomers. A consideration of the origins of this apparent anomaly is given in the conclusions. © 1998 John Wiley & Sons, Inc. J. Polym. Sci. B Polym. Phys. 36: 2435–2447, 1998     

一个关于影子系统的不等式

最近,S．Campi和P．Gronchi利用影子系统的概念对L^p-Brunn-Minkowski理论做了实质性的推进研究．该文主要给出了影子系统的一个性质,建立了n个影子系统的体积之积与生成它们的凸体的体积之间关系的一个不等式．     

A finite volume method for fluid flow in polar cylindrical grids

In the numerical simulation of fluid flows using a polar cylindrical grid, grid lines meet at a single point on the axis of the polar cylindrical grid system; this makes the grids around the axis degenerate from being general quadrilaterals into triangles. Therefore, a special treatment must be performed when the axis has to be included in the computational domain in order to solve a non-axisymmetrical fluid flow problem. In this paper a new numerical method has been developed to deal with the difficulty of the axis when the control volume technique is used with a non-staggered grid arrangement. Two illustrative examples of the proposed method are presented for simulating the fluid flows on the axis and all the numerical results obtained for the two examples are shown to be in good agreement with the available analytical solutions. © 1998 John Wiley & Sons, Ltd.     

Computation of buoyancy-driven flow in an eccentric centrifugal annulus with a non-orthogonal collocated finite volume algorithm

A computational study is performed on two-dimensional mixed convection in an annulus between a horizontal outer cylinder and a heated, rotating, eccentric inner cylinder. The computation has been done using a non-orthogonal grid and a fully collocated finite volume procedure. Solutions are iterated to convergence through a pressure correction scheme and the convection is treated by Van Leer's MUSCL scheme. The numerical procedure adopted here can easily eliminate the ‘Numerical leakage’ phenomenon of the mixed convection problem whereby strong buoyancy and centrifugal effects are encountered in the case of a highly eccentric annulus. Numerical results have been obtained for Rayleigh number Ra ranging from 7×10³ to 10⁷, Reynolds number Re from 0 to 1200 and Prandtl number Pr from 0.01 to 7. The mixed rotation parameter σ (=Ra/PrRe²) varies from ∞ (pure natural convection) to 0.01 with various eccentricities ε. The computational results are in good agreement with previous works which show that the mixed convection heat transfer characteristics in the annulus are significantly affected by σ and ε. The results indicate that the mean Nusselt number Nu increases with increasing Ra or Pr but decreases with increasing Re. In the case of a highly eccentric annulus the conduction effect becomes predominant in the throat gap. Hence the crucial phenomenon on whereby Nu first decreases and then increases can be found with increasing eccentricity. © 1998 John Wiley & Sons, Ltd.     

A bore-capturing finite volume method for open-channel flows

A high-resolution finite volume hydrodynamic solver is presented for open-channel flows based on the 2D shallow water equations. This Godunov-type upwind scheme uses an efficient Harten–Lax–van Leer (HLL) approximate Riemann solver capable of capturing bore waves and simulating supercritical flows. Second-order accuracy is achieved by means of MUSCL reconstruction in conjunction with a Hancock two-stage scheme for the time integration. By using a finite volume approach, the computational grid can be irregular which allows for easy boundary fitting. The method can be applied directly to model 1D flows in an open channel with a rectangular cross-section without the need to modify the scheme. Such a modification is normally required for solving the 1D St Venant equations to take account of the variation of channel width. The numerical scheme and results of three test problems are presented in this paper. © 1998 John Wiley & Sons, Ltd.     

A three-dimensional hydrodynamic model in curvilinear co-ordinates with collocated grid

A three-dimensional hydrodynamic model has been developed for turbulent flows with free surface. In the horizontal x–y-plane, a boundary-fitted curvilinear co-ordinate system is adopted, while in the vertical direction, a σ-co-ordinate transformation is used to represent the free surface and bed topography or lower boundary. Using the finite volume method, the convection terms are discretized using Roe's second-order-accurate scheme. The governing equations are solved in a collocated grid system by a fractional three-step implicit algorithm that has been developed to handle the velocity–pressure–depth coupling problem of free surface incompressible fluid flows. The present study is the extension of previous work to three-dimensional turbulent flows. The model has been applied to three test cases. Comparison with available data shows that the model developed is successful, and is valuable to engineering application. © 1998 John Wiley & Sons, Ltd.     

Domain decomposition for the incompressible Navier–Stokes equations: solving subdomain problems accurately and inaccurately

For the solution of practical flow problems in arbitrarily shaped domains, simple Schwarz domain decomposition methods with minimal overlap are quite efficient, provided Krylov subspace methods, e.g. the GMRES method, are used to accelerate convergence. With an accurate subdomain solution, the amount of time spent solving these problems may be quite large. To reduce computing time, an inaccurate solution of subdomain problems is considered, which requires a GCR-based acceleration technique. Much emphasis is put on the multiplicative domain decomposition algorithm since we also want an algorithm which is fast on a single processor. Nevertheless, the prospects for parallel implementation are also investigated. © 1998 John Wiley & Sons, Ltd.     

Computation of internal high-speed separated flow with modified B–L and J–K models

The existence of shock–turbulent boundary layer interactions lead to very complicated flow phenomena and pose a challenge for numerical simulation. In this paper, two turbulence models, the Baldwin–Lomax (B–L) model and the Johnson–King (J–K) model, which were originally developed for simple external flow simulation, are modified to model complex high-speed internal separated flows. The full Navier–Stokes solver used in this paper is based on a cell-centered finite volume method and multistepping time marching scheme. Both implicit residual smoothing and local time stepping techniques are incorporated to accelerate the convergence rate. To ensure the numerical stability with the present explicit scheme, a point-implicit treatment to the source term in the ordinary differential equation (ODE) of the J–K model has been developed and has proved to be very effective in modeling such a complex flow. An arc-bump channel flow case has been studied. Comparisons of computed results with experimental data show that the present solver, with the modified turbulence models, predicts the shock and the flow separation very well. The J–K model is found to predict the size of the separation bubble with a higher accuracy. © 1998 John Wiley & Sons, Ltd.     

Effect of available volumes on radial distribution functions

The traditional method of analyzing solution structuring properties of solutes using atom–atom radial distribution functions (rdfs) can give rise to misleading interpretations when the volume occupied by the solute is ignored. It is shown by using the examples of O(4) in α- and β-D-allose that a more reliable interpretation of rdfs can be obtained by normalising the rdf using the available volume, rather than the traditional volume of a spherical shell. © 1998 John Wiley & Sons, Inc. J Comput Chem 19: 363–367, 1998